中国大陆地区远震体波接收函数与岩石圈厚度的研究

Movements of separation and convergence between the continental plates, as well as the interaction beween the lithosphere and asthenosphere is the dominant factor in plate evolution. Moreover, those phenomena, the formation, enrichment and storage of energy and mineral strorage, as well as intraplate earthquakes are all relate to plate movement and evolution. Therefore, the study of continental lithosphere, is not only helpful to analysing the dynamic model between lithosphere and asthenoshere as well as different plates, but also important to the nation's economy and the people's livelihood. And the lithospheric thickness or Lithosphere-Asthenosphere Boundary (LAB) is one of the most important parameters in study of continental lithospheric formation and evolution. Chinese continent composed by many small plates, possesses diverse type of lithospheric structure. But our knowledge ahout Chinese continental lithosphere, especially the regional research, is almost based on the low-resolution results of surface wave dispersion analysis and seismic wave tomography. Howere, recently a technique employing S-to-P converted body waves (the S receiver function technique) has been developed that can be used to identify the LAB with a higher resolution. This thesis has collected waveform data of 232 broadband seismic stations that are located in China and neighboring regions. Using teleseismic S-wave and P-wave receiver functions have studied the Chinese continental lithospheric structure. The results of this study indicate that, the thickness of Chinese continental lithosphere become thinner from west to east, and obvious difference exists between different blocks. Four types of lithosphere have been detected: (1) Convergence thicking lithosphere in Tibetan Plateau; (2) Stable lithosphere in Tarim basin and upper Yangtze craton; (4) Active lithosphere in Orogenic belts; (4) Break-up thinning lithosphere in east China craton

新增生岩石圈与软流圈的相互作用：来自地幔橄榄岩捕虏体的证据

The petrology and geochemistry of peridotites entrained in Beiyan Cenozoic alkaline basalts within the middle segment of Tan-Lu fault zone and clinopyroxene megacrysts in the late Mesozoic and Cenozoic alkaline basaltic rocks from the North China Craton, have been systematically investigated. The main conclusions are obtained as follows. The peridotites entrained in alkaline basalts at Beiyan, Shandong Province, China are comprised of dominantly spinel lherzolites and spinel wehrlites with porphyroclastic, granuloblastic textures to resorption textures. The xenoliths are fertile in major element compositions (High CaO, TiO2, Low MgO, Cr2O3). The olivine Fo (= 100×Mg / (Mg+Fe) possesses a low and very large range of 81.0 to 91.0. The peridotites contain high percentages (Lherzolites: 10 - 19% in volume; Wehrlites: 24 - 28% in volume) of clinopyroxene with spongy textures. The Sr and Nd isotopic ratios of clinopyroxene separates from peridotites and pyroxenite xenoliths have a depleted and small range fall within the area of MORB, similar to newly-accreted lithospheric mantle. However, the appearance of many wehrlites and highly enriched LREE pattern suggest that this newly-accreted lithospheric mantle was considerably modified and reconstructed recently through the peridotite-asthenospheric melt interaction. The upwelling of asthenosphere from late Cretaceous to Eogene and upper mantle shearing of the Tan-Lu fault played an important role in the modification and reconstruction of the newly-accreted lithospheric mantle. The clinopyroxene megacrysts in the late Mesozoic and Cenozoic alkaline basaltic rocks from the eatern North China Craton are different in aspects of major elements, trace elements and isotopic composition. The characteristics of texture, mineral compositions and geochemistry as well as the Fe-Mg partitioning between the crystal and the melt indicates that the Al-augites in the Cenozoic basalts represent high-pressure crystallization products of alkaline basaltic melts. Thus, both of clinopyroxene megacrysts and host basalts could be derived from a same primitive magma. However, the Al-augites in the late Mesozoic basaltic rocks represent accidentally-included xenocrysts of basaltic components which had crystallized in the depth from a previously melting episode. The more depleted Sr-Nd isotopic compositions of Cenozoic megacrysts compared with those of host alkaline basalts and tholeiites demonstrate that even the alkali basalts could not completely represent primitive magma initiating in asthenosphere. That is to say, the Cenozoic alkaline basalts were more or less modified by some enriched Sr-Nd isotopic components during their eruption. Meanwhile, the tholeiites were not the products formed only by fractional crystallization of alkaline basaltic magma or different degrees of partial melting. It may result from the contribution of lithospheric mantle materials or crust contamination in magma chamber to alkali basaltic magmas.

