Rheological behaviours of graphene oxide reinforced cement composite

Graphene oxide (GO) offers great potential as nanoscale reinforcement for cementitious material. In this work, the rheological behaviours of the GO-cement composite were investigated for the first time. It was found that the workability of cement paste (w/c=0.5) is significantly decreased with the addition of 0.02wt% GO sheets. The rheology tests results show that the GO sheets greatly increase the yield stress and viscosity of the cement paste. It is also found that the yield stress and viscosity of the GO-cement composite increase with increasing size of GO sheets. The reduction of workability is undesirable for the application of the novel GO-cement composite. Therefore, further research works are needed to improve the workability of the composite.

Optimum mix design of concrete made with dune sand as fine aggregate

The use of dune sand for replacing ordinary fine aggregate in concrete has environmental benefits and the feasibility has been demonstrated in China and some Middle East countries. However, the use of dune sand tends to decrease the engineering properties (compressive strength and workability) of concrete. To improve engineering properties of dune sand concrete (DSC), the current paper is to check which strength andslump levels can be obtained by optimization of mix proportions. Results show that the ratio of cement to sand (C/S) has significant influence on the engineering properties of DSC. At low C/S ratio, the engineeringproperties of DSC are inferior to those of concretes made with normal sand (NSC). However, when C/S ratio exceeds 0.75, DSC has comparable or even better engineering properties compared to NSC. In the range ofinvestigated C/S ratio, DSC has comparable tensile splitting strength and elastic modulus to its reference NSC.Based on the experimental results, the Australia dune sand can be used as fine aggregate whenever mix proportions are properly controlled.

The properties of fly ash based geopolymer mortars made with dune sand

This paper reports the properties of fly ash based geopolymer mortars made with dune sand. The geopolymer mortars of different cation type, namely sodium based (Na), potassium based (K) and a mixed Na/K, were prepared with dune sand (DS) and river sand (RS). The corresponding geopolymer pastes were also prepared. A series of tests including compressive strength, modulus of elasticity, splitting tensile strength, microanalysis (using scanning electron microscopy), porosity (using mercury intrusion porosimetry), sorptivity and air void (using section analysis method) were carried out. The results showed a strong correlation between strength and porosity of geopolymeric materials. The addition of DS had influences on the chemical compositions and physical properties of geopolymer mortars. These influences were dependent on the type of cation. Based on the results of mechanical properties, DS can be utilised as the fine aggregate for the production of geopolymer based construction material.

Développement des bétons autoplaçants à faible teneur en poudre, Éco-BAP: formulation et performance

Abstract : Although concrete is a relatively green material, the astronomical volume of concrete produced worldwide annually places the concrete construction sector among the noticeable contributors to the global warming. The most polluting constituent of concrete is cement due to its production process which releases, on average, 0.83 kg CO[subscript 2] per kg of cement. Self-consolidating concrete (SCC), a type of concrete that can fill in the formwork without external vibration, is a technology that can offer a solution to the sustainability issues of concrete industry. However, all of the workability requirements of SCC originate from a higher powder content (compared to conventional concrete) which can increase both the cost of construction and the environmental impact of SCC for some applications. Ecological SCC, Eco-SCC, is a recent development combing the advantages of SCC and a significantly lower powder content. The maximum powder content of this concrete, intended for building and commercial construction, is limited to 315 kg/m[superscript 3]. Nevertheless, designing Eco-SCC can be challenging since a delicate balance between different ingredients of this concrete is required to secure a satisfactory mixture. In this Ph.D. program, the principal objective is to develop a systematic design method to produce Eco-SCC. Since the particle lattice effect (PLE) is a key parameter to design stable Eco-SCC mixtures and is not well understood, in the first phase of this research, this phenomenon is studied. The focus in this phase is on the effect of particle-size distribution (PSD) on the PLE and stability of model mixtures as well as SCC. In the second phase, the design protocol is developed, and the properties of obtained Eco-SCC mixtures in both fresh and hardened states are evaluated. Since the assessment of robustness is crucial for successful production of concrete on large-scale, in the final phase of this work, the robustness of one the best-performing mixtures of Phase II is examined. It was found that increasing the volume fraction of a stable size-class results in an increase in the stability of that class, which in turn contributes to a higher PLE of the granular skeleton and better stability of the system. It was shown that a continuous PSD in which the volume fraction of each size class is larger than the consecutive coarser class can increase the PLE. Using such PSD was shown to allow for a substantial increase in the fluidity of SCC mixture without compromising the segregation resistance. An index to predict the segregation potential of a suspension of particles in a yield stress fluid was proposed. In the second phase of the dissertation, a five-step design method for Eco-SCC was established. The design protocol started with the determination of powder and water contents followed by the optimization of sand and coarse aggregate volume fractions according to an ideal PSD model (Funk and Dinger). The powder composition was optimized in the third step to minimize the water demand while securing adequate performance in the hardened state. The superplasticizer (SP) content of the mixtures was determined in next step. The last step dealt with the assessment of the global warming potential of the formulated Eco-SCC mixtures. The optimized Eco-SCC mixtures met all the requirements of self-consolidation in the fresh state. The 28-day compressive strength of such mixtures complied with the target range of 25 to 35 MPa. In addition, the mixtures showed sufficient performance in terms of drying shrinkage, electrical resistivity, and frost durability for the intended applications. The eco-performance of the developed mixtures was satisfactory as well. It was demonstrated in the last phase that the robustness of Eco-SCC is generally good with regards to water content variations and coarse aggregate characteristics alterations. Special attention must be paid to the dosage of SP during batching.

