High resolution paleoceanography of the Guaymas Basin, Gulf of California, during the past 15000 yeras

Deep Sea Drilling Project Site 480 (27°54.10'N, 111°39.34'W; 655 m water depth) contains a high resolution record of paleoceanographic change of the past 15000 years for the Guaymas Basin, a region of very high diatom productivity within the central Gulf of California. Analyses of diatoms and silicoflagellates were completed on samples spaced every 40-50 yr, whereas ICP-AES geochemical analyses were completed on alternate samples (sample spacing 80-100 yr). The Bolling-Allerod interval (14.6-12.9 ka) (note, ka refers to 1000 calendar years BP throughout this report) is characterized by an increase in biogenic silica and a decline in calcium carbonate relative to surrounding intervals, suggesting conditions somewhat similar to those of today. The Younger Dryas event (12.9-11.6 ka) is marked by a major drop in biogenic silica and an increase in calcium carbonate. Increasing relative percentage contributions of Azpeitia nodulifera and Dictyocha perlaevis (a tropical diatom and silicoflagellate, respectively) and reduced numbers of the silicoflagellate Octactis pulchra are supportive of reduced upwelling of nutrient-rich waters. Between 10.6 and 10.0 ka, calcium carbonate and A. nodulifera abruptly decline at DSDP 480, while Roperia tesselata, a diatom indicative of winter upwelling in the modern-day Gulf, increases sharply in numbers. A nearly coincident increase in the silicoflagellate Dictyocha stapedia suggests that waters above DSDP 480 were more similar to the cooler and slightly more saline waters of the northern Gulf during much of the early and middle parts of the Holocene (~10 to 3.2 ka). At about 6.2 ka a stepwise increase in biogenic silica and the reappearance of the tropical diatom A. nodulifera marks a major change in oceanographic conditions in the Gulf. A winter shift to more northwesterly winds may have occurred at this time along with the onset of periodic northward excursions (El Nino-driven?) of the North Equatorial Countercurrent during the summer. Beginning between 2.8 and 2.4 ka, the amplitude of biogenic silica and wt% Fe, Al, and Ti (proxies of terrigenous input) increase, possibly reflecting intensification of ENSO cycles and the establishment of modern oceanographic conditions in the Gulf. Increased numbers of O. pulchra after 2.8 ka suggest enhanced spring upwelling.

Diatoms and Silicoflagellates from ODP Hole 114-699A and Site 114-704

The stratigraphic ranges and relative abundances of selected diatoms and silicoflagellates are presented from three Neogene sedimentary sequences from the subantarctic South Atlantic. These data were compiled from Hole 699A in the southwest South Atlantic and Holes 704A and 704B in the southeast South Atlantic. Thirty-five samples were examined from a 67.5-m section of Hole 699A, which is mostly late Miocene or younger in age. A total of 225 samples was examined from the upper 569.1-m lower Miocene to Quaternary section in Holes 704A and 704B. Although the partial census of the Site 704 sequences is only preliminary, it reveals that the Neogene is remarkably complete and serves as a reference for further detailed examination of an important biostratigraphic-magnetostratigraphic reference section for the Neogene record of the Southern Ocean.

Diatom abundance in ODP Leg 178 holes

This paper documents the biostratigraphic distribution and abundance of diatoms from sites drilled during Ocean Drilling Program Leg 178, off the Pacific margin of the Antarctic Peninsula. Drift sediments cored on the continental rise at Sites 1095, 1096, and 1101 have good recovery and a well-defined paleomagnetic record. Well-preserved diatoms are present throughout the upper Miocene to middle Pliocene and in the upper Quaternary section of these sites. The stratigraphic occurrence of diatom species through these intervals defines numerous datum levels. Diatom events are given absolute age estimates through direct correlation to the established paleomagnetic stratigraphy of Sites 1095, 1096, and 1101. Leg 178 diatom biostratigraphic results enable the development of a regional stratigraphic framework for the Pacific sector of the Southern Ocean and record the interaction of open-ocean and shelf-margin diatom floras.