特提斯喜马拉雅带晚白垩世-始新世沉积源区分析及其构造意义

Tethyan Himalayan Sequence (THS) is located at the frontier of the India-Asia collision zone, which can preserve critical information about collision. This paper reports detailed petrology, geochemistry, spinels electron microprobe data, and in situ U-Pb ages and Lu-Hf isotopic data on detrital zircons from the late Cretaceous to early Eocene strata in Gyantze and Gamba area, south Tibet that provide important constraints on the early tectonic evolution of the India-Asia collision. In Gyantze, the lithic arkose in Zongzhuo mélange is characterized by, SiO2 =80.4%, Al2O3=8.6%, Na2O=1.6%, K2O=1.1%, LaN/YbN=8.90, and εNd (0) =-10.27. Spinels compositions are characterized by low TiO2 (generally <0.1%) and a Cr number mainly between 70 and 80. The largest population of detrital zircons is within the 73-169Ma range with high εHf (t) and > 500 Ma with complex εHf (t) values. The lithic arkose in Rilang conglomerate is characterized by, SiO2 =56.5%, Al2O3=15.6%, Na2O=4.7%, K2O=0.6%, LaN/YbN=5.00-5.29, and εNd (0) =1.92. Spinels of 2006T98 display high TiO2 (generally >0.2%) and a Cr number mainly between 70 and 85, other spinels are characterized by low TiO2 (generally <0.2%) and a Cr number mainly between 60 and 90. The largest population of detrital zircons is within 90-146 Ma range with high εHf (t). The lithic arkose in Jiachala formation is characterized by, SiO2 =64.6%, Al2O3=12.1%, Na2O=1.9%, K2O=1.8%, LaN/YbN=7.73-9.13, and εNd (0) =-5.52~-8.43. Spinels in the Jiachala formation have low TiO2 (generally <0.2%) and a Cr number between 39 and 88. Detrital zircons have a wide range of age distribution of 82-3165Ma with complex εHf (t). In Gamba, The quartze sandstone in Jidula formation is characterized by, SiO2=97.4%, Al2O3=0.9%, Na2O=0.03%, K2O=0.18%, LaN/YbN=18.70-21.684, and εNd (0) between -13.1~-7.4. While the lithic arkose in Zhepure formation is characterized by, SiO2=68.4%, Al2O3=7.3%, Na2O=1.15%, K2O=0.52%, LaN/YbN=6.09-8.99, and εNd(0)=-5.8~-6.3. Based on our geochemical analysis, spinles electron microprobe data, U–Pb ages and Hf isotope data for detrital zircons of the late Cretaceous-Eocene strata in Gyantze and Gamba, southern Tibet, the following major conclusions can be drawn: 1. In Gyantze, the Zongzhuo mélange was mainly derived from accretionary prism/THS of continental slop and Gangdese arc. Rilang conglomerate was totally from Gangdese arc. The Jiachala formation was derived from THS, suture zone and Gangdese arc. 2. In Gamba, the Jidula formation was from India craton, while the Zhepure formation was derived from THS, suture zone and Gangdese arc. 3. The deposite of Zongzhuo mélange and Rilang conglomerate (73-55Ma) marks the collision between India and Asia. 4. Late Paleocene-Eocene tectonic evolution is consistent with foreland basin system.

