Preservation of York Minster historic limestone by hydrophobic surface coatings

Magnesian limestone is a key construction component of many historic buildings that is under constant attack from environmental pollutants notably by oxides of sulfur via acid rain, particulate matter sulfate and gaseous SO 2 emissions. Hydrophobic surface coatings offer a potential route to protect existing stonework in cultural heritage sites, however, many available coatings act by blocking the stone microstructure, preventing it from 'breathing' and promoting mould growth and salt efflorescence. Here we report on a conformal surface modification method using self-assembled monolayers of naturally sourced free fatty acids combined with sub-monolayer fluorinated alkyl silanes to generate hydrophobic (HP) and super hydrophobic (SHP) coatings on calcite. We demonstrate the efficacy of these HP and SHP surface coatings for increasing limestone resistance to sulfation, and thus retarding gypsum formation under SO/H O and model acid rain environments. SHP treatment of 19th century stone from York Minster suppresses sulfuric acid permeation.

Um percurso sobre o patrimônio e a morfologia urbana do centro de Fortaleza-CE

The incursion into the historical area from Fortaleza´s downtown presents reminiscences of a heritage collection that can be recognized as city built heritage, in architectural and urban aspects. The neighborhood has in its urban tracing a synthesis of the various phases from the Brazilian architecture materialized in its tracing and built goods. This composition mainly covers the eclectic production, passing the time of art déco, including the period of modern production. This paper aims to identify the existing heritage collection. This study aims to identify the existing net assets, the temporality and spatiality that allow to recreate the neighborhood´s form urbain history. Based on the theoretical and methodological support of the urban morphology urban of authors such as Aldo Rossi (1966), Gordon Cullen (1971), José Lamas (1990), Kevin Lynch (1960), and Philippe Panerai (1999) was allowed on a predefined route, to build part of urban memory of Fortaleza. The historical and morphological study runs through a sequenced analysis developed on the articulated subsets, formed by the network neighborhood squares: Praça José de Alencar, Praça Capistrano de Abreu (Lagoinha), Praça Clóvis Beviláquia, Praça do Carmo, Praça Murilo Borges (BNB), Praça Coração de Jesus, Parque das Crianças, Praça do Riacho Pajeú, Praça dos Voluntários (Polícia), Praça do Ferreira, Praça Waldemar Falcão (Correios), Praça General Tibúrcio (Leões), Praça Figueira de Melo, Bosque Dom Delgado (Pajeú), Praça Cristo Redentor, Praça Caio Prado (Sé), Praça dos Mártires (Passeio Público), e Praça Castro Carreira (Estação). Separated the neighborhood based on this square system because it is perceived that there is in these public spaces a path which includes a portion of the urban history of Fortaleza. In addition to this there is a higher concentration of goods in its area in relation to others sectors of the neighborhood, where the loss of the characterization is an imperative of the urban set. In order to find this network of public spaces contained in the study area were proposed two routes based on the city limits of 1875 established by Adolfo Herbster (Fortaleza´s city plan).The path starts by known boulevards (Imperador, Duque de Caxias and Dom Manuel avenues) and the seafront. The study is grounded in the literature review, document and empirical theme, consisting of an overlay of maps, drawings and photographic collection that ratify this net assets as both architectural urban nowadays. Among the results, it was observed that before a current context of loss of locus of the concept of historical-cultural agglomerated, the squares express the strongholds of equity ambience that perhaps stand in urban morphology of the capital from Ceará.

