A comparative study of insoluble and soluble polyimide thin films

Physical properties of thin films of soluble and insoluble aromatic polyimides were compared by d.s.c., u.v.-visible and fluorescence spectroscopy, and prism coupler technique. D.s.c. results showed that the thermal properties of insoluble polyimides are superior to those of soluble ones, owing to the specific molecular interactions of insoluble polyimides, revealed by fluorescence spectroscopy. However, the specific molecular interactions sacrifice the transparency in their thin films, shown by u.v.-visible transmission spectra. Negative birefringence of thin films, not only for soluble polimides but also for polyamic acids of insoluble polyimides, was confirmed by prism coupler, while thin films of insoluble polyimides thermally imidized lack high levels of negative birefringence. It is regarded that thin films of insoluble polyimides thermally imidized are likely to be isotropic because of molecular relaxation above their glass transition temperatures (T-g) in the course of thermal imidization, according to Flory's principle. On the contrary, thin films of insoluble poyimide chemically imidized keep the same levels of negative birefringence as those of the relevant polyamic acid thin films. Judging from the opposite cases, it is recognized that molecular relaxation above T-g weakens the optical anisotropy of polyimide thin films. (C) 1998 Elsevier Science Ltd. All rights reserved.

A European Perspective on the Precautionary Principle, Food Safety and the Free Trade Imperative of the WTO

A European Perspective on the Precautionary Principle, Food Safety and the Free Trade Imperative of the WTO. European Law Review, Vol.27, No.2. April 2002, pp.138-155. RAE2008

Rethinking cognition as the sole basis for determining Criminal Liability under the Manifest Illegality Principle

Olusanya, Olaoluwa, Rethinking cognition as the sole basis for determining Criminal Liability under the Manifest Illegality Principle, In: 'Rethinking International Criminal Law: The Substantive Part', Europa Law Publishing, pp.67-87, 2007. RAE2008

The Principle of Double Effect and Terminal Sedation

Williams, Glenys, 'The Principle of Double Effect and Terminal Sedation', Medical Law Review, 9 (2001), pp.41-53 RAE2008

"Networking is IPC": A Guiding Principle to a Better Internet

This position paper outlines a new network architecture, i.e., a style of construction that identifies the objects and how they relate. We do not specify particular protocol implementations or specific interfaces and policies. After all, it should be possible to change protocols in an architecture without changing the architecture. Rather we outline the repeating patterns and structures, and how the proposed model would cope with the challenges faced by today's Internet (and that of the future). Our new architecture is based on the following principle: Application processes communicate via a distributed inter-process communication (IPC) facility. The application processes that make up this facility provide a protocol that implements an IPC mechanism, and a protocol for managing distributed IPC (routing, security and other management tasks). Existing implementation strategies, algorithms, and protocols can be cast and used within our proposed new structure.

The feminine soul: love, courage, and sacrifice in three centuries of vocal repertoire

Music is a unique form of communication. It sings from soul to soul, touching each of us in uniquely different ways. While researching the life of Clara Schumann, I became intrigued with the idea that feminine qualities, as expressed by her music, could be found in other composers work for the soprano voice. I explored this possibility in a lecture recital and followed up this work by performing two operatic roles and a recital.