Termination of diamond surfaces with hydrogen, oxygen and fluorine using a small, simple plasma gun

We have formed and characterized polycrystalline diamond films with surfaces having hydrogen terminations, oxygen terminations, or fluorine terminations, using a small, simple and novel plasma gun to bombard the diamond surface, formed by plasma assisted CVD in a prior step, with ions of the wanted terminating species. The potential differences between surface regions with different terminations were measured by Kelvin Force Microscopy (KFM). The highest potential occurred for oxygen termination regions and the lowest for fluorine. The potential difference between regions with oxygen terminations and hydrogen terminations was about 80 mV, and between regions with hydrogen terminations and fluorine terminations about 150 mV. Regions with different terminations were identified and imaged using the secondary electron signal provided by scanning electron microscopy (SEM). since this signal presents contrast for surfaces with different electrical properties. The wettability of the surfaces with different terminations was evaluated, measuring contact angles. The sample with oxygen termination was the most hydrophilic, with a contact angle of 75 degrees. hydrogen-terminated regions with 83 degrees, and fluorine regions 93 degrees, the most hydrophobic sample. (C) 2010 Elsevier B.V. All rights reserved.

Efeito do campo elétrico em nanocones formados por aln e BN: um estudo por primeiros princípios

The development of computers and algorithms capable of making increasingly accurate and rapid calculations as well as the theoretic foundation provided by quantum mechanics has turned computer simulation into a valuable research tool. The importance of such a tool is due to its success in describing the physical and chemical properties of materials. One way of modifying the electronic properties of a given material is by applying an electric field. These effects are interesting in nanocones because their stability and geometric structure make them promising candidates for electron emission devices. In our study we calculated the first principles based on the density functional theory as implemented in the SIESTA code. We investigated aluminum nitride (AlN), boron nitride (BN) and carbon (C), subjected to external parallel electric field, perpendicular to their main axis. We discuss stability in terms of formation energy, using the chemical potential approach. We also analyze the electronic properties of these nanocones and show that in some cases the perpendicular electric field provokes a greater gap reduction when compared to the parallel field

Spectroscopic study of lanthanide squarate hydrates

In the present investigation some spectroscopic properties of several lanthanide squarate hydrates are reported. The Raman spectra show the same distinctive Jahn-Teller intensity pattern for non-totally symmetric modes, as previously observed for the free anion. In the case of the terbium salt, the Tb3+ emission is very intense even at room temperature, revealing an efficient excitation via the ligand electronic levels. The Tb3+ dilution in Gd3+ or La3+ hosts increases this excitation efficiency without any appreciable variation in the 5D4 excited-state lifetime. However, the Eu3+ emission is very weak, with excited states located above the 5D2 level (ca. 21 550 cm-1) being completely quenched at room temperature. At lower temperatures higher-lying levels are not so efficiently quenched. The broad band observed in the UV excitation spectra of Eu3+ and Tb3+ is easily assigned to an intra-ligand transition leading to ligand-to-lanthanide ion energy transfer processes. As observed for Tb3+, Eu3+ dilution in Gd3+ or La3+ hosts also increases the relative emission intensity mediated by the ligand, without variation in the 5D0 excited-state lifetime. The Eu3+ 5D0 excitation spectra show vibronic structures that can be interpreted on the basis of the data available from the vibrational spectra. An increase in the vibronic intensities is observed as the lanthanide concentration is increased. © 1994.

Optical transition probabilities and compositional dependence of Judd-Ofelt parameters of Er3+ ions in fluoroindate glass

Fluoroindate glasses containing 1, 2, 3, and 4 mol% ErF3 were prepared in a dry box under an argon atmosphere. Absorption spectra of these glasses at room temperature were obtained. The Judd-Ofelt parameters Ωλ (λ = 2, 4, 6) for f-f transitions of Er3+ ions as well as transition probabilities, branching ratios, radiative lifetimes, and peak cross-sections for stimulated emission of each band were determined. The concentration effect on the intensities is analyzed. The optical properties of the fluoroindate glasses doped with Er3+ ions are compared with those of other glasses described in the literature. © 1995.

Spectroscopic, morphological and electrochromic characterization of layer-by-layer hybrid films of polyaniline and hexaniobate nanoscrolls