胶东地区金矿床成矿时代及其成矿地球动力学背景-兼论壳幔相互作用与成岩成矿

Jiaodong Peninsula is the largest repository of gold in China. Varieties of studies have been involved in the mechanism of metallogenesis. This thesis is a part of the project "Study of basic geology related to the prespecting of the supra-large deposits" which supported by National Climbing Program of China to Prof. Zhou. One of the key scientific problems is to study the age and metallogenic dynamics of ore deposit and to understand how interaction between mantle and crust constrains on metallogenesis and lithogenesis. As Jiaodong Peninsula to be study area, the Rb-Sr, Sm-Nd and Pb isotopic systematics of pyrite and altered rocks are measured to define the age and origin of gold. The elemental and Sr-Nd-Pb isotopic compositions of dikes and granites was studied to implicate the source and lithogenesis of the dike and granite and removal of lithosphere and the interaction between mantle and crust in the Jiaodong Peninsula. Considering the tectonic of Jiaodong Peninsula, basic on the time and space, this thesis gives a metallogenic dynamics of gold mineralization and discusses the constraints of the interaction between mantle and crust on the metallogenesis and lithogenesis. This thesis reports the first direct Rb-Sr dating of pyrites and ores using sub-sampling from lode gold deposit in Linglong, Jiaodong Peninsula and the results demonstrate this as a useful geochronological technique for gold mineralization with poor age constraint. The Rb-Sr data of pyrites yields an isochron age of (121.6-122.7) Ma, whereas, those of ore and ore-pyrite spread in two ranges from 120.0 to 121.8 Ma and 110.0-111.7 Ma. Studies of characteristic of gold deposit, microscopy of pyrite and quartz indicate that the apparent ages of ore and ore-pyrite are not isochron ages, it was only mixed by two end members, i.e., the primitive hydrothermal fluids and wall rocks. However, the isochron age of pyrite samples constrains the age of gold mineralization, i.e., early Cretaceous, which is in good consistence with the published U-Pb ages of zircon by using the SHRIMP technique. The whole rock Rb-Sr isochron age of altered rocks indicates that the age of gold mineralizing in the Xincheng gold deposit is 116.6 ± 5.3 Ma. The Sr, Nd and Pb isotopic compositions of pyrite and altered rocks indicate that the gold and relevant elements were derived from multi-sources, i.e. dikes derived from enriched lithospheric mantle and granites, granodiorites and metamorphic rocks outcropped on the crust. It also shows that the hydrothermal fluids derived from mantle magma degassing had play an important role in the gold mineralizing. The major and trace elements, Sr-Nd-Pb isotopic data of granites and granodiorites suggest that the Linglong Granite and Kunyushan Granite were derived from partial melting of basement rocks in the Jiaodong Peninsula at post-collision of North China Craton with South China Craton. Guojialing Granodiorite was considered to be derived from a mixture source, that is, mixed by magmas derived from an enriched lithospheric mantle and crust during the delamination of lithosphere induced by the subduction of Izanagi Plate and the movement of Tancheng-Lujiang Fault. There are kinds of dikes occurred in the Jiaodong Peninsula, which are accompanying with gold mineralization in time and space. The dikes include gabrro, diabase, pyroxene diorite, gabrrophyre, granite-porphyry, and aplite. The whole rock K-Ar ages give two age intervals: 120-124 Ma for the dikes that erupted at the gold mineralizing stage, and <120 Ma of the dikes that intruded after gold mineralizing. According to the age and the relationship between the dikes and gold mineralizing, the dikes could be divided into two groups: Group I (t = 120-124 Ma) and Group II (t < 120Ma). Group I dikes show the high Mg and K, low Ti contents, negative Nb anomalies and positive Eu anomalies, high ~(87)Sr/~(86)Sr and negative εNd(t) values and an enrichment in light rare earth elements, large ion lithosphile elements and a depletion in high field strength elements. Thus the elemental and isotopic characteristics of the Group I dikes indicate that they were derived from an enriched lithospheric mantle perhaps formed by metasomatism of the melt derived from the recycled crustal materials during the deep subduction of continent. In contrast, the Group II dikes have high Ti, Mg and K contents, no negative Nb anomalies, high ~(87)Sr/~(86)Sr and positive or little negative εNd(t) values, which indicate the derivation from a source like OIB-source. The geochemical features also give the tectonic constraints of dikes, which show that Group I dikes were formed at continental arc setting, whereas Group II dikes were formed within plate background. Considering the tectonic setting of Jiaodong Peninsula during the period of gold mineralizing, the metallogenic dynamics was related to the subduction of Izanagi Plate, movement of Tancheng-Lujiang Fault and removal of lithopheric mantle during Late Mesozoic Era.

内蒙古东部喀喇沁地区早中生代底侵作用

Mafic granulite xenoliths have been extensively concerned over the recent years because they are critical not only to studies of composition and evolution of the deep parts of continental crust but to understanding of the crust-mantle interaction. Detailed petrology, geochemistry and isotope geochronology of the Early Mesozoic mafic-ultramafic cumulate xenoliths and mafic granulite xenoliths and their host diorites from Harqin area, eastern Inner-Mongolia have been studied here. Systematic Rb-Sr isochron, ~(40)Ar-~(39)Ar and K-Ar datings for mafic-ultramafic cumulate xenoliths give ages ranging from 237Ma to 221Ma. Geochemical research and forming temperature and pressure estimates suggest that cumulates are products of the Early Mesozoic mantle-derived magmatic underplating and they formed in the magmatic ponds at the lowermost of the continental crust and are later enclaved by the dioritic magma. Detailed study on the first-discovered mafic granulite xenoliths reveals that their modal composition, mineral chemistry and metamorphic P-T conditions are all different from those of the Precambrian granulite exposed on the earth surface of the North China craton. High-resolution zircon U-Pb dating suggests that the granulite facies metamorphism may take place in 253 ～ 236Ma. Hypersthene single mineral K-Ar dating gives an age of 229Ma, which is believed to represent a cooling age of the granulite. As the host rock of the cumulate and granulite xenoliths, diorites intruded into Archean metamorphic rocks and Permian granite. They are mainly composed of grandodiorite, tonalite and monzogranite and show metaluminous and calc-alkaline features. Whole rock and single mineral K-Ar dating yields age of 221 ～ 223Ma, suggesting a rapid uplift in the forming process of the diorites. Detailed field investigation and geochemical characteristics indicate that these diorites with different rock types are comagmatic rocks, and they have no genetic correlation with cumulate and granulite xenoliths. Geochemical model simulating demonstrates that these diorites in different lithologies are products of highly partial melting of Archean amphibolite. It is considered that the Early Mesozoic underplating induced the intrusion of diorites, and it reflects an extensional geotectonic setting. Compression wave velocity V_P have been measured on 10 representative rock samples from the Early Mesozoic granulite and mafic-ultramafic cumulate xenoliths population as an aid to interpret in-situ seismic velocity data and investigating velocity variation with depth in a mafic lower crust. The experiments have been carried out at constant confining pressures up to 1000MPa and temperatures ranging from 20 ℃ to around 1300 ℃, using the ultrasonic transmission technique. After corrections for estimated in situ crustal pressures and temperatures, elastic wave velocities range from 6.5 ～ 7.4 km s~(-1). On the basis of these experimental data, the Early-Mesozoic continental compression velocity profile has also been reestablished and compared with those of the present and of the different tectonic environments in the world. The result shows that it is similar to the velocity structure of the extensional tectonic area, providing new constraints on the Early Mesozoic continental structure and tectonic evolution of the North-China craton. Combining with some newly advancements about the regional geology, the thesis further proposes some constraints on the Mesozoic geotectonic evolution history, especially the features of deep geology of the North China craton.