Kalaureia 1894 : A Cultural History of the First Swedish Excavation in Greece

The excavation of the Sanctuary of Poseidon at Kalaureia in 1894 marks the beginning of Swedish archaeological fieldwork in Greece. During a couple of hot summer months, two philologists from Uppsala University, Sam Wide (1861-1918) and Lennart Kjellberg (1857-1936), worked in the sanctuary together with the architect Sven Kristenson (1858-1937), the Greek foreman Pankalos and around twenty local workmen. In 1997, the Swedish Institute at Athens began new excavations at the sanctuary. This thesis examines the beginnings of Swedish fieldwork in Greece. Within the framework of a cultural history of archaeology, inspired by archaeological ethnography and the New Cultural History, it explores how archaeology functioned as a cultural practice in the late nineteenth century. A micro-historical methodology makes use of a wide array of different source material connected to the excavation of 1894, its prelude and aftermath. The thesis takes the theoretical position that the premises for archaeological knowledge production are outcomes of contemporary power structures and cultural politics. Through an analysis of how the archaeologists constructed their self-images through a set of idealized stereotypes of bourgeois masculinity, academic politics of belonging is highlighted. The politics of belonging existed also on a national level, where the Swedish archaeologists entered into a competition with other foreign actors to claim heritage sites in Greece. The idealization of classical Greece as a birthplace of Western values, in combination with contemporary colonial and racist cultural frameworks in Europe, created particular gazes through which the modern country was appropriated and judged. These factors all shaped the practices through which archaeological knowledge was created at Kalaureia. Some excavations tend to have extensive afterlives through the production of histories of archaeology. Therefore, this thesis also explores the representations of the 1894 excavation in the historiography of Swedish classical archaeology. It highlights the strategies by which the excavation at Kalaureia has served to legitimize further Swedish engagements in Greek archaeology, and explores the way in which historiography shapes our professional identities.

Incorporação de resíduos cerâmicos vidrados em argamassas bastardas: estudo de propriedades físicas e mecânicas

Dissertação de Natureza Científica para obtenção do grau de Mestre em Engenharia Civil Perfil de Edificações

Impacto de la accesibilidad y urbanización en el patrimonio edificado de las tenencias (pueblos) de Morelia Michoacán, México

Los valores del patrimonio edificado en las tenencias del municipio de Morelia distan mucho de ser los de la zona de monumentos de la capital, ya que tienen que ver con la cultura popular, el saber colectivo y las tradiciones constructivas. El artículo explica que como reflejo de los cambios en la economía, cultura y desarrollo de sus habitantes, las tenencias experimentan un proceso de transformación y hasta la pérdida de su patrimonio edificado. Las unidades de análisis se seleccionaron con el Índice de Accesibilidad e Interacción Espacial; posteriormente se explican los indicadores de Accesibilidad y Urbanización, y finalmente estos datos se correlacionan con el indicador de transformación del patrimonio. Medir y conocer las características de los factores que transforman el patrimonio cultural edificado es una manera anticipada de conservarlo como una manifestación cultural, histórica, de una forma de vida y un elemento de identidad.

A petrographic investigation into the durability of common replacement sandstones to the crystallisation of de-icing salts