Diatoms in Paleocene sediments of the southwestern South Atlantic

The taxonomy and stratigraphy of pelagic Paleocene diatoms from ODP Sites 698, 700, and 702 and DSDP Site 524 in the South Atlantic and DSDP Site 214 in the Indian Ocean are presented, as well as paleogeographic and paleoecologic implications. Eleven new species and one new variety are described and one new combination is proposed: Coscinodiscus cruxii sp. nov. Grunowiella palaeocaenica var. alternans var. nov. Hemiaulusl beatus sp. nov. Hemiaulusl ciesielskii sp. nov. Hemiaulusl conicus sp. nov. Hemiaulus kristoffersenii sp. nov. Hemiaulus nocchiae sp. nov. Hemiaulusl oonkii sp. nov. Hemiaulusl velatus sp. nov. Triceratium gombosii sp. nov. Trochosira gracillima comb. nov. Trochosira marginata sp. nov. Trochosira radiata sp. nov. Hole 700B provides one of the most continuous diatomaceous Paleocene profiles known. Stratigraphic ranges of diatom species from this and other Southern Hemisphere sites are calibrated against calcareous microfossil zones. The first-appearance datums of Triceratium gombosii, Hemiaulus incurvus, and Triceratium mirabile in Paleocene deep-sea sediments are useful for regional stratigraphic correlations. Quantitative analysis of the biosiliceous microfossil groups (diatoms, silicoflagellates, radiolarians, and archaeomonadaceae) shows that preservation of diatoms is confined primarily to the upper Paleocene (planktonic foraminifer Zones P3 and P4 and calcareous nannofossil Zones upper NP5 to lower NP9). In the lower Paleocene only short intervals in Hole 700B are diatomaceous. A correlation between the degree of silica diagenesis and the calcium carbonate content of the sediment is not obvious. Diatom species analysis reflects changes in the paleoenvironment between island-related upwelling conditions with highly diverse and well-preserved diatom assemblages and less productive periods resulting in less wellpreserved diatom assemblages with a higher content of robust neritic diatoms.

Neogene diatoms of the Japan Sea

A series of excellent upper Miocene through Quaternary diatomaceous sequences recovered at four sites during Leg 127 was examined for diatoms. The diagenetic transition from opal-A to opal-CT is a diachronic horizon from the uppermost part of the Denticulopsis katayamae Zone (8.5 Ma) at Hole 797B to the uppermost part of the Neodenticula kamtschatica Zone (5.73 Ma) at Hole 795A. The diatom zonation of Koizumi (1985) best divides the upper Miocene to Quaternary sequences above the opal-A/opal-CT boundary and also is useful to date carbonate concretions including diatoms below the boundary. Forty diatom datum levels were evaluated biostratigraphically based on the sediment accumulation rate curve, and several isochronous datum levels are newly proposed for the Japan Sea area. A warm-water current did not penetrated into the Japan Sea through the Tsushima strait during the late Miocene and Pliocene time, because subtropical warm-water diatoms are essentially not present in such sediment samples. The occurrences of diatom are cyclic throughout the Quaternary sediments and are affected by eustatic sea level changes.

Miocene to Holocene diatom biostratigraphy of ODP Leg 105 sites

Diatoms occur sporadically in lower Miocene to Holocene sediments recovered at ODP Site 645 and in upper Pliocene to Holocene sediments at ODP Site 646. The diatom assemblage at Site 645 contains rare stratigraphic indicators. Fragmentation of frustules and the occurrence of species characteristic of high-latitude shelf, upper-slope environments suggest current transportation from the shelf. The diatom abundance and preservation at Site 646 probably reflect climatic changes and are also affected by dissolution, but it is not possible to detect the dominant factor. Therefore, the stratigraphic ranges of the primary and secondary biostratigraphic indicators are often unreliable.

High-resolution sedimentological and paleontological record of ODP Site 167-1019

Holocene and latest Pleistocene oceanographic conditions and the coastal climate of northern California have varied greatly, based upon high-resolution studies (ca. every 100 years) of diatoms, alkenones, pollen, CaCO3%, and total organic carbon at Ocean Drilling Program (ODP) Site 1019 (41.682°N, 124.930°W, 980 m water depth). Marine climate proxies (alkenone sea surface temperatures [SSTs] and CaCO3%) behaved remarkably like the Greenland Ice Sheet Project (GISP)-2 oxygen isotope record during the Bølling-Allerod, Younger Dryas (YD), and early part of the Holocene. During the YD, alkenone SSTs decreased by >3°C below mean Bølling-Allerod and Holocene SSTs. The early Holocene (ca. 11.6 to 8.2 ka) was a time of generally warm conditions and moderate CaCO3 content (generally >4%). The middle part of the Holocene (ca. 8.2 to 3.2 ka) was marked by alkenone SSTs that were consistently 1-2°C cooler than either the earlier or later parts of the Holocene, by greatly reduced numbers of the gyre-diatom Pseudoeunotia doliolus (<10%), and by a permanent drop in CaCO3% to <3%. Starting at ca. 5.2 ka, coastal redwood and alder began a steady rise, arguing for increasing effective moisture and the development of the north coast temperate rain forest. At ca. 3.2 ka, a permanent ca. 1°C increase in alkenone SST and a threefold increase in P. doliolus signaled a warming of fall and winter SSTs. Intensified (higher amplitude and more frequent) cycles of pine pollen alternating with increased alder and redwood pollen are evidence that rapid changes in effective moisture and seasonal temperature (enhanced El Niño-Southern Oscillation [ENSO] cycles) have characterized the Site 1019 record since about 3.5 ka.