大别－苏鲁造山带与华北陆块东部岩石层三维速度结构

The 3-D velocity images of the crest and upper mantle beneath the region of 112° -124°E, 28°-39°N including the Dabie-Sulu orogenic belt are reconstructed by using 36405 P-wave arrivals of 3437 regional and 670 distant earthquakes during the period from 1981 to 1996, and gridding the area of 0.5° * 0.5°. The results of tomography demonstrate that: 1. The results of tomographic imaging show a broad heterogeneity in P wave velocity structure for the lithosphere beneath the Dabie-Sulu orogenic belt. 2. In the Dabie orogenic belt, the velocity patterns in the crust are different among various tectonic units. The Dabie and Qinling orogenic belts are remarkable in the tomographic images, and in mm the Hongan and Dabie blocks in the Dabie orogenic belt are also imaged very distinguishably. 3. A velocity (about 5.9～6.0 km/s) layer exists in the Dabie block at depth between 15～25 km, which is coincident with the low-resistance layer at the depth of 12-23 km, being inferred to be the tectonic detachment zone and suggesting that the extension detachment structure was formed in the middle crust. Beneath the southern and northerm Dabie tectonic units, the north-dipping high-velocity (at level of 6.5 ～ 6.6 km/s) block was developed in the crust, which might be correlated with the UHP rockswith low content of the meta-ultramafic rocks. This result is in agreement with the geological observation on the surface. 4. The velocity image at 40 km depth reveals the features at the top of mantle and the configuration of the Moho discontinuity. The depth of the Moho changes slightly along the trend of the orogenic belt. It in Hongan block is less than 40 km, but it is different in the western and eastern parts of the Dabie block, the former is more than 40 km, and the latter less than or equal to 40 km. The remnant of the mountain root exists between the Shangcheng-Macheng fault and the line of Huoshan-Yuexi-Yingshan in the Dabie orogenic belt, and beneath the southern and northern Dabie tectonic units. However, the thickness of the Moho is about 40 km and there is no obvious changes, which suggest that the Dabie orogenic belt has been experienced quite in the gravity equilibration. The Moho's depth in the Sulu is less than 40 km. 5. There is a dipping slab-like high-velocity body in the uppermost mantle. It is sandwiched by slow velocities and exists beneath the Dabie-Sulu orogenic belt in the range of depths between the Moho discontinuity and 110 km at least. This high-velocity body outlines a picture of the slab interpreted as the remnant of the Triassic subducted YZ. 6. The Sulu orogenic belt displays "crocodilian" velocity structure, the upper crust of the Yangtze thrusted over the Huabei crest, and the Huabei crust indented into the Yangtze crust, where the ancient subduction zone of the Yangtze lithosphere located. Based on the previous geological data, this structure is not related with the collision between the Yangtze and Sino-Korean Blocks, but caused by the sinistral offset of the Tan-Lu Fault. Studied on the velocity structure of the eastern Huabei lithosphere indicates: 1. The 'present-day' lithosphere of the eastern Huabei is between 40-100 km thick with greatly thinned lithosphere around the Bohai Sea. Generally, thickness of the lithosphere in this region decreased eastwards. 2. The attenuation of the lithosphere is attributed to the strongly uplift of the asthenosphere. In the area between the Taihang Mountains and the Tan-Lu Fault, there is a 'lever' with red low velocity belt, it is clearly defined, transverse continuity, depth between 100-150 km, local variations visible, and an upwards trend towards the Bohai Sea. Generally, the velocity structure in the mantle beneath the lithosphere displays irregular column-shape consisting of alternating high and low velocities, and when cold high velocity ancient lithosphere connects with the hot low velocity mantle materials forming precipitous compact structure. More heat pathways from the mantle occur towards the Tan-Lu Fault. 3. The strongly irregular characteristics of the contact between the asthenosphere and the lithosphere is induced by the long-term hot, chemical erosion and alteration on the contact. 4. There are still preserved high velocity lithosphedc root beneath Huabei with 'block-shape' distribution and surrounded by hot materials. Results of our studies indicate that the evolution models of the eastern China mantle are characterized by the direct contact between the uplifted lithosphere and the Huabei Craton accompanying the upwelling of the deep mantle materials. At the contact betwen the lithosphere and the asthenosphere, the upwelled mantle materials replaced and altered the lower lithosphere forming the metasome through the hot and chemical modifications impacted on the Craton lithosphere, and changed it into the lithosphere gradually, resulting in the lithospheric thinning. Thus, the lithospheric thinning is the result of the upwelling of the asthenosphere.