The combination of semiconducting oxides and polyaniline in the nanoscale range may result in hybrid materials having enhanced properties, such as electrochromism and charge capacity. This paper reports the spectroscopic, morphological and electrochromic characterization of hybrid films made up of hexaniobate one-dimensional (1D) nanoscrolls and polyaniline prepared by the layer-by-layer assembly technique (LbL). Secondary electron imaging and backscattered electron imaging techniques performed using a scanning electron microscope showed that polyaniline is adsorbed on the hexaniobate nanoscrolls, which confirms the combination of the components in the nanoscale domain. UV-VIS-NIR electronic spectra of the LbL hybrid films showed the absorption tail in the NIR region, assigned to delocalized polarons of the polyaniline. Resonance Raman spectra in the 1000-1700 cm(-1) range indicated that hybrid films present a higher relative intensity of polaron bands at 1337 and 1508 cm(-1) than pristine polyaniline in the emeraldine salt form. These results suggest that hexaniobate nanoscrolls induce a secondary doping of polyaniline. The cyclic voltammetry (CV) data for the hybrid film showed a specific capacity of 870 C cm(-3). According to CV results, the synergistic effect on charge storage properties of the hybrid material is attributed to the enhanced electroactivity of the hexaniobate component in the LbL film. Spectroelectrochemical experiments showed that the electrochromic efficiencies at 420 nm are ca. -41 and 24 cm(2) C-1 as the potential changes from 0.8 to -0.9 V and from -0.9 to -1.8 V, respectively, whereas at 800 nm the efficiencies are ca. -55 and 8 cm(2) C-1 for the same potential ranges. The electrochromic efficiencies and multi-colour character of the LbL film of hexaniobate nanoscrolls and polyaniline indicate that this novel hybrid material is an interesting modified electrode for electrochromic devices.

Nahfeld-induzierte Elektronenemissions-Mikrospektroskopie an stark gekoppelten Plasmonen und metallischen Mikrostrukturen

Plasmonen stellen elektromagnetische Moden in metallischen Strukturen dar, in denen die quasifreien Elektronen im Metall kollektiv oszillieren. Während des letzten Jahrzehnts erfuhr das Gebiet der Plasmonik eine rasante Entwicklung, basierend auf zunehmenden Fortschritten der Nanostrukturierungsmethoden und spektroskopischen Untersuchungsmethoden, die zu der Möglichkeit von systematischen Einzelobjektuntersuchungen wohldefinierter Nanostrukturen führte. Die Anregung von Plasmonen resultiert neben einer radiativen Verstärkung der optischen Streuintensität im Fernfeld in einer nicht-radiativen Überhöhung der Feldstärke in unmittelbarer Umgebung der metallischen Struktur (Nahfeld), die durch die kohärente Ladungsansammlung an der metallischen Oberfläche hervorgerufen wird. Das optische Nahfeld stellt folglich eine bedeutende Größe für das fundamentale Verständnis der Wirkung und Wechselwirkung von Plasmonen sowie für die Optimierung plasmonbasierter Applikationen dar. Die große Herausforderung liegt in der Kompliziertheit des experimentellen Zugangs zum Nahfeld, der die Entwicklung eines grundlegenden Verständisses des Nahfeldes verhinderte.rnIm Rahmen dieser Arbeit wurde Photoemissionselektronenmikroskopie (PEEM) bzw. -mikrospektroskopie genutzt, um ortsaufgelöst die Eigenschaften nahfeld-induzierter Elektronenemission zu bestimmen. Die elektrodynamischen Eigenschaften der untersuchten Systeme wurden zudem mit numerischen, auf der Finiten Integrationsmethode basierenden Berechnungen bestimmt und mit den experimentellen Resultaten verglichen.rnAg-Scheiben mit einem Durchmesser von 1µm und einer Höhe von 50nm wurden mit fs-Laserstrahlung der Wellenlänge 400nm unter verschiedenen Polarisationszuständen angeregt. Die laterale Verteilung der infolge eines 2PPE-Prozesses emittierten Elektronen wurde mit dem PEEM aufgenommen. Aus dem Vergleich mit den numerischen Berechnungen lässt sich folgern, dass sich das Nahfeld an unterschiedlichen Stellen der metallischen Struktur verschiedenartig ausbildet. Insbesondere wird am Rand der Scheibe bei s-polarisierter Anregung (verschwindende Vertikalkomponente des elektrischen Felds) ein Nahfeld mit endlicher z-Komponente induziert, während im Zentrum der Scheibe das Nahfeld stets proportional zum einfallenden elektrischen Feld ist.rnWeiterhin wurde erstmalig das Nahfeld optisch angeregter, stark gekoppelter Plasmonen spektral (750-850nm) untersucht und für identische Nanoobjekte mit den entsprechenden Fernfeldspektren verglichen. Dies erfolgte durch Messung der spektralen Streucharakteristik der Einzelobjekte mit einem Dunkelfeldkonfokalmikroskop. Als Modellsystem stark gekoppelter Plasmonen dienten Au Nanopartikel in sub-Nanometerabstand zu einem Au Film (nanoparticle on plane, NPOP). Mit Hilfe dieser Kombination aus komplementären Untersuchungsmethoden konnte erstmalig die spektrale Trennung von radiativen und nicht-radiativen Moden stark gekoppelter Plasmonen nachgewiesen werden. Dies ist insbesondere für Anwendungen von großer Relevanz, da reine Nahfeldmoden durch den unterdrückten radiativen Zerfall eine große Lebensdauer besitzen, so dass deren Verstärkungswirkung besonders lange nutzbar ist. Ursachen für die Unterschiede im spektralen Verhalten von Fern- und Nahfeld konnten durch numerische Berechnungen identifiziert werden. Sie zeigten, dass das Nahfeld nicht-spärischer NPOPs durch die komplexe Oszillationsbewegung der Elektronen innerhalb des Spaltes zwischen Partikel und Film stark ortsabhängig ist. Zudem reagiert das Nahfeld stark gekoppelter Plasmonen deutlich empfindlicher auf strukturelle Störstellen des Resonators als die Fernfeld-Response. Ferner wurde der Elektronenemissionsmechanismus als optischer Feldemissionsprozess identifiziert. Um den Vorgang beschreiben zu können, wurde die Fowler-Nordheim Theorie der statischen Feldemission für den Fall harmonisch oszillierender Felder modifiziert.

