Life cycle assessment of biodiesel production from micro-algae: a case study in Denmark

Le sperimentazioni riguardanti la produzione di biodiesel da alghe sono state condotte solo in laboratorio o in impianti pilota e il processo produttivo non è ancora stato sviluppato su scala industriale. L’obiettivo di questo lavoro di tesi è stato quello di valutare la potenziale sostenibilità ambientale ed energetica della produzione industriale di biodiesel da microalghe nella realtà danese ipotizzando la coltivazione in fotobioreattori. La tesi ha analizzato le diverse tecnologie attualmente in sperimentazione cercando di metterne in evidenza punti di forza e punti di debolezza. La metodologia applicata in questa tesi per valutare la sostenibilità ambientale ed energetica dei processi analizzati è LCA strumento che permette di effettuare la valutazione sull’intero ciclo di vita di un prodotto o di un processo. L’unità funzionale scelta è 1 MJ di biodiesel. I confini del sistema analizzato comprendono: coltivazione, raccolta, essicazione, estrazione dell’olio, transesterificazione, digestione anaerobica della biomassa residuale e uso del glicerolo ottenuto come sottoprodotto della transesterificazione. Diverse categorie d’impatto sono state analizzate. In questo caso studio, sono stati ipotizzati 24 diversi scenari differenziati in base alle modalità di coltivazione, di raccolta della biomassa, di estrazione dell’olio algale. 1. la produzione di biodiesel da microalghe coltivate in fotobioreattori non appare ancora conveniente né dal punto di vista energetico né da quello ambientale. 2. l’uso di CO2 di scarto e di acque reflue per la coltivazione, fra l’altro non ancora tecnicamente realizzabili, migliorerebbero le prestazioni energetiche ed ambientali del biodiesel da microalghe 3. la valorizzazione di prodotti secondari svolge un ruolo importante nel processo e nel suo sviluppo su larga scala Si conclude ricordando che il progetto di tesi è stato svolto in collaborazione con la Danish Technical University of Denmark (DTU) svolgendo presso tale università un periodo di tirocinio per tesi di sei mesi

Influence of beveling and ultrasound application on marginal adaptation of box-only Class II (slot) resin composite restorations

A laboratory study was performed to assess the influence of beveling the margins of cavities and the effects on marginal adaptation of the application of ultrasound during setting and initial light curing. After minimal access cavities had been prepared with an 80 microm diamond bur, 80 box-only Class II cavities were prepared mesially and distally in 40 extracted human molars using four different oscillating diamond coated instruments: (A) a U-shaped PCS insert as the non-beveled control (EMS), (B) Bevelshape (Intensiv), (C) SonicSys (KaVo) and (D) SuperPrep (KaVo). In groups B-D, the time taken for additional bevel finishing was measured. The cavities were filled with a hybrid composite material in three increments. Ultrasound was also applied to one cavity per tooth before and during initial light curing (10 seconds). The specimens were subjected to thermomechanical stress in a computer-controlled masticator device. Marginal quality was assessed by scanning electron microscopy and the results were compared statistically. The additional time required for finishing was B > D > C (p < or = 0.05). In all groups, thermomechanical loading resulted in a decrease in marginal quality. Beveling resulted in higher values for "continuous" margins compared with that of the unbeveled controls. The latter showed better marginal quality at the axial walls when ultrasound was used. Beveling seems essential for good marginal adaptation but requires more preparation time. The use of ultrasonic vibrations may improve the marginal quality of unbeveled fillings and warrants further investigation.

Study of and design procedure for dual circularly polarized waveguide slot arrays

For the past sixty years, waveguide slot radiator arrays have played a critical role in microwave radar and communication systems. They feature a well-characterized antenna element capable of direct integration into a low-loss feed structure with highly developed and inexpensive manufacturing processes. Waveguide slot radiators comprise some of the highest performance—in terms of side-lobe-level, efficiency, etc. — antenna arrays ever constructed. A wealth of information is available in the open literature regarding design procedures for linearly polarized waveguide slots. By contrast, despite their presence in some of the earliest published reports, little has been presented to date on array designs for circularly polarized (CP) waveguide slots. Moreover, that which has been presented features a classic traveling wave, efficiency-reducing beam tilt. This work proposes a unique CP waveguide slot architecture which mitigates these problems and a thorough design procedure employing widely available, modern computational tools. The proposed array topology features simultaneous dual-CP operation with grating-lobe-free, broadside radiation, high aperture efficiency, and good return loss. A traditional X-Slot CP element is employed with the inclusion of a slow wave structure passive phase shifter to ensure broadside radiation without the need for performance-limiting dielectric loading. It is anticipated this technology will be advantageous for upcoming polarimetric radar and Ka-band SatCom systems. The presented design methodology represents a philosophical shift away from traditional waveguide slot radiator design practices. Rather than providing design curves and/or analytical expressions for equivalent circuit models, simple first-order design rules – generated via parametric studies — are presented with the understanding that device optimization and design will be carried out computationally. A unit-cell, S-parameter based approach provides a sufficient reduction of complexity to permit efficient, accurate device design with attention to realistic, application-specific mechanical tolerances. A transparent, start-to-finish example of the design procedure for a linear sub-array at X-Band is presented. Both unit cell and array performance is calculated via finite element method simulations. Results are confirmed via good agreement with finite difference, time domain calculations. Array performance exhibiting grating-lobe-free, broadside-scanned, dual-CP radiation with better than 20 dB return loss and over 75% aperture efficiency is presented.