Numerical simulation of fresh SCC flow in wall and beam elements using flow dynamics models

Abstract : Recently, there is a great interest to study the flow characteristics of suspensions in different environmental and industrial applications, such as snow avalanches, debris flows, hydrotransport systems, and material casting processes. Regarding rheological aspects, the majority of these suspensions, such as fresh concrete, behave mostly as non-Newtonian fluids. Concrete is the most widely used construction material in the world. Due to the limitations that exist in terms of workability and formwork filling abilities of normal concrete, a new class of concrete that is able to flow under its own weight, especially through narrow gaps in the congested areas of the formwork was developed. Accordingly, self-consolidating concrete (SCC) is a novel construction material that is gaining market acceptance in various applications. Higher fluidity characteristics of SCC enable it to be used in a number of special applications, such as densely reinforced sections. However, higher flowability of SCC makes it more sensitive to segregation of coarse particles during flow (i.e., dynamic segregation) and thereafter at rest (i.e., static segregation). Dynamic segregation can increase when SCC flows over a long distance or in the presence of obstacles. Therefore, there is always a need to establish a trade-off between the flowability, passing ability, and stability properties of SCC suspensions. This should be taken into consideration to design the casting process and the mixture proportioning of SCC. This is called “workability design” of SCC. An efficient and non-expensive workability design approach consists of the prediction and optimization of the workability of the concrete mixtures for the selected construction processes, such as transportation, pumping, casting, compaction, and finishing. Indeed, the mixture proportioning of SCC should ensure the construction quality demands, such as demanded levels of flowability, passing ability, filling ability, and stability (dynamic and static). This is necessary to develop some theoretical tools to assess under what conditions the construction quality demands are satisfied. Accordingly, this thesis is dedicated to carry out analytical and numerical simulations to predict flow performance of SCC under different casting processes, such as pumping and tremie applications, or casting using buckets. The L-Box and T-Box set-ups can evaluate flow performance properties of SCC (e.g., flowability, passing ability, filling ability, shear-induced and gravitational dynamic segregation) in casting process of wall and beam elements. The specific objective of the study consists of relating numerical results of flow simulation of SCC in L-Box and T-Box test set-ups, reported in this thesis, to the flow performance properties of SCC during casting. Accordingly, the SCC is modeled as a heterogeneous material. Furthermore, an analytical model is proposed to predict flow performance of SCC in L-Box set-up using the Dam Break Theory. On the other hand, results of the numerical simulation of SCC casting in a reinforced beam are verified by experimental free surface profiles. The results of numerical simulations of SCC casting (modeled as a single homogeneous fluid), are used to determine the critical zones corresponding to the higher risks of segregation and blocking. The effects of rheological parameters, density, particle contents, distribution of reinforcing bars, and particle-bar interactions on flow performance of SCC are evaluated using CFD simulations of SCC flow in L-Box and T-box test set-ups (modeled as a heterogeneous material). Two new approaches are proposed to classify the SCC mixtures based on filling ability and performability properties, as a contribution of flowability, passing ability, and dynamic stability of SCC.

Influência de polímeros superabsorventes na retracção de argamassas

Hoje em dia, o desenvolvimento dos superplastificantes permite a produção de betões com menor razão água/cimento. Ao usar razões água/cimento mais baixas, os materiais científicos apresentam maior tendência para fissurar devido à retracção autogénea. Este trabalho apresenta um estudo sobre a utilização de polímeros superabsorventes (SAP) no controlo da retracção. O uso de SAPs em materiais comentícios atenua a retracção autogénea pois estes produtos permitem o fornecimento interno de água. Estes produtos podem também afectar outras propriedades, afectando as características mecânicas e a trabalhabilidade. Para análise do efeito dos SAP foram estudadas argamassas com várias concentrações deste produto, tendo como referência argamassas semelhantes sem SAP, determinando-se as retracções autogénea e total, a resistência à compressão e o módulo de elasticidade. Além de SAP, foi também utilizado um agregado leve, um outro tipo de introdutor de água, para comparação com os polímeros em estudo. /ABSTRACT: This work presents a study on the use of superabsorbent polymers (SAP) in the control of shrinkage. The use of SAPs in cementitious materials reduces the autogenous shrinkage because these products enable the internal supply of water. These materials can also affect other properties such as mechanical properties and workability. To analyze the effect of SAP, mortars containing various concentrations of this product were studied, in comparison with reference mortars without SAP. The tests performed were autogenous and total shrinkage, compressive strength and modulus of elasticity. Besides SAP, it was also used a lightweight aggregate, another type of internal supply of water, for comparison with the polymers under study.

