Percepção de sucesso na carreira da mulher executiva brasileira

Este artigo está baseado em uma pesquisa descritiva, de natureza quantitativa, que permitiu mensurar de forma clara e com rigor necessário a percepção de sucesso na carreira por parte das mulheres executivas brasileiras. O universo de pesquisa foi formado por mulheres que ocupam cargos em nível executivo em empresas no estado de São Paulo e a amostra foi não probabilística e por conveniência, composta por 238 mulheres em atividade profissional. Os dados foram coletados por intermédio de uma escala de Percepção de Sucesso na Carreira (PSC) composta por 48 itens distribuídos em 11 fatores, que foram agrupados em duas dimensões. A primeira é a dimensão subjetiva, composta pelos seguintes fatores: Competência, Contribuição, Cooperação, Criatividade, Desenvolvimento, Empregabilidade, Identidade e Valores. A segunda é a dimensão objetiva, composta pelos fatores Hierarquia/Promoção e Remuneração. O fator Equilíbrio Vida-Trabalho foi avaliado em separado. Observou-se que 85,0% das respondentes afirmaram que são reconhecidas por sua competência profissional e 83,7% que são reconhecidas por sua contribuição em suas atividades profissionais. O reconhecimento devido à cooperação em suas atividades profissionais é percebido por 85,9% das respondentes. Seguindo o mesmo raciocínio, 69,4% afirmaram que são reconhecidas por sua criatividade no exercício de suas atividades profissionais e 85,3% afirmaram que são reconhecidas por seu desenvolvimento profissional. Das entrevistadas, 60,4% afirmaram que se sentem seguras e empregáveis no mercado de trabalho e 76,4% das respondentes afirmaram que se identificam com o trabalho. Com relação ao fator valor, 89,9% das mulheres entrevistadas afirmaram que prezam pelos valores em suas atividades. Com relação ao fator hierarquia e promoção, 163 das respondentes (68,5%) afirmaram que têm reconhecimento e 105 (44,2%) consideram importantes as recompensas financeiras. Por fim, 59,7% das respondentes afirmaram que valorizam o equilíbrio entre a vida profissional e pessoal. Comparando-se as médias dos valores atribuídos para as dimensões: subjetiva, objetiva e o equilíbrio vidatrabalho, constata-se a superioridade da dimensão subjetiva, o que indica que os fatores subjetivos de percepção de sucesso são mais relevantes que os fatores objetivos nas respondentes. Em segundo lugar aparece o fator equilíbrio Vida-Trabalho e, por último, a dimensão objetiva. As mulheres executivas pesquisadas valorizam mais a busca pelo equilíbrio entre a vida profissional e a vida pessoal do que os ganhos materiais, representados por cargos e salários. Pode-se considerar que a percepção de sucesso na carreira da mulher executiva caracteriza-se pela predominância dos fatores subjetivos, o que indica maior femininização no atual mercado de trabalho brasileiro.

Laminados compósitos de PRFV: efeitos da descontinuidade geométrica e do envelhecimento ambiental acelerado

The growing demand in the use of composite materials necessitates a better understanding of its behavior related to many conditions of loading and service, as well as under several ways of connections involved in mechanisms of structural projects. Within these project conditions are highlighted the presence of geometrical discontinuities in the area of cross and longitudinal sections of structural elements and environmental conditions of work like UV radiation, moisture, heat, leading to a decrease in final mechanical response of the material. In this sense, this thesis aims to develop studies detailed (experimental and semi-empirical models) the effects caused by the presence of geometric discontinuity, more specifically, a central hole in the longitudinal section (with reduced cross section) and the influence of accelerated environmental aging on the mechanical properties and fracture mechanism of FGRP composite laminates under the action of uniaxial tensile loads. Studies on morphological behavior and structural degradation of composite laminates are performed by macroscopic and microscopic analysis of affected surfaces, in addition to evaluation by the Measurement technique for mass variation (TMVM). The accelerated environmental aging conditions are simulated by aging chamber. To study the simultaneous influence of aging/geometric discontinuity in the mechanical properties of composite laminates, a semiempirical model is proposed and called IE/FCPM Model. For the stress concentration due to the central hole, an analisys by failures criteria were performed by Average-Stress Criterion (ASC) and Point-Stress Criterion (PSC). Two polymeric composite laminates, manufactured industrially were studied: the first is only reinforced by short mats of fiberglass-E (LM) and the second where the reinforced by glass fiber/E comes in the form of bidirectional fabric (LT). In the conception configurations of laminates the anisotropy is crucial to the final mechanical response of the same. Finally, a comparative study of all parameters was performed for a better understanding of the results. How conclusive study, the characteristics of the final fracture of the laminate under all conditions that they were subjected, were analyzed. These analyzes were made at the macroscopic level (scanner) microscope (optical and scanning electron). At the end of the analyzes, it was observed that the degradation process occurs similarly for each composite researched, however, the LM composite compared to composite LT (configurations LT 0/90º and LT ±45º) proved to be more susceptible to loss of mechanical properties in both regarding with the central hole as well to accelerated environmental aging