Radiocarbon ages, diatom abundance and laminae description of sediment core MD03-2597

Laminated sediments are unique archives of palaeoenvironmental and palaeoceanographic conditions, recording changes on seasonal and interannual timescales. Diatom-rich laminated marine sediments are examined from Dumont d'Urville Trough, East Antarctic Margin, to determine changes in environmental conditions on the continental shelf from 1136 to 3122 cal. yr BP. Scanning electron microscope backscattered electron imagery (BSEI) and secondary electron imagery are used to analyse diatom assemblages from laminations and to determine interlamina relationships. Diatom observations are quantified with conventional assemblage counts. Laminae are primarily classified according to visually dominant species identified in BSEI and, secondarily, by terrigenous content. Nine lamina types are identified and are characterized by: Hyalochaete Chaetoceros spp. resting spores (CRS); CRS and Fragilariopsis spp.; Fragilariopsis spp.; Corethron pennatum and Rhizosolenia spp.; C. pennatum; Rhizosolenia spp.; mixed diatom assemblage; Stellarima microtrias resting spores (RS), Porosira glacialis RS and Coscinodiscus bouvet; and P. glacialis RS. Formation of each lamina type is controlled by seasonal changes in sea ice cover, nutrient levels and water column stability. Quantitative diatom assemblage analysis revealed that each lamina type is dominated by CRS and Fragilariopsis sea ice taxa, indicating that sea ice cover was extensive and persistent in the late Holocene. However the lamina types indicate that the sea ice regime was not consistent throughout this period, notably that a relatively warmer period, ~3100 to 2500 cal. yr BP, was followed by cooling which resulted in an increase in year round sea ice by ~1100 cal. yr BP.

Application of digital image correlation at the microscale in fiber-reinforced composites

Digital image correlation (DIC) is applied to analyzing the deformation mechanisms under transverse compression in a fiber-reinforced composite. To this end, compression tests in a direction perpendicular to the fibers were carried out inside a scanning electron microscope and secondary electron images obtained at different magnifications during the test. Optimum DIC parameters to resolve the displacement and strain field were computed from numerical simulations of a model composite and they were applied to micrographs obtained at different magnifications (250_, 2000_, and 6000_). It is shown that DIC of low-magnification micrographs was able to capture the long range fluctuations in strain due to the presence of matrix-rich and fiber-rich zones, responsible for the onset of damage. At higher magnification, the strain fields obtained with DIC qualitatively reproduce the non-homogeneous deformation pattern due to the presence of stiff fibers dispersed in a compliant matrix and provide accurate results of the average composite strain. However, comparison with finite element simulations revealed that DIC was not able to accurately capture the average strain in each phase.