青藏高原东缘新生代富钾碱性岩的年龄与岩石地球化学特征

The Cenozoic high-Potassium alkaline magma rocks are widely distributed in the eastern margin of Qinghai-Xizang (Tibet) plateau, such as Mangkang, Deqin, Jianchuan, Haidong in the western Yunnan Province, Yanyuan, Muli in the western Sichuan province, including syenite, minette and trachyte and lamprophyres, which formaed a large alkaline-rich magmatic rock zone along the Jinshajiang-Ailaoshan fault. Here we present detailed Geochemical and Geochronology study for the Cenozoic high-K alkline magma rocks from Mangkang, Deqin, Jianchuan, Haidong and Muli, Yanyuan, Yanbian, Yaoan (western Yangtze craton). Rocks of our target area include syenite, minette and trachyte. Geochronologic dating and compilation of existing age data suggest magmatism occurred at 32-38Ma and distribute along the Jinsha suture, from Jinping, Daping, Zhenyuan to Haidong, Jianchuan, Deqin, Mangkang, Zaduo to Qiangtang Bandaohu, Zhentouya. They all share same geochemical features such as rich in potassium and alkaline, rich in LREE, slightly negative Eu anomalies, negative anomalies in Nb, Ta, Ti,. These indicate they come from EMU mantle. Geochronologic dating on western Yangtze craton minette surgest minette in Haidong, Yanyuan, Yanbian, Yaoan, Deqin ocurred at 30-37Ma, well minette in Muli ocurred at IMa. Need more detailed geology study to find differece of these two episode magmatism.

胶东地区三类金矿成矿系统地质地球化学及动力学

The East Shandong gold province is located on the southeastern margin of the North China Craton and features uplift in the north and depression in the south. The uplift area is made up of the Archaean Jiaodong Group, the Proterozoic Jingshan Group and Yanshannian granites. Most gold deposits in the uplift area are spatially associated with the Yanshannian granites. Two types of gold mineralization occur in the region: the quartz-vein type hosted in the Linglong granite suite, and the shear zone type hosted by either the Linglong granite or Guojialing granitoid suites. The mineralization ages are 113～126 Ma. The southern part of East Shandong contains the Mesozoic Jiaolai basin, which formed during regional extension. The basin is bounded by the Wulian-Rongcheng fault in the southeast and the Tanlu fault in the west. The Pengjiakuang, Fayunkuang and Dazhuangzi gold deposit occurs on the northeastern margin of the basin. The mineralization ages of these deposits are 110～128 Ma. This paper focuses on a low-angle detachment fault developed between the Proterozoic Jingshan Group metamorphic complex and the northeastern margin of the basin. Our field work shows that the distribution of the Pengjiakuang gold deposit was controlled by the detachment fault. Moreover, the Fayunkuang, Guocheng and Liaoshang gold deposits also occurr in the periphery of the basin, and their features are similar to Pengjiakuang gold deposit. The study of geological geochemistry of the gold deposits has shown: ①three-type gold deposit was situated in the Jiaodong area, including altered rock type (Jiaojia type), quartz vein type (Linglong type) and breccia type (Pengjiakuang type); the ore-forming materials and fluid for Pengjiakuang type gold deposit shows multiple source; ②the ore materials of Jiaojia and Linglong type deposits are mainly from deep source. The author has studied geological-geochemical dynamics of three types deposits in Jiaodong area. The study of tectonic dynamics shows that ore-forming structure differential stress values of Pengjiakuang gold deposit is 100 * 10~6～130 * 10~6 Pa, and that of Jiaojia gold deposit is 100 * 10~5～194 * 10~6 Pa. Dynamics of hydrothermal ore-forming fluid has also been studied in this paper. Author applies Bernoulli equation to dynamic model of hydrothermal fluid motion in brittle fracture and cracks (quartz vein type gold mineralization), and applies Darcy law to dynamic model of hydro thermal fluid motion in porous medium (altered rock type gold mineralization). Author does daring try in order to study quantitativly transport mechanism of hydrothermal ore-forming fluid in this paper. The study of fluid inclusions and crystal dynamics shows that reaction system of hydrothermal ore-forming includes three types, as follows: ore-forming reaction, controlling reaction and buffer controlling reaction. They depend on each other, controlling each other, which form a organic system. Further research shown that formation of ore shoots was controlled by coincidence processes of tectonic dynamic condition and thermodynamic evolution. This paper has summaried reginoal metallogenic laws and seted up metallogenic(dynamics) models for Jiaodong gold ore belt.