Distribution of Pliocene diatom faunas in the Northwest Pacific

High-resolution quantitative diatom data are tabulated for the early part of the late Pliocene ( 3.25 to 2.08 Ma ) at DSDP Site 580 in the northwestern Pacific. Sample spacing averages 11 k.y. between 3.1 and 2.8 Ma, but increases to 14 to 19 k.y. prior to 3.1 Ma and after 2.8 Ma. Q-mode factor analysis of the middle Pliocene assemblage reveals four factors which explain 92.4% of the total variance of the 47 samples studied between 3.25 and 2.55 Ma. Three of the factors are closely related to modern subarctic, transitional, and subtropical elements, while the fourth factor, which is dominated by Coscinodiscus marginatus and the extinct Pliocene species Neodenticula kamtschatica, appears to correspond to a middle Pliocene precursor of the subarctic water mass. Knowledge of the modern and generalized Pliocene paleoclimatic relationships of various diatom taxa is used to generate a paleoclimate curve ("Twt") based on the ratio of warm-water (subtropical) to cold-water diatoms with warm-water transitional taxa (Thalassionema nitzschioides, Thalassiosira oestrupii, and Coscinodiscus radiatus) factored into the equation at an intermediate (0.5) value. The "Twt" ratios at more southerly DSDP Sites 579 and 578 are consistently higher (warmer) than those at Site 580 throughout the Pliocene, suggesting the validity of the ratio as a paleoclimatic index. Diatom paleoclimatic data reveal a middle Pliocene (3.1 to 3.0 Ma) warm interval at Site 580 during which paleotemperatures may have exceeded maximum Holocene values by 3 °- 5.5 °C at least three times. This middle Pliocene warm interval is also recognized by planktic foraminifers in the North Atlantic, and it appears to correspond with generalized depleted oxygen isotope values suggesting polar warming. The diatom "Twt" curve for Site 580 compares fairly well with radiolarian and silicoflagellate paleoclimatic curves for Site 580, planktic foraminiferal sea-surface temperature estimates for the North Atlantic, and benthic oxygen isotope curves for late Pliocene, although higher resolution studies on paired samples are required to test the correspondence of these various paleoclimatic indices.

Abiotic characteristics and diatom abundance and biomass in different sectors of the Argentinien Shelf and antartic waters

A large spatial scale study of the diatom species inhabiting waters from the subantarctic (Argentine shelf) to antarctic was made for the first time in order to understand the relationships between these two regions with regard to the fluctuations in diatom abundances in relation with environmental features, their floristic associations and the effect of the Polar Front as a biogeographic barrier. Species-specific diatom abundance, nutrient and chlorophyll-a concentration were assessed from 64 subsurface oceanographic stations carried out during the austral summer 2002, a period characterized by an anomalous sea-ice coverage corresponding to a ''warm year". Significant relationships of both diatom density and biomass with chlorophyll-a (positive) and water temperature (negative) were found for the study area as a whole. Within the Subantarctic region, diatom density and biomass values were more uniform and significantly (in average: 35 and 11 times) lower than those of the Antarctic region, and did not correlate with chlorophyll-a. In antarctic waters, instead, biomass was directly related with chlorophyll-a, thus confirming the important contribution of diatoms to the Antarctic phytoplanktonic stock. A total of 167 taxa were recorded for the entire study area, with Chaetoceros and Thalassiosira being the best represented genera. Species richness was maximum in subantarctic waters (46; Argentine shelf) and minimum in the Antarctic region (21; Antarctic Peninsula), and showed a significant decrease with latitude. Floristic associations were examined both qualitatively (Jaccard Index) and quantitatively (correlation) by cluster analyses and results allowed differentiating a similar number of associations (12 vs. 13, respectively) and two main groups of stations. In the Drake Passage, the former revealed that the main floristic change was found at the Polar Front, while the latter reflected the Southern ACC Front as a main boundary, and yielded a higher number of isolated sites, most of them located next to different Antarctic islands. Such differences are attributed to the high relative density of Fragilariopsis kerguelensis in Argentine shelf and Drake Passage waters and of Porosira glacialis and species of Chaetoceros and Thalasiosira in the Weddell Sea and near the Antarctic Peninsula. From a total of 84 taxa recorded in antarctic waters, only 17 were found exclusively in this region, and the great majority (67) was also present in subantarctic waters but in extremely low (< 1 cell/l) concentrations, probably as a result of expatriation processes via the ACC-Malvinas Current system. The present results were compared with those of previous studies on the Antarctic region with respect to both diatom associations in regular vs. atypically warm years, and the distribution and abundance of some selected planktonic species reported for surface sediments.

