Major ion concentrations in rain water and atmospheric moisture above the Atlantic Ocean

Concentratios of Cl-, Mg2+, Ca2+, and HCO3- ions were studied in rain waters and condensed atmospheric moisture above the Atlantic Ocean. Maximal number of samples was collected in the eastern tropical North Atlantic. Concentration of chloride ions ranged from 1 to 28 mg/l in rain waters (average 4.3 mg/l) and ranged from 0.3 to 2 mg/l in condensed atmospheric moisture with the average about one order of magnitude less than that for rain waters. Chloride normalized concentrations of magnesium and calcium are greater in rain waters and condensed atmospheric moisture than in ocean water due to more intensive subtraction of these ions as compared to chloride ions. Chloride normalized HCO3- concentration is one order of magnitude greater in atmospheric moisture than in seawater, possibly because of volatile component CO2 taking part in exchange between the ocean and the atmosphere.

Stable isotope record of planktonic foraminifera of the South Atlantic

The central problem of late Quaternary circulation in the South Atlantic is its role in transfer of heat to the North Atlantic, as this modifies amplitude, and perhaps phase, of glacialinterglacial fluctuations. Here we attempt to define the problem and establish ways to attack it. We identify several crucial elements in the dynamics of heat export: (1) warm-water pile-up (and lack thereof) in the Western equatorial Atlantic, (2) general spin-up (or spin-down) of central gyre, tied to SE trades, (3) opening and closing of Cape Valve (Agulhas retroflection), (4) deepwater E-W asymmetry. Means for reconstruction are biogeography, stable isotopes, and productivity proxies. Main results concern overall glacial-interglacial contrast (less pile-up, more spin-up, Cape Valve closed, less NADW during glacial time), dominance of precessional signal in tropics, phase shifts in precessional response. To generate working hypotheses about the dynamics of surface water circulation in the South Atlantic we employ Croll's paradigm that glacial - interglacial fluctuations are analogous to seasonal fluctuations. Our general picture for the last 300 kyrs is that, as concerns the South Atlantic, intensity of surface water (heat) transport depends on the strength of the SE trades. From various lines of evidence it appears that strenger SE trades appeared during glacials and cold substages during interglacials, analogous to conditions in southern winter (August).

Planktonic foraminiferal d18O values and apparent calcification depths of core-top samples along an east-west transect across the tropical Atlantic/Caribbean

D18O values of nine tropical-subtropical planktonic foraminiferal species with different preferential habitat depths collected from 62 core-top samples along an east-west transect across the tropical Atlantic/Caribbean were used to test the applicability of interspecific d18O gradients for reconstructions of tropical upper ocean stratification. In general, the d18O difference (Delta d18O) between intermediate- and shallow-dwelling species decreases, and Delta d18O between deep and intermediate dwellers increases with increasing thermocline depth towards the west. The statistical significance of regional differences in Delta d18O highlights Delta d18O between the intermediate dwellers (in particular Globorotalia scitula and Globorotalia tumida) and the shallow dweller Globigerinoides ruber pink, as well as Delta d18O between the deep dwellers Globorotalia crassaformis or Globorotalia truncatulinoides dextral and intermediate dwellers as most sensitive to changes in tropical Atlantic thermocline depth. Based on the observed regional variations in interspecific Delta d18O, we propose a multispecies stratification index "STRAtrop" = (d18Ointermediate - d18Oshallow) / (d18Odeep - d18Oshallow) for the tropical ocean. Statistically significant differences in STRAtrop values between the E-Atlantic and the Caribbean suggest that this index may be a useful tool to monitor variations in tropical upper ocean stratification in the geological record.