山东西部中生代碳酸岩和火山岩的地球化学特征及其成因研究

On account of some very peculiar features, such as extremely high Sr and Nd contents which can buffer their primary isotopic signatures against crustal contamination, deep-seated origin within mantle, and quick ascent in lithosphere, carbonatites are very suitable for deciphering the nature of sub-continental lithospheric mantle(SCLM) and receiving widespread attentions all around the world. The Mesozoic carbonatites located in western Shandong was comprehensively investigated in this dissertation. The extremely high REE concentrations, similar spider diagrams to most other carbonatites around the world and high Sr. low Mn contents of apatite from carbonatites confirm their igneous origin. The K depletion of carbonatites from this studies reflect the co-existing of carbonatite melts with pargasite+phlogopite lherzolite rather than phlogopite lherzolite. Geological characteristics and their occumng without associated silicate rocks argue against their origin of fractionation of or liquid immisibility with carbonated silicate melts. In contrast to the low S7Sr/86Sr and high l43Nd/l44Nd of other carbonatites in the world, carbonatites of this studies show EMU features with high S7Sr/86Sr and low l4jNd/144Nd ratios, which imply that this enriched nature was formed through metasomatism of enriched mantle preexisted beneath the Sino-korean craton by partial melts of subducted middle-lower crust of Yangtze craton. In addition to carbonatites, the coeval Mesozoic volcanic rocks from western Shandong were also studied in this dissertation. Mengyin and Pingyi volcanic rocks, which located in the south parts of western Shandong are shoshonite geochemically. while volcanic rocks cropped out in other places are high-K calc-alkaline series. All these volcanic rocks enriched in LREE and LILE. depleted in HFSE, and show TNT(strong negative anomalies in Ta, Nb. Ti) patterns in spider diagrams which are common phenomena in arc-related volcanic rocks. The Sr-Nd-Pb isotopic systematics reveal that the volcanic rocks decrease gradually in 87Sr/86Sr, 206Pb/204Pb, 20SPb/204Pb and increase in TDM from south to north, suggesting the distinction of SCLM beneath Shandong in Mesozoic is more explicit in south-north trending than in east-west trending. The variable features of SCLM can be attributed to the subduction of Yangtze craton beneath Sino-Korean craton, and subsequent metasomatism of SCLM by partial melts of Yangtze lower crust in different extent.

华南震旦纪-寒武纪两期成磷事件及其地球动力学意义

Phosphorus is an important biological and ecological element that to a certain degree constrains ecological environment and nutrient (including carbon) cycling. Marine sedimentary phosphorites are the principal phosphorus supply of the mankind. In the eastern to southern margins of the Yangtze Craton, South China, there are two phosphogenetic events at the Doushantuo stage of the Late Sinian and the Meishucun stage of the Early Cambrian respectively, corresponding two explosion events of life across the Precambrian\Cambrian boundary. Phosphorus ores from the Sinian and Cambrian phosphate in South China can be classified roughly into two categories, namely, grained and non-grained phosphorites. Grained phosphorites, hosted in dolostone type of phosphogenetic sequences and with larger industrial values, occur mainly in margins of the Upper Yangtze Platform, formed in shallow-water environments with high hydraulic energy and influenced by frequent sea-level change. Non-grained phosphorites, hosted principally in black-shale type of phosphogenetic sequences and with smaller industrial values, are distributed mainly in the Jiangnan region where deeper-water sub-basins with low hydraulic energy were prevailing at the time of phosphogenesis. Secular change ofδ~(13)C, δ~(18) O, ~(86)Sr/~(87)Sr values of carbonates from Sinian and Cambrian sequences were determined. A negative abnormal ofδ~(13)C, δ~(18)O values and positive abnormal of 86Sr/87Sr values from the fossiliferous section of the Lowest Cambrian Meishucun Formation implies life depopulation and following explosion of life across the PrecambriamCambrian boundary. Based on a lot of observations, this paper put forward a six-stage genetic model describing the whole formational process of industrial phosphorites: 1) Phosphorus was transported from continental weathering products and stored in the ocean; 2) dissolved phosphates in the seawater were enriched in specific deep seawater layer; 3) coastal upwelling currents took this phosphorus-rich seawater to a specific coastal area where phosphorus was captured by oceanic microbes; 4) clastic sediments in this upwelling area were enriched in phosphorus because of abundant phosphorus-rich organic matters and because of phosphorus absorption on grain surfaces; 5) during early diagenesis, the phosphorus enriched in the clastic sediments was released into interstitial water by decomposition and desorption, and then transported to the oxidation-reduction interface where authigenic phosphates were deposited and enriched; 6) such authigenic phosphate-rich layers were scoured, broken up, and winnowed in shallow-water environments resulting in phosphate enrichment. The Sinian-Cambrian phosphorites in South China are in many aspects comparable with coastal-upwelling phosphorites of younger geological ages, especially with phosphorites from modern coastal upwelling areas. That implies the similarities between the Sinian-Cambrian ocean and the modern ocean. Although Sinian-Cambrian oceanic life was much simpler than modern one, but similar oceanic planktons prevail, because oceanic planktons (particularly phytoplanktons) are crucial for phosphate enrichment related to coastal upwelling. It implies also a similar seawater-layering pattern between the Sinian-Cambrian ocean and the modern ocean. The two global phosphate-forming events and corresponding life-explosion events at the Sinian and Cambrian time probably resulted from dissolved-phosphate accumulation in seawater over a critical concentration during the Earth's evolution. Such an oceanic system with seawater phosphorus supersaturation is evidently unstable, and trends to return to normal state through phosphate deposition. Accordingly, this paper put forward a new conception of "normal state <=> phosphorus-supersaturation state" cycling of oceanic system. Such "normal state <=> phosphorus-supersaturation state" cycling was not only important for the three well-known global phosphate-forming events, also related to the critical moments of life evolution on the Earth. It might be of special significance. The favorable paleo-oceanic orientation in regard to coastal-upwelling phosphorite formation suggests a different orientation of the Yangtze Craton between the Sinian time and the present time (with a 135° clockwise difference), and a 25° anti-clockwise rotation of the Yangtze Craton from late Sinian to early Cambrian. During the Sinian-Cambrian time, the Yangtze Craton might be separated from the Cathaysia Block, but might be still associated with the North China Craton.

