917 resultados para improvement of Lagrangian bounds
Resumo:
The discretization size is limited by the sampling theorem, and the limit is one half of the wavelength of the highest frequency of the problem. However, one half of the wavelength is an ideal value. In general, the discretization size that can ensure the accuracy of the simulation is much smaller than this value in the traditional finite element method. The possible reason of this phenomenon is analyzed in this paper, and an efficient method is given to improve the simulation accuracy.
Resumo:
The alpha decay constant is the product of the penetrability P and assault frequency nu(0) in the fission-like model. An effective assault frequency P-nu replacing the previous assault frequency nu(0) is introduced for improvement of a fission-like model named the generalized liquid drop model (GLDM) to describe the nuclear alpha decay process more accurately. Two analytical formulae are proposed for the effective assault frequency due to experimental data within the GLDM. The improved model can be used to give accurate calculations for alpha decay half-lives.
Resumo:
Catalytic activity of Pt catalysts for soot oxidation was studied using temperature programmed reactions. The activity of Pt loaded over TiO2-SiO2 (Pt/TiO2-SiO2) showed higher activity than other Pt/MOx systems (MOx = TiO2, ZrO2, SiO2, Al2O3. TiO2-ZrO2. TiO2-Al2O3, ZrO2-SiO2, ZrO2-Al2O3, SiO2-Al2O3). The activity was highest when the molar ratio of TiO2/(TiO2 + SiO2) ranged from 0.4 to 0.7. The effect of pretreatment with a gas containing low SO2 concentrations on the activity was compared for Pt/SiO2, Pt/TiO2 and Pt/TiO2-SiO2. In the case of Pt/TiO2-SiO2, the activity was markedly promoted by the pretreatment whereas no variation in the activity was observed for Pt/SiO2. The difference in the behavior towards the SO, pretreatment was attributed to property difference in the supports for sulfate accumulation. The high activity of Pt/TiO2-SiO2 was also confirmed under practical conditions with a diesel engine exhaust using a catalyst-supported diesel particulate filter (DPF). (C) 2003 Elsevier Science B.V. All rights reserved.
Resumo:
It has been experimentally found that molybdenum oxide (MoO3) as the interfacial modification layer on indium-tin-oxide (ITO) in organic light-emitting diodes (OLEDs) significantly improves the efficiency and lifetime. In this paper, the role of MoO3 and MoO3 doped N,N '-di(naphthalene-1-yl)-N,N '-diphenyl-benzidine (NPB) as the interface modification layer on ITO in improvement of the efficiency and stability of OLEDs is investigated in detail by atomic force microscopy (AFM), polarized optical microscopy, transmission spectra, ultraviolet photoemission spectroscopy (UPS) and X-ray photoemission spectroscopy (XPS).
Resumo:
A well-known red fluorescent dye 4-(dicy-anomethylene)-2-t-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)4H-pyran (DCJTB) was codoped with an electron transport organic molecule tris(8-hydroxyquinohne) aluminum (Alq3) in a host matrix of polystyrene (PS), and the amplified spontaneous emission (ASE) was studied by optically pumping. It was found that the ASE performance was significantly improved by the introduction of Alq3. The Alq3:DCJTB:PS blending thin films showed a low threshold (2.4 mu J/pulse) and a high net gain coefficient (109.95 cm(-1)) compared with the pure DCJTB:PS system (threshold of 15.2 mu J/pulse and gain of 35.94 cm(-1)). The improvement of the ASE performance was considered to be attributable to the effective Foster energy transfer from Alq(3) to DCJTB. Our results demonstrate that the Alq(3):DCJTB could be a promising candidate as gain medium for red organic diode lasers.
Resumo:
Improvement of the sensitivity of electrochemical sandwich enzyme immunoassay has been achieved by electrodepositing redox polymer on screen-printed carbon electrode surface, on which the sandwich complex was formed.
