847 resultados para DIN


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Desde os primórdios da humanidade, a descoberta do método de processamento cerebral do som, e consequentemente da música, fazem parte do imaginário humano. Portanto, as pesquisas relacionadas a este processo constituem um dos mais vastos campos de estudos das áreas de ciências. Dentre as inúmeras tentativas para compreensão do processamento biológico do som, o ser humano inventou o processo automático de composição musical, com o intuito de aferir a possibilidade da realização de composições musicais de qualidade sem a imposição sentimental, ou seja, apenas com a utilização das definições e estruturas de música existentes. Este procedimento automático de composição musical, também denominado música aleatória ou música do acaso, tem sido vastamente explorado ao longo dos séculos, já tendo sido utilizado por alguns dos grandes nomes do cenário musical, como por exemplo, Mozart. Os avanços nas áreas de engenharia e computação permitiram a evolução dos métodos utilizados para composição de música aleatória, tornando a aplicação de autômatos celulares uma alternativa viável para determinação da sequência de execução de notas musicais e outros itens utilizados durante a composição deste tipo de música. Esta dissertação propõe uma arquitetura para geração de música harmonizada a partir de intervalos melódicos determinados por autômatos celulares, implementada em hardware reconfigurável do tipo FPGA. A arquitetura proposta possui quatro tipos de autômatos celulares, desenvolvidos através dos modelos de vizinhança unidimensional de Wolfram, vizinhança bidimensional de Neumann, vizinhança bidimensional Moore e vizinhança tridimensional de Neumann, que podem ser combinados de 16 formas diferentes para geração de melodias. Os resultados do processamento realizado pela arquitetura proposta são melodias no formato .mid, compostas através da utilização de dois autômatos celulares, um para escolha das notas e outro para escolha dos instrumentos a serem emulados, de acordo com o protocolo MIDI. Para tal esta arquitetura é formada por três unidades principais, a unidade divisor de frequência, que é responsável pelo sincronismo das tarefas executadas pela arquitetura, a unidade de conjunto de autômatos celulares, que é responsável pelo controle e habilitação dos autômatos celulares, e a unidade máquina MIDI, que é responsável por organizar os resultados de cada iteração corrente dos autômatos celulares e convertê-los conforme a estrutura do protocolo MIDI, gerando-se assim o produto musical. A arquitetura proposta é parametrizável, de modo que a configuração dos dados que influenciam no produto musical gerado, como por exemplo, a definição dos conjuntos de regras para os autômatos celulares habilitados, fica a cargo do usuário, não havendo então limites para as combinações possíveis a serem realizadas na arquitetura. Para validação da funcionalidade e aplicabilidade da arquitetura proposta, alguns dos resultados obtidos foram apresentados e detalhados através do uso de técnicas de obtenção de informação musical.

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Feeding experiments were conducted on the postlarvae of Channa striatus with two different live feeds - a copepod (Thermocyclops decipiens) and cladocerans (Moina micrura and Ceriodaphnia comuta) individually and in mixture. Food was provided at the rate of (500±50 Ind/L) and the experiments were carried out in 100 litre capacity tanks for 30 days. Results indicated better weight gain (951.85±28.77%) and survival (92.00<%) of postlarvae fed with mixed live food than individual live feed organisms.