大别（超）包产到户铁岩和阜新火山岩铂族元素斌存规律研究

The platinum-group elements (PGE), including Os, Ir, Ru, Rh, Pt and Pd, axe strongly siderophile and chalcophile. On the basis of melting temperature, the PGE may be divided into two groups: the Ir group (IPGE, >2000°C) consisting of Os, Ir and Ru, and the Pd group (PPGE, <20GO°C) consisting of Rh, Pt and Pd. Because of their unique geochemical properties, PGE provide critical information on global-scale differentiation processes, such as core-mantle segregation, late accretionary history, and core-mantle exchange. In addition, they may be used to identify magma source regions and unravel complex petrogenetic processes including partial melting, melt percolation and metasomatism in the mantle, magma mixing and crustal contamination in magma chambers and melt crystallization.Compared with other rocks, (ultra)mafic rocks have lower REE content but higher PGE content, so PGE have advantages in studying the petrogeneses and evolution of them. In this study, we selected (ultra)mafic rocks collected in Dabie Orogen and volcanic rocks from Fuxin Region. Based on the distribution and behaviour of platinum-group elements, combined with other elements, we speculate the magma evolution and source mantle of these (ultra)mafic rocks and volcanic rocks.Many (ultra)mafic rocks are widely distributed in Dabie Region. According to their deformation and metamorphism, we classed them into three types. One is intrusive (ultra)mafic rocks, which are generally undeformed and show no or little sign of metamorphism, such as (ultra)mafic intrusions in Shacun, zhujiapu, Banzhufan, qingshan, Xiaohekou, Jiaoziyan, Renjiawan and Daoshichong. The other one is ultrahigh pressure metamorphic (ultra)mafic rocks, some of them appeared as eelogites, such as complex in Bixiling and adjacent Maowu. Another one is intense deformed and metamorphic, termed as tectonic slice, alpine-type (ultra)mafic rocks. The most representative is Raobazhai and Dahuapin. However, there are many controversies about the formation of those (ultra)mafic rocks. Here, we select typical rocks of the three types. The PGE were determined by inductively coupled plasma mass spectrometry (ICP-MS) ater NiS fire-assay and tellurium co-precipitation.The PGE tracing shows that three components are needed in the source of the cretaceous (uitra)mafic intrusions. They could be old enriched sub-continental lithospheric mantle, lower crust and depleted asthenospheric mantle. The pattern of PGE also shows the primitive magma of these intrusions underwent S saturation. According to palladium, we can conclude that the mantle enrich in PGE. Distribution of PGE in Bixiiing and Maowu (ultra)mafic rocks display they are products of magmas fractional crystallization. The (ultra)mafic rocks in Bixiiing and Maowu are controlled by various magmatic processes and the source mantle is depleted in PGE. Of interest is that the mantle produced UHP (ultra)mafic rocks are PGE-depleted, whereas the mantle of cretaceous (ultra)mafic intrusions are enrich in PGE. This couldindicate that the mantle change from PGE-enriched to PGE-depleted during120-OOMa, which in accord with the time of tectonic system change in the East China. At the same time, (ultra)mafic intrusions in cretaceous took information of deep mantle, which means the processes in deep mantle arose structural movement in the crust The character of PGE in alpine-type (ultra)mafic rocks declared that the rocks had experienced two types of metasomatic processes - hydrous melt derived from slab and silicate melt. In addition, we analyze the platinum-group elements in volcanic rocks on the northern margin of the North China Craton, Fuxin. The volcanic rocks characterized by negative anomalies of platinum. This indicates that platinum alloys, which may host some Pt resided in the mantle. The PGE patterns also show that Jianguo alkali basalts derived from asthenospheric mantle source, but wulahada high-Mg andesites derived from lithospheric mantle.