Thermal, stress, and traps effects in AlGaN/GaN HEMTs

GaN y AlN son materiales semiconductores piezoeléctricos del grupo III-V. La heterounión AlGaN/GaN presenta una elevada carga de polarización tanto piezoeléctrica como espontánea en la intercara, lo que genera en su cercanía un 2DEG de grandes concentración y movilidad. Este 2DEG produce una muy alta potencia de salida, que a su vez genera una elevada temperatura de red. Las tensiones de puerta y drenador provocan un stress piezoeléctrico inverso, que puede afectar a la carga de polarización piezoeléctrica y así influir la densidad 2DEG y las características de salida. Por tanto, la física del dispositivo es relevante para todos sus aspectos eléctricos, térmicos y mecánicos. En esta tesis se utiliza el software comercial COMSOL, basado en el método de elementos finitos (FEM), para simular el comportamiento integral electro-térmico, electro-mecánico y electro-térmico-mecánico de los HEMTs de GaN. Las partes de acoplamiento incluyen el modelo de deriva y difusión para el transporte electrónico, la conducción térmica y el efecto piezoeléctrico. Mediante simulaciones y algunas caracterizaciones experimentales de los dispositivos, hemos analizado los efectos térmicos, de deformación y de trampas. Se ha estudiado el impacto de la geometría del dispositivo en su auto-calentamiento mediante simulaciones electro-térmicas y algunas caracterizaciones eléctricas. Entre los resultados más sobresalientes, encontramos que para la misma potencia de salida la distancia entre los contactos de puerta y drenador influye en generación de calor en el canal, y así en su temperatura. El diamante posee une elevada conductividad térmica. Integrando el diamante en el dispositivo se puede dispersar el calor producido y así reducir el auto-calentamiento, al respecto de lo cual se han realizado diversas simulaciones electro-térmicas. Si la integración del diamante es en la parte superior del transistor, los factores determinantes para la capacidad disipadora son el espesor de la capa de diamante, su conductividad térmica y su distancia a la fuente de calor. Este procedimiento de disipación superior también puede reducir el impacto de la barrera térmica de intercara entre la capa adaptadora (buffer) y el substrato. La muy reducida conductividad eléctrica del diamante permite que pueda contactar directamente el metal de puerta (muy cercano a la fuente de calor), lo que resulta muy conveniente para reducir el auto-calentamiento del dispositivo con polarización pulsada. Por otra parte se simuló el dispositivo con diamante depositado en surcos atacados sobre el sustrato como caminos de disipación de calor (disipador posterior). Aquí aparece una competencia de factores que influyen en la capacidad de disipación, a saber, el surco atacado contribuye a aumentar la temperatura del dispositivo debido al pequeño tamaño del disipador, mientras que el diamante disminuiría esa temperatura gracias a su elevada conductividad térmica. Por tanto, se precisan capas de diamante relativamente gruesas para reducer ele efecto de auto-calentamiento. Se comparó la simulación de la deformación local en el borde de la puerta del lado cercano al drenador con estructuras de puerta estándar y con field plate, que podrían ser muy relevantes respecto a fallos mecánicos del dispositivo. Otras simulaciones se enfocaron al efecto de la deformación intrínseca de la capa de diamante en el comportamiento eléctrico del dispositivo. Se han comparado los resultados de las simulaciones de la deformación y las características eléctricas de salida con datos experimentales obtenidos por espectroscopía micro-Raman y medidas eléctricas, respectivamente. Los resultados muestran el stress intrínseco en la capa producido por la distribución no uniforme del 2DEG en el canal y la región de acceso. Además de aumentar la potencia de salida del dispositivo, la deformación intrínseca en la capa de diamante podría mejorar la fiabilidad del dispositivo modulando la deformación local en el borde de la puerta del lado del drenador. Finalmente, también se han simulado en este trabajo los efectos de trampas localizados en la superficie, el buffer y la barrera. Las medidas pulsadas muestran que tanto las puertas largas como las grandes separaciones entre los contactos de puerta y drenador aumentan el cociente entre la corriente pulsada frente a la corriente continua (lag ratio), es decir, disminuir el colapse de corriente (current collapse). Este efecto ha sido explicado mediante las simulaciones de los efectos de trampa de superficie. Por su parte, las referidas a trampas en el buffer se enfocaron en los efectos de atrapamiento dinámico, y su impacto en el auto-calentamiento del dispositivo. Se presenta también un modelo que describe el atrapamiento y liberación de trampas en la barrera: mientras que el atrapamiento se debe a un túnel directo del electrón desde el metal de puerta, el desatrapamiento consiste en la emisión del electrón en la banda de conducción