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Sefid-Rood River Estuary (SRE) is the most important riverine ecosystem in the south Caspian Sea along the Iranian coast lines. The aim of this study was to examine spatial and temporal variability in Phytoplankton and Zooplankton abundance and diversity in SRE. Variability of Chlorophyll a and inorganic nutrient concentration were determined during a year (November 2004– October 2005) in five sampling stations. Primary and secondry production were determined during a year. Total chlorophyll a concentration during the investigation ranged between zero to 22.8 μgl-1 and the highest levels were consistently recorded during summer and the lowest during winter with a annual mean concentration 4.48 μgl-1. Nutrient concentration was seasonally related to river flow with annual mean concentration: NO2 0.05±0.2 mgl-1, NO3 1.13±0.57 mgl-1, NH4 0.51±0.66 mgl-1, total phosphate 0.13±0.1mgl-1 and SiO2 5.68±1.91 mgl-1. Bacillariophytes, Cyanophytes, Chlorophytes, Pyrophytes and Euglenophytes were the dominant phytoplankton groups in this shallow and turbid estuary. The diversity and abundance of phytoplankton had a seasonal pattern while Diatomas and Chrysophytes were dominant throughout the year but Cyanophytes observed only during the summer. Zooplankton community structure was dominated by copepods which 68% of the total zooplankton. In the winter and summer seasons two increased in the number of zooplankton community and usually toward the sea had occurred. Zooplankton also showed a significant spatial and temporal variation. The high turbidity and temperature prime characteristics of SRE seem to be determining factors acting directly on phytoplankton and zooplankton temporal variability and nutrient fluctuations. Everywhere in this estuary nutrients appeared to be in excess of algal requirement and did not influence a phytoplankton and zooplankton composition. Also there was a positive correlation between chlorophyll a and temperature and a negative one with DIN and TP. Primary production determined in this estuary by dark and light butter method and G.P.P. 38.27±34.12 mgcm-2h-1 and N,PP 201.6±289.9 mgcm-2d-1. secondry production determined 15/128 mgc/m3/year. Everywhere in this estuary nutrients appeared to be in excess to algal requirement and did not influence in Chl. a and primary production. The most important factor influence on Chl. a was water temperature.

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The physical meaning and methods of determining loudness were reviewed Loudness is a psychoacoustic metric which closely corresponds to the perceived intensity of a sound stimulus. It can be determined by graphical procedures, numerical methods, or by commercial software. These methods typically require the consideration of the 1/3 octave band spectrum of the sound of interest. The sounds considered in this paper are a 1 kHz tone and pink noise. The loudness of these sounds was calculated in eight ways using different combinations of input data and calculation methods. All the methods considered are based on Zwicker loudness. It was determined that, of the combinations considered, only the commercial software dBSonic and the loudness calculation procedure detailed in DIN 45631 using 1/3 octave band levels filtered using ANSI S1.11-1986 gave the correct values of loudness for a 1 kHz tone. Comparing the results between the sources also demonstrated the difference between sound pressure level and loudness. It was apparent that the calculation and filtering methods must be considered together, as a given calculation will produce different results for different 1/3 octave band input. In the literature reviewed, no reference provided a guide to the selection of the type of filtering that should be used in conjunction with the loudness computation method.

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Algal bloom phenomenon was defined as "the rapid growth of one or more phytoplankton species which leads to a rapid increase in the biomass of phytoplankton", yet most estimates of temporal coherence are based on yearly or monthly sampling frequencies and little is known of how synchrony varies among phytoplankton or of the causes of temporal coherence during spring algal bloom. In this study, data of chlorophyll a and related environmental parameters were weekly gathered at 15 sampling sites in Xiangxi Bay of Three-Gorges Reservoir (TGR, China) to evaluate patterns of temporal coherence for phytoplankton during spring bloom and test if spatial heterogeneity of nutrient and inorganic suspended particles within a single ecosystem influences synchrony of spring phytoplankton dynamics. There is a clear spatial and temporal variation in chlorophyll a across Xiangxi Bay. The degree of temporal coherence for chlorophyll a between pairs of sites located in Xiangxi Bay ranged from -0.367 to 0.952 with mean and median values of 0.349 and 0.321, respectively. Low levels of temporal coherence were often detected among the three stretches of the bay (Down reach, middle reach and upper reach), while high levels of temporal coherence were often found within the same reach of the bay. The relative difference of DIN between pair sites was the strong predictor of temporal coherence for chlorophyll a in down and middle reach of the bay, while the relative difference in Anorganic Suspended Solids was the important factor regulating temporal coherence in middle and upper reach. Contrary to many studies, these results illustrate that, in a small geographic area (a single reservoir bay of approximately 25 km), spatial heterogeneity influence synchrony of phytoplankton dynamics during spring bloom and local processes may override the effects of regional processes or dispersal.