华北北缘斜长角闪岩的部分熔融实验及其地质意义

基性岩类的（脱水）部分熔融实验是研究地球内部中酸性岩浆（熔体）形成的重要实验方法，自二十世纪70年代以来越来越受到地质学家的高度重视。华北北缘广泛分布的中生代埃达克质岩石的成因，十几年来引起国内外学者的激烈争论，至今仍没有定论。近年来的研究表明张家口地区同时出露的古老太古宙中基性下地壳岩石、中生代中酸性埃达克质岩浆岩以及汉诺坝基性麻粒岩包体等可能反映了源岩和熔融产物的综合信息，这为我们运用实验岩石学手段研究华北北缘埃达克质岩石成因提供了非常理想的条件。 本文在1.5-2.0GPa，800-1000℃条件下，对采自华北北缘的斜长角闪岩同时进行了块状与粉末状两种样品的部分熔融实验研究，利用电子探针对各实验产物进行了主量元素分析以及利用LA-ICP-MS对部分熔体进行了微量元素测试，进而比较了相同条件下块状和粉末状样品的熔融特征，并对比了实验获得的熔体与华北北缘中生代埃达克质岩石的地球化学特征，同时也将实验获得的残留体与汉诺坝基性麻粒岩包体进行了比较。获得以下主要认识： （1）相同的温度、压力和恒温时间条件下块状样品的熔融温度比粉末样品的更低。在1.5-2.0GPa，800℃时块状斜长角闪岩样品已经发生部分融融，而相同条件下粉末样品中没有观察到熔体，粉末样品的部分熔融发生在850℃左右。在850-1000℃温度范围内，相同条件下块状样品的熔体含量比粉末样品的熔体含量高出5-17vol.％，即相同条件下块状样品比粉末样品的熔融程度更高，说明块状样品更容易达到可以分凝形成岩浆的临界熔体分数（CMF），这可能暗示着自然界中的岩浆形成可能比以往通过粉末实验结果推测的更容易发生。此外，在较高的温度条件下（950-1000℃），块状样品与粉末样品的熔体在主量和微量元素上都具有大致相同的地球化学特征，可以认为二者在在岩石学应用上是等效的。 （2）1.5GPa下实验获得的熔体为花岗质－花岗闪长质熔体，850-1000℃熔体的主-微量元素的地球化学特征与华北北缘中生代埃达克质岩石的整体特征具有很好的相似性，并与实验原岩产地张家口地区的三个典型中酸性埃达克质岩体的地球化学特征类似。可以认为实验的斜长角闪岩在1.5GPa下部分熔融能够形成华北北缘中生代埃达克质岩石。2.0GPa下的实验熔体为花岗质－奥长花岗质成分，其主量和微量元素特征均与华北北缘埃达克质岩石存在较大的差别，说明该压力下不能够形成华北北缘埃达克质岩石。 （3）实验残留相主要组成为Hb+Cpx+Gt±Pl，相当于麻粒岩相或榴辉岩相的矿物组合。与汉诺坝基性麻粒岩包体的典型矿物组合Cpx+Opx+Pl存在较大差别，在化学成分上，残留相比麻粒岩包体也整体上富Fe、Al，而贫Mg、Ca。综合来看汉诺坝基性麻粒岩包体可能是多种源岩在相对低压的条件下经过多期部分熔融综合作用的结果，本次实验的原岩及条件难以完全解释其复杂的成因。 另外，针对实验熔体和华北北缘埃达克质岩石之间的一些差异，不排除可能同时存在其他与之类似的源岩，成分上具有相对富Mg、Ca而贫Fe、Al，以及不同程度的Th、U、Zr、Hf富集等特征，与斜长角闪岩一起部分熔融，共同形成中生代华北北缘的中酸性埃达克质岩石。

扬子地块西南缘卡林型金矿床成矿流体地球化学研究

扬子地块西南缘是中国甚至世界上独特的、大面积分布的低温热液矿床矿集区,广泛发育Au、Ag、Hg、Sb、As、U、Cu、Pb-Zn以及重晶石、萤石、冰洲石等低温热液矿床,其中不少矿床属大型-超大型矿床规模.以沉积岩为容矿岩石的卡林型金矿(又称微细浸染型金矿),则是该区重要的矿产类型.目前已发现烂泥沟、紫木凼、戈塘、金牙、高龙等大、中型卡林型金矿床6个,小型矿床、矿点(矿化点)近200余处.主要集中分布在黔西南、滇东南和桂西北的交界地区,周边被深(大)断裂带所限,大体呈三角形,俗称"金三角".首先对该区众多的基性-超基性岩浆岩的同位素年代学及其反映的地质背景进行了较系统的研究,选择革挡和八渡(D)、纳哥(P)、烂泥沟和丫他(T)等代表性金矿床,进行了系统的流体包裹体岩相学、显微测温学、单个包裹体的激光Raman、流体包裹体群中的微量元素以及Rb-Sr、He-Ar、同位素组成等研究,获得了大量数据,并拍摄了大量包裹体照片(约400张).该次对该区卡林型金矿成矿流体地球化学的研究,作者认为在以下方面取得一定进展:(1)发现(或证实)了该区卡林型金矿富含C0<,2>相包裹体,并且种类众多,提出了卡林型金矿的成矿作用,经历了流体不混溶的过程(沸腾作用):(2)进一步证实了有机质参与卡林型金矿的成矿过程:(3)证实了盆地超压流体的存在,并提出了卡林型金矿的大规模成矿作用是"盆地超压流体-矿源岩-盆地伸展"耦合的观点.