mediante túnel asistido por fonones. El modelo también simula la corriente de puerta, debida a la emisión electrónica dependiente de la temperatura y el campo eléctrico. Además, también se ilustra la corriente de drenador dependiente de la temperatura y el campo eléctrico. ABSTRACT GaN and AlN are group III-V piezoelectric semiconductor materials. The AlGaN/GaN heterojunction presents large piezoelectric and spontaneous polarization charge at the interface, leading to high 2DEG density close to the interface. A high power output would be obtained due to the high 2DEG density and mobility, which leads to elevated lattice temperature. The gate and drain biases induce converse piezoelectric stress that can influence the piezoelectric polarization charge and further influence the 2DEG density and output characteristics. Therefore, the device physics is relevant to all the electrical, thermal, and mechanical aspects. In this dissertation, by using the commercial finite-element-method (FEM) software COMSOL, we achieved the GaN HEMTs simulation with electro-thermal, electro-mechanical, and electro-thermo-mechanical full coupling. The coupling parts include the drift-diffusion model for the electron transport, the thermal conduction, and the piezoelectric effect. By simulations and some experimental characterizations, we have studied the device thermal, stress, and traps effects described in the following. The device geometry impact on the self-heating was studied by electro-thermal simulations and electrical characterizations. Among the obtained interesting results, we found that, for same power output, the distance between the gate and drain contact can influence distribution of the heat generation in the channel and thus influence the channel temperature. Diamond possesses high thermal conductivity. Integrated diamond with the device can spread the generated heat and thus potentially reduce the device self-heating effect. Electro-thermal simulations on this topic were performed. For the diamond integration on top of the device (top-side heat spreading), the determinant factors for the heat spreading ability are the diamond thickness, its thermal conductivity, and its distance to the heat source. The top-side heat spreading can also reduce the impact of thermal boundary resistance between the buffer and the substrate on the device thermal behavior. The very low electrical conductivity of diamond allows that it can directly contact the gate metal (which is very close to the heat source), being quite convenient to reduce the self-heating for the device under pulsed bias. Also, the diamond coated in vias etched in the substrate as heat spreading path (back-side heat spreading) was simulated. A competing mechanism influences the heat spreading ability, i.e., the etched vias would increase the device temperature due to the reduced heat sink while the coated diamond would decrease the device temperature due to its higher thermal conductivity. Therefore, relative thick coated diamond is needed in order to reduce the self-heating effect. The simulated local stress at the gate edge of the drain side for the device with standard and field plate gate structure were compared, which would be relevant to the device mechanical failure. Other stress simulations focused on the intrinsic stress in the diamond capping layer impact on the device electrical behaviors. The simulated stress and electrical output characteristics were compared to experimental data obtained by micro-Raman spectroscopy and electrical characterization, respectively. Results showed that the intrinsic stress in the capping layer caused the non-uniform distribution of 2DEG in the channel and the access region. Besides the enhancement of the device power output, intrinsic stress in the capping layer can potentially improve the device reliability by modulating the local stress at the gate edge of the drain side. Finally, the surface, buffer, and barrier traps effects were simulated in this work. Pulsed measurements showed that long gates and distances between gate and drain contact can increase the gate lag ratio (decrease the current collapse). This was explained by simulations on the surface traps effect. The simulations on buffer traps effects focused on illustrating the dynamic trapping/detrapping in the buffer and the self-heating impact on the device transient drain current. A model was presented to describe the trapping and detrapping in the barrier. The trapping was the electron direct tunneling from the gate metal while the detrapping was the electron emission into the conduction band described by phonon-assisted tunneling. The reverse gate current was simulated based on this model, whose mechanism can be attributed to the temperature and electric field dependent electron emission in the barrier. Furthermore, the mechanism of the device bias via the self-heating and electric field impact on the electron emission and the transient drain current were also illustrated.