Diatom biostratigraphy and datum events of ODP Hole 183-1140A

Ocean Drilling Program (ODP) Leg 183 Site 1140 provided a lower Oligocene to middle Miocene record of diatom assemblages from the northern Kerguelen Plateau. Samples were examined to improve the resolution of shipboard diatom biostratigraphy. The material is complementary to that recovered during ODP Legs 119 and 120, and the diatom zonation of Harwood and Maruyama could be readily applied. A standard succession of biostratigraphic zones from the middle Miocene and lower Oligocene was delineated, although some zones were unrecognizable because of poor core recovery. The detailed diatom biostratigraphy presented here agrees well with shipboard calcareous nannofossil biostratigraphy. Sediment accumulation rates based on diatom bioevents average 1.26 cm/k.y.

Diatom biostratigraphy of ODP Holes 191-1179B and 191-1179C

Although the objective of Ocean Drilling Program Leg 191 was to install a seismic monitoring station and to test a hard rock reentry drilling system, several good, near-continuous sedimentary core sequences were recovered during the cruise. Two holes, 1179B and 1179C, yielded an upper Miocene to Pleistocene diatom record through an expanded section with excellent recovery. Because diatom species included in both low-latitude and high-latitude biostratigraphies are present, zonations for the equatorial Pacific and northwest Pacific are applied to the sediments. The oldest zones from each zonation that are represented in the cores are the Nitzschia miocenica Zone and the Rouxia californica Zone, respectively. Only one zonal boundary is not observed within the diatom assemblage, that being the top of the Nitzschia jouseae Zone and base of the Rhizosolenia praebergonii Subzone A (equatorial Pacific). Preservation is good overall, and sample abundances vary from rare to abundant. This would be an excellent section for further biostratigraphic, paleoclimatic, and paleoceanographic study.

Palaeoceanographic data of sediment core MD01-2416

We present an SiF4 separation line, coupled to a laser fluorination system, which allows for an efficient combined silica d18O and d30Si analysis (50 min per sample). The required sample weight of 1.5-2.0 mg allows for high-resolution isotope studies on biogenic opal. Besides analytical tests, the new instrumentation set-up was used to analyse two marine diatom fractions (>63 µm, 10-20 µm) with different diatom species compositions extracted from a Bølling/Allerød-Holocene core section [MD01-2416, North-West (NW) Pacific] to evaluate the palaeoceanographic significance of the diatom isotopic signals and to address isotopic effects related to contamination and species-related isotope effects (vital and environmental effects). While d30Si offsets between the two fractions were not discernible, supporting the absence of species-related silicon isotope effects, systematic offsets occur between the d18O records. Although small, these offsets point to species-related isotope effects, as bias by contamination can be discarded. The new records strengthen the palaeoceanographic history during the last deglaciation in the NW Pacific characterized by a sequence of events with varying surface water structure and biological productivity. With such palaeoceanographic evolution it becomes unlikely that the observed systematic d18O offsets signal seasonal temperature variability. This calls for reconsideration of vital effects, generally excluded to affect d18O measurements.