Resumo:
Polycrystalline Sr2FeMoO6 compounds with most vacancies at normal Fe sites were fabricated through Mo hole doping; its effect is similar to Fe3+ by our estimation. Sharp increase of magnetoconductance at low field was evidence of spin-polarized tunneling between the grains. The room temperature low-field magnetoresistivity at optimal doping x=0.03 is 8.5% in 3000 Oe and increases to 11.4% in 1 T associated with soft magnetic behaviors; furthermore it exhibits a ferromagnetic Curie temperature of 450 K, connected with hole doping effect. The improved magnetoresistivity behavior was related to Curie temperature.
Resumo:
Radiation effects on polyimide blends' were studied at different irradiation temperatures and with different irradiation doses. The irradiation polyimides were the blends of linear polyimide (HQDPA/ODA) and 4-phenylethynyl phthalic anhydride end-capped oligomer polyimide. The tensile strength and the elongation at break of irradiated films were determined as the function of irradiation temperature and dose. Under proper conditions crosslinking reaction occurred when the polyimide blends were irradiated at high temperature. The mechanical properties of irradiated polyimide blends were found to be different from the linear polyimide.
Resumo:
In this paper, we study the effects of electrical annealing at different voltages on the performance of organic light-emitting diodes. The light-emitting diodes studied here are single-layer devices based on a conjugated dendrimer doped with 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole as the emissive layer. We find that these devices can be annealed electrically by applying a voltage. This process reduces the turn-on voltage and enhances the brightness and efficiency. We obtained an external electroluminescence quantum efficiency of 0.07% photon/electron and a brightness of 2900 cd m(-2) after 12.4 V electrical annealing, which are about 6 times and 9 times higher than un-annealing devices, respectively. The improved luminance and efficiency are attributed to the presence of a space charge field near the electrodes caused by charging of traps.
Resumo:
The oxygen permselectivity of a poly[1-(trimethylsilyl)-1-propyne) (PTMSP) membrane was drastically improved by plasma polymerization of fluorine-containing monomers. The effects of such plasma polymerization conditions as deposition time, plasma power an
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One of the most attractive features of derivative spectrometry is its higher resolving power. In the present power, numerical derivative techniques are evaluated from the viewpoint of increase in selectivity, the latter being expressed in terms of the interferent equivalent concentration (IEC). Typical spectral interferences are covered, including flat background, sloped background, simple curved background and various types of line overlap with different overlapping degrees, which were defined as the ratio of the net interfering signal at the analysis wavelength to the peak signal of the interfering line. the IECs in the derivative spectra are decreased by one to two order of magnitudes compared to those in the original spectra, and in the most cases, assume values below the conventional detection limits. The overlapping degree is the dominant factor that determines whether an analysis line can be resolved from an interfering line with the derivative techniques. Generally, the second derivative technique is effective only for line overlap with an overlapping degree of less than 0.8. The effects of other factors such as line shape, data smoothing, step size and the intensity ratio of analyte to interferent on the performance of the derivative techniques are also discussed. All results are illustrated with practical examples.
Resumo:
An incubating temperature of 15 degreesC is used to induce triploidy in Etiocheir sinensis through inhibition of the release of polar body H, and that of 18 degreesC to induce tetraploidy through inhibition of the first cleavage. Flow cytometry is used to identify the ploidy in different developmental stages. For induction of triploidy in fertilized eggs in vitro, the highest induction rate observed in blastula by cytochalasin B, 6-DMAP and KCI is 49.1%, 51.7% and 77.5%, respectively. In the KCI treatment of pregnant crabs with the fertilized eggs, the highest triploid induction rate observed in the zoea is 85.3%. For induction of tetraploidy, the highest induction rate observed in the blastula by cytochaslasin 13, 6-DMAP and KCI is 50.3%, 54.9% and 79.8% respectively. In the KCI treatment of pregnant crabs with the fertilized eggs, the highest induction rate in zoea is 27.3%. Through this study such difficulty as in vitro culture is overcome. Triploid zoea Etiocheir sinensis has been developed for the first time. The induction rate of tetraploid zoea has also been greatly improved.