Diagnostics of classical and dusty plasmas w ith collecting and emissive langmuir probes = Diagnosis de plasmas clásicos y granulares mediante sondas colectoras y emisoras de Langmuir

Las sondas eléctricas se emplean habitualmente en la diagnosis de plasmas. La presente tesis aborda la operación de las sondas colectoras y emisoras de Langmuir en plasmas fríos de baja densidad. El estudio se ha centrado en la determinación del potencial de plasma, Vsp, mediante el potencial flotante de una sonda emisora. Esta técnica consiste en la medida del potencial de la sonda correspondiente a la condición de corriente neta igual a cero, el cual se denomina potencial flotante, VF. Este potencial se desplaza hacia el potencial del plasma según aumenta la emisión termoiónica de la sonda, hasta que se satura cerca de Vsp. Los experimentos llevados a cabo en la pluma de plasma de un motor iónico y en un plasma de descarga de glow muestran que la corriente de electrones termoiónicos es mayor que la corriente de electrones recogidos para una sonda polarizada por debajo del potencial del plasma, resultado inconsistente con la teoría tradicionalmente aceptada. Para investigar estos resultados se ha introducido el parámetro R, definido como el cociente entre la corriente de electrones emitidos y recogidos por la sonda. Este parámetro, que está relacionado con la diferencia de potencial VF - Vsp, también es útil para la descripción de los modos de operación de la sonda emisora (débil, fuerte y más allá del fuerte). Los resultados experimentales evidencian que, al contrario de lo que indica la teoría, R es mayor que la unidad. Esta discrepancia se puede solucionar introduciendo una población efectiva de electrones. Con dicha población, el nuevo modelo para la corriente total de la sonda reproduce los datos experimentales. El origen de este grupo electrónico es todavía una cuestión abierta, pero podría estar originada por una nueva estructura de potencial cerca de la sonda cuando ésta trabaja en el régimen de emisión fuerte. Para explicar dicha estructura de potencial, se propone un modelo unidimensional compuesto por un mínimo de potencial cerca de la superficie de la sonda. El análisis numérico indica que este pozo de potencial aparece para muy altas temperaturas de la sonda, reduciendo la cantidad de electrones emitidos que alcanzan el plasma y evitando así cualquier posible perturbación de éste. Los aspectos experimentales involucrados en el método del potencial flotante también se han estudiado, incluyendo cuestiones como las diferentes técnicas de obtención del VF, el cociente señal-ruido, el acoplamiento de la señal de los equipos utilizados para la obtención de las curvas I-V o la evidencia experimental de los diferentes modos de operación de la sonda. Estas evidencias empíricas se encuentran en todos los aspectos de operación de la sonda: la recolección de electrones, el potencial flotante, la precisión en las curvas I-V y la emisión electrónica. Ésta última también se estudia en la tesis, debido a que un fenómeno de super emisión tiene lugar en el régimen de emisión fuerte. En este modo de operación, las medidas experimentales indican que las corrientes termoiónicas de electrones son mayores que aquéllas predichas por la ecuación de Richardson-Dushman clásica. Por último, la diagnosis de plasmas usando sondas eléctrica bajo presencia de granos de polvo (plasmas granulares) en plasmas fríos de baja densidad también se ha estudiado, mediante la aplicación numérica de la técnica del potencial flotante de la sonda emisora en un plasma no convencional. Los resultados apuntan a que el potencial flotante de una sonda emisora se vería afectado por altas densidades de polvo o grandes partículas. ABSTRACT Electric probes are widely employed for plasma diagnostics. This dissertation concerns the operation of collecting and emissive Langmuir probes in low density cold plasmas. The study is focused on the determination of the plasma potential, Vsp, by means of the floating potential of emissive probes. This technique consists of the measurement of the probe potential, corresponding to the zero net probe current, which is the so-called floating potential, VF . This potential displaces towards the plasma potential as the thermionic electron emission increases, until it saturates near Vsp. Experiments carried out in the plasma plume of an ion thruster and in a glow discharge plasma show the thermionic electron current of the emissive Langmuir probe is higher than the collected electron current, for a probe with a bias potential below Vsp, which is inconsistent with the traditional accepted theory. To investigate these results, a parameter R is introduced as the ratio between the emitted and the collected electron current. This parameter, which is related to the difference VF - Vsp, is also useful for the description of the operation modes of the emissive Langmuir probe (weak, strong and beyond strong). The experimental results give an inconsistency of R > 1, which is solved by a modification of the theory for emissive probes, with the introduction of an effective electron population. With this new electron group, the new model for the total probe current agrees with the experimental data. The origin of this electron group remains an open question, but it might be originated by a new potential structure near the emissive probe when it operates in the strong emission regime. A simple one-dimension model composed by a minimum of potential near the probe surface is discussed for strongly emitting emissive probes. The results indicate that this complex potential structure appears for very high probe temperatures and the potential well might reduce the emitted electrons population reaching the plasma bulk. The experimental issues involved in the floating potential method are also studied, as the different obtaining techniques of VF, the signal-to-noise ratio, the signal coupling of the I-V curve measurement system or the experimental evidence of the probe operation modes. These empirical proofs concern all the probe operation aspects: the electron collection, the floating potential, the I-V curve accuracy as well as the electron emission. This last issue is also investigated in this dissertation, because a super emission takes place in the strong emission regime. In this operation mode, the experimental results indicate that the thermionic electron currents might be higher than those predicted by the classical Richardson-Dushman equation. Finally, plasma diagnosis using electric probes in the presence of dust grains (dusty plasmas) in low density cold plasmas is also addressed. The application of the floating potential technique of the emissive probe in a non-conventional complex plasma is numerically investigated, whose results point out the floating potential of the emissive probe might be shifted for high dust density or large dust particles.

Estudio de los materiales que componen el sistema constructivo de las viviendas del casco histórico de Maracaibo (Venezuela)