Study of the mechanism of action of anoplin, a helical antimicrobial decapeptide with ion channel-like activity, and the role of the amidated C-terminus

Anoplin, an antimicrobial, helical decapeptide from wasp venom, looses its biological activities by mere deamidation of its C-terminus. Secondary structure determination, by circular dichroism spectroscopy in amphipathic environments, and lytic activity in zwitterionic and anionic vesicles showed quite similar results for the amidated and the carboxylated forms of the peptide. The deamidation of the C-terminus introduced a negative charge at an all-positive charged peptide, causing a loss of amphipathicity, as indicated by molecular dynamics simulations in TFE/water mixtures and this subtle modification in a peptide's primary structure disturbed the interaction with bilayers and biological membranes. Although being poorly lytic, the amidated form, but not the carboxylated, presented ion channel-like activity on anionic bilayers with a well-defined conductance step; at approximately the same concentration it showed antimicrobial activity. The pores remain open at trans-negative potentials, preferentially conducting cations, and this situation is equivalent to the interaction of the peptide with bacterial membranes that also maintain a high negative potential inside. Copyright (C) 2007 European Peptide Society and John Wiley & Sons, Ltd.

Second-order statistics for diversity-combining, techniques in Nakagami-fading channels

Exact and closed-form expressions for the level crossing rate and average fade duration are presented for the M branch pure selection combining (PSC), equal gain combining (EGC), and maximal ratio combining (MRC) techniques, assuming independent branches in a Nakagami environment. The analytical results are thoroughly validated by reducing the general case to some special cases, for which the solutions are known, and by means of simulation for the more general case. The model developed here is general and can be easily applied to other fading statistics (e.g., Rice).

A 4.2 kDa synthetic peptide as a potential probe to evaluate the antibacterial activity of coumarin drugs

The coumarin antibiotics are potent inhibitors of DNA replication whose target is the enzyme DNA gyrase, an ATP-dependent bacterial type II topoisomerase. The coumarin drugs inhibit gyrase action by competitive binding to the ATP-binding site of DNA gyrase B protein. The production of new biologically active products has stimulated additional studies on coumarin-gyrase interactions. In this regard, a 4.2 kDa peptide mimic of DNA gyrase B protein from Escherichia coli has been designed and synthesized. The peptide sequence includes the natural fragment 131-146 (coumarin resistance-determining region) and a segment containing the gyrase-DNA interaction region (positions 753-770). The peptide mimic binds to novobiocin (K-a = 1.4 +/- 0.3 x 10(5) m(-1)), plasmid (K-a = 1.6 +/- 0.5 x 10(6) m(-1)) and ATP (K-a = 1.9 f 0.4 x 10(3) m(-1)), results previously found with the intact B protein. on the other hand, the binding to novobiocin was reduced when a mutation of Arg-136 to Leu-136 was introduced, a change previously found in the DNA gyrase B protein from several coumarin-resistant clinical isolates of Escherichia coLi. In contrast, the binding to plasmid and to ATP was not altered. These results suggest that synthetic peptides designed in a similar way to that described here could be used as mimics of DNA gyrase in studies which seek a better understanding of the ATP, as well as coumarin, binding to the gyrase and also the mechanism of action of this class of antibacterial drugs. Copyright (C) 2004 European Peptide Society and John Wiley Sons, Ltd.

Photoinduced structural changes in antimony polyphosphate based glasses

A photocontraction effect in amorphous films of the binary glass system 0.20 [Sb(PO3)(3)](n)-0.80 Sb2O3 has been observed after UV irradiation using the 350.7 nm Kr+ ion laser line with 5.0 W/cm(2). Good optical quality films up to 4.0 mum were deposited on silica substrates at room temperature in vacuum by electron beam physical vapor deposition (EB-PVD) and characterized using WDX, XRD, optical absorption, infrared reflectance, profilometry and atomic force microscopy (AFM) techniques. Very stable glasses were prepared by the melt quenching technique and used as evaporation source for the production of films. The photoinduced structural change (PSC) was observed as a variation of about 6% in the film thickness and this effect is accompanied by a photobleaching of the irradiated area with a blue shift of the optical absorption edge. Otherwise this photoinduced change in the film thickness is very sensitive to the variations in the shape and intensity of the laser beam; therefore several possibilities in optical recording arise from these results. (C) 2003 Published by Elsevier B.V.