Scottish sandstone buildings are now suffering the long-term effects of salt-crystallisation damage, owing in part to the repeated deposition of de-icing salts during winter months. The use of de-icing salts is necessary in order to maintain safe road and pavement conditions during cold weather, but their use comes at a price. Sodium chloride (NaCl), which is used as the primary de-icing salt throughout the country, is a salt known to be damaging to sandstone masonry. However, there remains a range of alternative, commercially available de-icing salts. It is unknown however, what effect these salts have on porous building materials, such as sandstone. In order to protect our built heritage against salt-induced decay, it is vital to understand the effects of these different salts on the range of sandstone types that we see within the historic buildings of Scotland. Eleven common types of sandstone were characterised using a suite of methods in order to understand their mineralogy, pore structure and their response to moisture movement, which are vital properties that govern a stone’s response to weathering and decay. Sandstones were then placed through a range of durability tests designed to measure their resistance to various weathering processes. Three salt crystallisation tests were undertaken on the sandstones over a range of 16 to 50 cycles, which tested their durability to NaCl, CaCl2, MgCl2 and a chloride blend salt. Samples were primarily analysed by measuring their dry weight loss after each cycle, visually after each cycle and by other complimentary methods in order to understand their changing response to moisture uptake after salt treatment. Salt crystallisation was identified as the primary mechanism of decay across each salt, with the extent of damage in each sandstone influenced by environmental conditions and pore-grain properties of the stone. Damage recorded in salt crystallisation tests was ultimately caused by the generation of high crystallisation pressures within the confined pore networks of each stone. Stone and test-specific parameters controlled the location and magnitude of damage, with the amount of micro-pores, their spatial distribution, the water absorption coefficient and the drying efficiency of each stone being identified as the most important stone-specific properties influencing salt-induced decay. Strong correlations were found between the dry weight loss of NaCl treated samples and the proportion of pores <1µm in diameter. Crystallisation pressures are known to scale inversely with pore size, while the spatial distribution of these micro-pores is thought to influence the rate, overall extent and type of decay within the stone by concentrating crystallisation pressures in specific regions of the stone. The water absorption determines the total amount of moisture entering into the stone, which represents the total amount of void space for salt crystallisation. The drying parameters on the other hand, ultimately control the distribution of salt crystallisation. Those stones that were characterised by a combination of a high proportion of micro-pores, high water absorption values and slow drying kinetics were shown to be most vulnerable to NaCl-induced decay. CaCl2 and MgCl2 are shown to have similar crystallisation behaviour, forming thin crystalline sheets under low relative humidity and/or high temperature conditions. Distinct differences in their behaviour that are influenced by test specific criteria were identified. The location of MgCl2 crystallisation close to the stone surface, as influenced by prolonged drying under moderate temperature drying conditions, was identified as the main factor that caused substantial dry weight loss in specific stone types. CaCl2 solutions remained unaffected under these conditions and only crystallised under high temperatures. Homogeneous crystallisation of CaCl2 throughout the stone produced greater internal change, with little dry weight loss recorded. NaCl formed distinctive isometric hopper crystals that caused damage through the non-equilibrium growth of salts in trapped regions of the stone. Damage was sustained as granular decay and contour scaling across most stone types. The pore network and hydric properties of the stones continually evolve in response to salt crystallisation, creating a dynamic system whereby the initial, known properties of clean quarried stone will not continually govern the processes of salt crystallisation, nor indeed can they continually predict the behaviour of stone to salt-induced decay.

Arrifes : urbanismo e património construído

Dissertação de Mestrado, Património, Museologia e Desenvolvimento, 8 de Julho de 2016, Universidade dos Açores.

Valorização do Património Edificado de Ponta Delgada : estudo em torno da memória dos lugares

Dissertação de Mestrado, Património, Museologia e Desenvolvimento, 29 de Setembro de 2016, Universidade dos Açores.

Alfama : Análise da paisagem urbana como expressão do património subunidade de estudo: Zona Ribeirinha, da Rua da Alfândega a Rua do Jardim do Tabaco

Esta investigação tem como contexto o bairro de Alfama, centrando-se em uma área específica situada na zona ribeirinha com início na Rua da Alfândega e se estendendo até a Rua do Jardim do Tabaco. É uma zona com relevante potencial turístico, mas com pouco dinamismo apesar dos vários atrativos que lá existem. O trabalho tem como objetivo analisar a paisagem urbana na subunidade de estudo citada acima de forma a descobrirmos através da leitura do espaço urbano uma identidade patrimonial para desta maneira propormos a sua valorização. Para facilitar o estudo dividimos a área em cinco trechos e através da observação in loco esboçarmos sua situação ao nível de morfologia urbana, das características espaciais, dos usos e do modo de apropriação do espaço pelas pessoas e pelas atividades, o estado de conservação do edificado, o mobiliário urbano e todas as características do seu entorno. Para a análise da paisagem fizemos um levantamento fotográfico digital e uma avaliação visual do percurso procurando enquadrar-se na leitura da paisagem estudada pelos autores Kevin Lynch e Gordon Cullen. O estudo também passa por uma avaliação dos seus aspectos significativos, ou seja, os registres de memórias que são pontos fortes da paisagem urbana. São aspectos que identificam o local e definem a sua legibilidade. Em paralelo elaboramos uma análise SWOT que contribuiu para entendermos o complexo de desafios que se colocam ao nosso universo de estudo e justificar o contributo desta dissertação através de propostas concretas de valorização. ABSTRACT; The context of this research is Alfama district, focusing on a specific area located on the waterfront starting at Alfândega Street and extending until Jardim do Tabaco Street. lt is an area with a relevant tourism potential, however with a small dynamic despite its many attractions. The research aim to study the urban landscape in the sub-unit mentioned above in order to uncover, through an urban reading, a patrimonial identity seeking its recovery. To facilitate the research, the area was divided into five sections and, by in loco observation, we outlined its position into a urban morphology rank, space characteristics, uses and appropriation of space by individuals and activities, conservation condition of the building, urban furniture and all the features of its surroundings. With regards the landscape study, was done a digital inventory and a visual evaluation of the route in quest of to fit it in the landscape studies by the authors Kevin Lynch and Gordon Cullen. The research also goes through an appraisal of its significant aspects, in other words, the memories records that are the strengths of the urban landscape. These are aspects that identify the location and define its readability. ln parallel we had developed a SWOT analysis which helped to understand the complex challenges in this universe of studies and justify the contribution of this thesis with concrete recovery proposals.