En este trabajo de investigación que se presenta para optar al grado de Doctor, se analizan y estudian los materiales que conforman las viviendas de mampostería de arenisca “Piedra de Ojo” del casco histórico de Maracaibo, Venezuela, construidas en el siglo XIX. No existe una bibliografía descriptiva técnico-constructiva del sistema constructivo, por lo que esta tesis complementa la escasa descripción estilística existente donde apenas se mencionan algunos materiales de construcción. Definido el marco histórico y las manzanas del área en donde se encontraban las viviendas preseleccionadas a estudiar, en la visita de campo se seleccionaron 12 que se encontraban en estado de deterioro, y que permitieron recolectar las muestras más fácilmente. Para realizar la caracterización y comportamientos de los diferentes materiales utilizados: piedra y morteros en los cerramientos, maderas en armaduras de tejados, techos y carpintería de puertas y ventanas, cerámicos en muros y acabados, etc. Para complementar lo antes dicho se ha dividido esta tesis en seis capítulos: En el capítulo I se desarrolla el estado del arte a nivel nacional e internacional de trabajos de investigación, similares. Se aborda la memoria histórica, que es una reseña de la evolución de la vivienda en la ciudad de Maracaibo. En el capítulo II se describe la metodología empleada en la tesis, de acuerdo a los objetivos, tanto generales como específicos de la investigación. Que ha cubierto diferentes frentes: consulta bibliográfica, levantamiento planimétrico, toma de muestras, análisis de visu, caracterización físico-química y correlación de resultados. Se ha desarrollado el trabajo tanto in situ como en laboratorio y despacho. El capítulo III presenta la caracterización de la arenisca “Piedra de Ojo”, se desarrolla: la descripción geológica y caracterización petrológica. Se reseñan los ensayos realizados en laboratorio como: caracterización de visu, caracterización petrográfica, estudio petrográfico por microcopia óptica de trasmisión, estudio petrográfico por microcopia electrónica de barrido, microscopia electrónica de barrido en modo electrones secundarios (SSE) y microscopia electrónica de barrido en modo electrones retrodispersados. También las propiedades escalares de los mampuestos y los siguientes valores: densidades, porosidades y resistencia mecánicas, entre otros. En el capítulo IV se analizan las características de los morteros aplicados en las viviendas, y la patología o lesiones que presentan. Se clasifican en tres tipos: mortero de junta o asiento, de enfoscado y revoco. Se documenta la realización de los ensayos físicos y químicos, resistencia mecánica y de granulometría; se explican sus componentes principales: conglomerante de cal, áridos y aditivos y la tecnología de fabricación, así como las características físicas, hídricas, químicas y granulométricas. El capítulo V, contiene las aplicaciones constructivas de los materiales de albañilería, Se describen otros elementos de la vivienda como; cimentaciones, muros mixtos, molduras, apliques y pinturas y finalmente pavimentos. Y en el capítulo VI se analizan las especies de madera más representativas usadas en las armaduras de las cubiertas, así como los elementos de cubrición. De igual forma se describe la carpintería de puertas y ventanas, así como sus dinteles o cargaderos de madera y se realiza la identificación anatómica, las propiedades físicas y mecánicas de las utilizadas. Entre los resultados y conclusiones se determinó que el 90% de los materiales utilizados en su construcción proceden de zonas cercanas a la construcción de la vivienda, como la formación El Milagro convertida en cantera de piedra y que el resto de los materiales provenían de la Isla de Toas y de la exportación de las islas del Caribe y de Europa como el cemento. El principal aporte de esta investigación es el análisis técnico constructivo y la caracterización física, mecánica y química de los materiales de la vivienda, con el fin de que dicha información sea usada para definir los materiales nuevos a utilizar en las restauraciones de las viviendas y en futuras líneas de investigación. ABSTRACT In this research paper submitted to opt to the degree of Doctor, the materials that make the “Piedra de Ojo” sandstone masonry houses of the historical center of Maracaibo, Venezuela, built in the XIX century, are analyzed and studied. There exists no technical-constructive descriptive literature of the constructive system, so this thesis complements the very limited existing stylistic description, where barely some construction materials are mentioned. With the historical context and the blocks of the area where the preselected houses to be studied being defined, 12 of these houses that were in a state of decay (deterioration) were selected and this condition allowed to collect samples more easily, in order to carry out the characterization and behavior of the different materials used: stone and mortars in the walls, wood trusses in roofs, ceilings and woodwork of doors and windows, walls and ceramic finishes, etc. To complement the foregoing, this thesis has been divided in six chapters: In Chapter I, the state of art at national and international levels of similar research is developed, which is a review of the evolution of housing in the city of Maracaibo. In Chapter II, the methodology used in the thesis is described, according to the research’s objectives, general and specific ones, which have covered several fronts: literature survey, planimetric survey, sampling, visu analysis, physical-chemical characterization and correlation of results. Chapter III presents the characterization of the “Piedra de Ojo” sandstone; geological description and petrologic characterization are developed. Essays performed in the laboratory are reviewed, such as: visu characterization, petrographic characaterization, petrographic study by optical microscopy of transmission, petrographic study by electronic scanning microscopy in secondary electron mode (SSE) and electron microscopy scaning by backscattered electron mode. Also scalar properties of the masonry and the following: density, porosity and mechanical resistance, among others. In Chapter IV, characteristics of the mortars used in the houses are analyzed and pathology or damages are presented. They are classified into three types: grout, cement render and plaster. Physical and chemical testing, mechanical strength and grain size (granulometric) is documented; its main components are explained: lime binder, aggregates and additives and manufacturing technology as well as the physical, water, chemical and granulometric characteristics. Chapter V contains the constructive applications of masonry materials. Other housing elements are described, such as; foundations, mixed walls, moldings, wall paintings and finally floorings (pavements). And in chapter VI the most representative species of wood used in the overhead fixtures and cover elements are analyzed. Likewise, woodwork of doors and windows and their wooden lintels or landings are described; anatomical identification and physical and mechanical properties of the ones used is made. The results and conclusions determined that 90% of the materials used in its construction came from areas near the construction of housing, such as El Milagro formation, converted into stone quarry and other materials came from the Toas Island and from the export of the Caribbean islands and Europe, such as cement. The main contribution of this research is the constructive technical analysis and physical, mechanical and chemical characterization of the materials of the houses, in order that such information is used to define the new materials to be used in the housing restoration and future research lines.