AGENDA AMBIENTAL DEL AGUA EN COSTA RICA

La crisis de gobcrnabilidad de los recursos hídricos es clara y evidente en Costa Rica. Estos recursos están en proceso de deterioro y peligrosamente amenazados. En tan solo cinco décadas se pasó de la riqueza y abundancia de agua, a la vulnerabilidad y escasez de ésta. Un conjunto de realidades ha originado la mencionada crisis: la ausencia de políticas hídricas integrales, claras y estables, un marco legal desactualizado. estático y de mínimo cumplimiento, que ha permitido el uso ineficiente y la contaminación de los cuerpos de agua y desde luego la cultura dominante de poca o ninguna valoración del agua como recurso vital para el desarrollo presente y futuro de todas las especies que poblamos el país.La Agenda Ambiental del Agua en Costa Rica ha sido elaborada mediante un proceso parlicipativo. donde diversos actores sociales en diferentes regiones —Limón, Liberia y la Gran Area Metropolitana (GAM)— priorizaron los 10 principales problemas y sus potenciales soluciones:1) La educación formal e informal es muy débil respecto a como alcanzar el uso eficiente e inteligente de los recursos hrdricos. Igualmente, es débil para revertir el patrón de manejo de vertidos sin responsabilidad social.2) La excesiva centralización de las decisiones. Muy poca participación ciudadana tanto en la estructura organizativa como en la toma de decisiones.3) La inoperancia del marco institucional y legal —desconocimiento por parte de la sociedad civil de los procesos de denuncia y otros; la tramitología de denuncia es demasiado lenta e ineficiente, razón por la cual los denunciantes se cansan y desaniman—.4) La deficiente y casi nula valoración económica del agua, que tome en cuenta el manejo integral de las cuencas y la búsqueda de la permanencia del recurso en el futuro.5) La ausencia de planes hídricos de cuencas donde el plan regulador sea un componente básico.6) La desigual calidad del agua para los costarricenses según operador del servicio y región geográfica.7) La contaminación de aguas superficiales y subterráneas.8) La ausencia de conocimiento, socialización, sistematización y movilización en relación con el manejo del agua. Es necesario el aumento de las capacidades tanto técnicas y científicas como de cambio de cultura y conocimiento popular.9) Falta de información básica y mecanismos claros para poder utilizarla.10) La información existente en la actualidad se encuentra dispersa en diferentes orgarnza ciones y en algunos investigadores, lo que impide su uso efectivo.La Agenda Ambiental del Agua en Costa Rica aproxima los costos para la solución de los problemas apuntados anteriormente. Se necesita invertir alrededor de US$J .500 millones para abordar la gestión integrada de los recursos hídricos en el país.Abstract: The crisis of governance of thc watcr resources is clear and evideni in Costa Rica. These resources are in proccss oídeterioration anddangerously threatened. In only five decades it passed of che wealth and water abundance, to che vulnerability and shortagc of thc same one. A set of realities has originated dic mentioned crisis; dic abscncc of an integral, clear and siable water policy, a legal framework out of date. static one and of minimal fulfillmeni. which has allowed che inefficicrn use and ihe pollution ofihe water bodies. And certainly. hc dominecring culture of small ci no valuation to the water as vital resource for thc prcscnt and future dcvclopment of alI dic species. thai we populate che country.The Environmental Agenda of the Water in Costa Rica has bccn claborated by means of a participatory proccss. which includes several social actors in diverse regions —Limon. Liberia and Great Metropolitan Area (GAM) These actors prioritized lO principal problems related to water resources and thcir potential solutions:1) The formal and informal education is very weak with regard to since as reaches the efficient and intelligeni use of thc water resources. Equally. dic boss of managing is weak for revert of spilt without social responsibilicy.2) The excessive centralization of che decisions with very little civil parlicipation. both in the organizational siructure and in the decision making process.3) The un.workability of ihe institutional and legal framewoik —ignorance cii che pan of civil society of che proces.ses of denunciation and others the denunciation niechanism is ioo slow and inefticieni, a reason for which dic cbtmants get tired and discouragc—.4) Thedeficientone and almosi voideconomic valuationofthe waier. which bears in mmd the integral managing of the basin and dic scarc h of dic permancncy of dic resource to future.5) Thc absence of water plans of basin where dic regulatory plan is a basic component.6) The unequal quality of the water for dic Costa Ricans according tooperacor of dic service and geographica] region.7) The pollution of superficial and underground waters.8) The absence of knowledgc. socializ.arion, systematizing and mobilization in relation co the waier managing. Thc increase of dic capacities is necessary so much tcchnical and scicntific like of change of culture and popular knowledge.9) Lack of basic information and clear mechanisms to be able to use it.10) Thc cxisting information aL preseni is dispersed in different organizations and in sorne investigators, which prevents ihe effective use of the same one.The Environmental Agenda of the Water in Costa Rica brings the costs near for the solution of the pointed problems previously. Costa Rica needs to invest about US$1.500 million Lo approach ihe integrated managcment of the water resources in the country.