Os limites da gentrificação na vila planalto

Dissertação (mestrado)—Universidade de Brasília, Faculdade de Arquitetura e Urbanismo, Programa de Pós-Graduação em Arquitetura e Urbanismo, 2015.

Arquitectura de espaços abertos

Dissertação para obtenção do grau de Mestre em Arquitectura, apresentada na Universidade de Lisboa - Faculdade de Arquitectura.

Design de comunicação

Dissertação de Doutoramento para obtenção do grau de Doutor em Design, dissertação apresentada na Universidade de Lisboa - Faculdade de Arquitetura.

O património industrial na cidade de Lisboa

Dissertação para obtenção do grau de Mestre em Arquitetura, apresentada na Universidade de Lisboa - Faculdade de Arquitetura.

Modelo para regular la identidad y el comportamiento de los usos del suelo en el área de primer orden del centro histórico de Cuenca

Históricamente la ciudad de Cuenca es, ha sido y muy probablemente será un importante centro de desarrollo tanto para la provincia del Azuay, como para el país; dicho desarrollo tuvo su inicio en lo que hoy se conoce como Centro Histórico de la ciudad. No se puede dejar de lado el hecho de que este sector tiene el reconocimiento de Patrimonio Cultural de la Humanidad otorgado por la UNESCO en diciembre de 1999. El presente trabajo de titulación se ha centrado en el Área de Primer Orden del Centro Histórico de Cuenca, con el objetivo principal de proponer un modelo de usos de suelo que ayude a regular tanto la intensidad como el comportamiento de las actividades humanas presentes en el área de estudio; así como la preservación del patrimonio edificado. El camino para alcanzar dicho objetivo se dividió en cuatro etapas: la primera se centró en la recopilación de información tanto teórica como histórica; la segunda fue la elaboración del diagnóstico de la situación actual en lo referente a los usos de suelo; la tercera estuvo destinada a la formulación de una metodología que guíe la elaboración del modelo, basado en la información bibliográfica revisada con anterioridad, y finalmente en la última etapa se llevó a cabo la aplicación de lo propuesto para el área de análisis.

Intervención urbano arquitectónica en el manzano 002-N13 del Centro Histórico de Cuenca

Los centros históricos patrimoniales de las ciudades son organismos vivosque se ven afectados por una serie de actuaciones, que surgen por la expansión de la ciudad y las nuevas necesidades. Factores que frecuentemente atentan contra el patrimonio edificado y sus valores, causando en muchas ocasiones pérdidas irreversibles. El centro histórico de la ciudad de Cuenca presenta problemas de destrucción y deterioro del patrimonio edificado por la deficiente valoración histórica-crítica. Además, la inversión de recursos y actuaciones urbanas se limita a los manzanos circundantes a la plaza central sin alcanzar a la periferia del casco histórico. Por este motivo, surge el estudio del manzano 002-N13, en donde se emplaza la Iglesia Patrimonial y el geriátrico Hogar Asilo Cristo Rey. Para el cual se propone un proyecto de intervención urbano arquitectónico quetiene como objetivo re-potencializar las condiciones históricas, funcionales y formales del mismo. Siendo necesario realizar una investigación integral del manzano y del contexto urbano inmediato, un estudio histórico crítico y una valoración de las edificaciones con el fin de facultar reflexiones que permitan adquirir una postura adecuada de actuación urbano arquitectónica.