The fatigue properties of pressure diecast zinc-aluminium based alloys

The fatigue behaviour of the cold chamber pressure-die-cast alloys: Mazak3, ZA8, ZA27, M3K, ZA8K, ZA27K, K1, K2 and K3 was investigated at temperature of 20°C. The alloys M3K, ZA8K and ZA27K were also examined at temperatures of 50 and 100°C. The ratio between fatigue strength and tensile strength was established at 20°C at 107 cycles. The fatigue life prediction of the alloys M3K, ZA8K and ZA27K was formulated at 20, 50 and 100°C. The prediction formulae were found to be reasonably accurate. All of the experimental alloys were heterogeneous and contained large but varying amounts of pores. These pores were a major contribution and dominated the alloys fatigue failure. Their effect, however, on tensile failure was negligible. The ZA27K possessed the highest tensile strength but the lowest fatigue strength. The relationship between the fracture topography and the microstructure was also determined by the use of a mixed signal of a secondary electron and a back-scattered electron on the SEM. The tensile strength of the experimental alloys was directly proportional to the aluminium content within the alloys. The effect of copper content was also investigated within the alloys K1, K2, ZA8K and K3 which contained 0%, 0.5%, 1.0% and 2.0% respectively. It was determined that the fatigue and tensile strengths improved with higher copper contents. Upon ageing the alloys Mazak3, ZA8 and ZA27 at an ambient temperature for 5 years, copper was also found to influence and maintain the metastable Zn-Al (αm) phase. The copper free Mazak3 upon ageing lost this metastable phase. The 1.0% copper ZA8 alloy had lost almost 50% of its metastable phase. Finally the 2.0% copper ZA27 had merely lost 10% of its metastable phase. The cph zinc contained a limited number of slip systems, therefore twinning deformation was unavoidable in both fatigue and tensile testing.

Why is it possible to detect doped regions of semiconductors in low voltage SEM:a review and update

There is an urgent need for fast, non-destructive and quantitative two-dimensional dopant profiling of modern and future ultra large-scale semiconductor devices. The low voltage scanning electron microscope (LVSEM) has emerged to satisfy this need, in part, whereby it is possible to detect different secondary electron yield values (brightness in the SEM signal) from the p-type to the n-type doped regions as well as different brightness levels from the same dopant type. The mechanism that gives rise to such a secondary electron (SE) contrast effect is not fully understood, however. A review of the different models that have been proposed to explain this SE contrast is given. We report on new experiments that support the proposal that this contrast is due to the establishment of metal-to-semiconductor surface contacts. Further experiments showing the effect of instrument parameters including the electron dose, the scan speeds and the electron beam energy on the SE contrast are also reported. Preliminary results on the dependence of the SE contrast on the existence of a surface structure featuring metal-oxide semiconductor (MOS) are also reported. Copyright © 2005 John Wiley & Sons, Ltd.

Growth and characterization of anodic Films on InP in KOH and (NH4)2S

The current-voltage characteristics of InP were investigated in (NH4)2S and KOH electrolytes. In both solutions, the observation of current peaks in the cyclic voltammetric curves was attributed to the growth of passivating films. The relationship between the peak currents and the scan rates suggests that the film formation process is diffusion controlled in both cases. The film thickness required to inhibit current flow was found to be much lower on samples anodized in the sulphide solution. Focused ion beam (FIB) secondary electron images of the surface films show that film cracking of the type reported previously for films grown in (NH4)2S is also observed for films grown in KOH. X-ray and electron diffraction measurements indicate the presence of In2O3 and InPO4 in films grown in KOH and In2S3 in films grown in (NH4)2S.

The morphology of ordered block copolymer patterns as probed by high resolution imaging

The microphase separation of block copolymer (BCP) thin films can afford a simple and cost-effective means to studying nanopattern surfaces, and especially the fabrication of nanocircuitry. However, because of complex interface effects and other complications, their 3D morphology, which is often critical for application, can be more complex than first thought. Here, we describe how emerging microscopic methods may be used to study complex BCP patterns and reveal their rich detail. These methods include helium ion microscopy (HIM) and high resolution x-section transmission electron microscopy (XTEM), and complement conventional secondary electron and atomic force microscopies (SEM and TEM). These techniques reveal that these structures are quite different to what might be expected. We illustrate the advances in the understanding of BCP thin film morphology in several systems, which result from this characterization. The systems described include symmetric, lamellar forming polystyrene-b-polymethylmethacrylate (PS-b-PMMA), cylinder forming polystyrene-b-polydimethylsiloxane (PS-b-PDMS), as well as lamellar and cylinder forming patterns of polystyrene-b-polyethylene oxide (PS-b-PEO) and polystyrene-b-poly-4-vinylpyridine (PS-b-P4VP). Each of these systems exhibits more complex arrangements than might be first thought. Finding and developing techniques whereby complex morphologies, particularly at very small dimensions, can be determined is critical to the practical use of these materials in many applications. The importance of quantifying these complex morphologies has implications for their use in integrated circuit manufacture, where they are being explored as alternative pattern forming methods to conventional UV lithography.