Siliceous microfossil assemblage and accumulation rate variations across the Middle Eocene Climatic Optimum at ODP Site 171-1051

The Middle Eocene Climatic Optimum (MECO; ~ 40 million years ago [Ma]) is one of the most prominent transient global warming events in the Paleogene. Although the event is well documented in geochemical and isotopic proxy records at many locations, the marine biotic response to the MECO remains poorly constrained. We present new high-resolution, quantitative records of siliceous microplankton assemblages from the MECO interval of Ocean Drilling Program (ODP) Site 1051 in the subtropical western North Atlantic Ocean, which are interpreted in the context of published foraminiferal and bulk carbonate stable isotope (d18O and d13C) records. High diatom, radiolarian and silicoflagellate accumulation rates between 40.5 and 40.0 Ma are interpreted to reflect an ~ 500 thousand year (kyr) interval of increased nutrient supply and resultant surface-water eutrophication that was associated with elevated sea-surface temperatures during the prolonged onset of the MECO. Relatively low pelagic siliceous phytoplankton sedimentation accompanied the peak MECO warming interval and the termination of the MECO during an ~ 70 kyr interval centered at ~ 40.0 Ma. Following the termination of the MECO, an ~ 200-kyr episode of increased siliceous plankton abundance indicates enhanced nutrient levels between ~ 39.9 and 39.7 Ma. Throughout the Site 1051 record, abundance and accumulation rate fluctuations in neritic diatom taxa are similar to the trends observed in pelagic taxa, implying either similar controls on diatom production in the neritic and pelagic zones of the western North Atlantic or fluctuations in sea level and/or shelf accommodation on the North American continental margin to the west of Site 1051. These results, combined with published records based on multiple proxies, indicate a geographically diverse pattern of surface ocean primary production changes across the MECO. Notably, however, increased biosiliceous accumulation is recorded at both ODP Sites 1051 and 748 (Southern Ocean) in response to MECO warming. This may suggest that increased biosiliceous sediment accumulation, if indeed a widespread phenomenon, resulted from higher continental silicate weathering rates and an increase in silicic acid supply to the oceans over several 100 kyr during the MECO.

Siliceous phytoplankton in middle Eocene sediments of ODP Hole 207-1260A

The Middle Eocene diatom and silicoflagellate record of ODP Site 1260A (Demerara Rise) is studied quantitatively in order to throw light on the changes that siliceous phytoplankton communities experienced during a Middle Eocene warming event that occurred between 44.0 and 42.0 Ma. Both Pianka's overlap index, calculated per couple of successive samples, and cluster analysis, point to a number of significant turnover events highlighted by changes in the structure of floristic communities. The pre-warming flora, dominated by cosmopolitan species of the diatom genus Triceratium, is replaced during the warming interval by a new and more diverse assemblage, dominated by Paralia sulcata (an indicator of high productivity) and two endemic tropical species of the genus Hemiaulus. The critical warming interval is characterized by a steady increase in biogenic silica and a comparable increase in excess Ba, both reflecting an increase in productivity. In general, it appears that high productivity not only increased the flux of biogenic silica, but also sustained a higher diversity in the siliceous phytoplankton communities. The microflora preserved above the critical interval is once again of low diversity and dominated by various species of the diatom genus Hemiaulus. All assemblages in the studied material are characterized by the total absence of continental and benthic diatoms and the relative abundance of neritic forms, suggesting a transitional depositional environment between the neritic and the oceanic realms.

Distribution of biological, anthropogenic, and volcanic constituents in the San Francisco Bay Coastal System

Although conventional sediment parameters (mean grain size, sorting, and skewness) and provenance have typically been used to infer sediment transport pathways, most freshwater, brackish, and marine environments are also characterized by abundant sediment constituents of biological, and possibly anthropogenic and volcanic, origin that can provide additional insight into local sedimentary processes. The biota will be spatially distributed according to its response to environmental parameters such as water temperature, salinity, dissolved oxygen, organic carbon content, grain size, and intensity of currents and tidal flow, whereas the presence of anthropogenic and volcanic constituents will reflect proximity to source areas and whether they are fluvially- or aerially-transported. Because each of these constituents have a unique environmental signature, they are a more precise proxy for that source area than the conventional sedimentary process indicators. This San Francisco Bay Coastal System study demonstrates that by applying a multi-proxy approach, the primary sites of sediment transport can be identified. Many of these sites are far from where the constituents originated, showing that sediment transport is widespread in the region. Although not often used, identifying and interpreting the distribution of naturally-occurring and allochthonous biologic, anthropogenic, and volcanic sediment constituents is a powerful tool to aid in the investigation of sediment transport pathways in other coastal systems.