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The concentrations of major anions and cations, nitrogen and phosphorus, dissolved and particulate trace elements, and organic pollutants were determined for the middle and lower reaches of the Yangtze River (Changjiang) from below the Three Gorges Dam (TGD) to the mouth at Shanghai in November 2006. The concentration of dissolved inorganic phosphate (DIP) was constant at a low level of 6-8 mu gP/L, but the concentration of nitrate (NO3-) approximately doubled downstream and was closely correlated with K+. This translated to a daily load of well over 1000 It of dissolved inorganic nitrogen (DIN) at Datong. The average concentrations of dissolved Pb (0.078 +/- 0.023 mu g/L), Cd (0.024 +/- 0.009 mu g/L), Cr(0.57 +/- 0.09 mu g/L), Cu (1.9 +/- 0.7 mu g/L), and Ni (0.50 +/- 0.49 mu g/L) were comparable with those in other major world rivers, while As (3.3 +/- 1.3 mu g/L) and Zn (1.5 +/- 0.6 mu g/L) were higher by factors of 5.5 and 2.5, respectively. The trace element contents of suspended particles of As (31 +/- 28 mu g/g), Pb (83 +/- 34 mu g/g), and Ni (52 +/- 16 mu g/g) were close to maximum concentrations recommended for rivers by the European Community (EC). The average concentrations of Cd (2.6 +/- 1.6 mu g/g), Cr (185 +/- 102 mu g/g), Cu (115 +/- 106 mu g/g), and Zn (500 +/- 300 mu g/g) exceeded the EC standards by a factor of two, and Hg (4.4 +/- 4.7 mu g/g) by a factor of 4 to 5. Locally occurring peak concentrations exceed these values up to fourfold, among them the notorious elements As, Hg, and Tl. All dissolved and particulate trace element concentrations were higher than estimates made twenty years ago [Zhang, J., Geochemistry of trace metals from Chinese river/estuary systems: an overview. Estuar Coast Shelf Sci 1995; 41: 631-658.]. The enormous loads of anthropogenic pollutants disposed to the river were diluted by the large water discharge of the Yangtze even during the lowest flow resulting in the relatively low concentration levels of trace elements and organic pollutants observed. We estimated loads of e.g. As, Pb and Ni to the East China Sea to be about 4600 kg As d(-1), 3000 kg Pb d(-1), and 2000 kg Ni d(-1). About 6000 t d(-1) of dissolved organic carbon (DOC) was delivered into the sea at the time of our cruise. We tested for 236 organic pollutants, and only the most infamous were found to be barely above detection limits. We estimated that the load of chlorinated compounds, aromatic hydrocarbons, phenols, and PAHs were between 500 and 3500 kg d(-1). We also detected eight herbicides entering the estuary with loads of 5-350 kg d(-1). The pollutant load, even when at low concentrations, are considerable and pose an increasing threat to the health of the East China Sea ecosystem. (c) 2008 Elsevier B.V. All rights reserved.

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The spatial and temporal dynamics of physical variables, inorganic nutrients and phytoplankton chlorophyll a were investigated in Xiangxi Bay from 23 Feb. to 28 Apr. every six days, including one daily sampling site and one bidaily sampling site. The concentrations of nutrient variables showed ranges of 0.02-3.20 mg/L for dissolved silicate (Si); 0.06-2.40 mg/L for DIN (NH4N + NO2N + NO3N); 0.03-0.56 mg/L for PO4P and 0.22-193.37 mu g/L for chlorophyll a, respectively. The concentration of chlorophyll a and inorganic nutrients were interpolated using GIS techniques. The results indicated that the spring bloom was occurred twice in space during the whole monitoring period (The first one: 26 Feb.-23 Mar.; the second one: 23 Mar.-28 Apr.). The concentration of DIN was always high in the mouth of Xiangxi Bay, and PO4P was high in the upstream of Xiangxi Bay during the whole bloom period. Si seems no obvious difference in space in the beginning of the spring bloom, but showed high heterogeneity in space and time with the development of spring bloom. By comparing the interpolated maps of chlorophyll a and inorganic variables, obvious consumptions of Si and DIN were found when the bloom status was serious. However, no obvious depletion of PO4P was found. Spatial regression analysis could explained most variation of Chl-a except at the begin of the first and second bloom. The result indicated that Si was the factor limiting Chl-a in space before achieved the max area of hypertrophic in the first and second bloom period. When Si was obviously exhausted, DIN became the factor limiting the Chl-a in space. Daily and bidaily monitoring of Site A and B, representing for high DIN: PO4P ratio and low DIN:PO4P ratio, indicated that the concentration of Si was decreased with times at both site A and B, and the dramatically drop of DIN was found in the end monitoring at site B. Multiple stepwise regression analysis indicated that Si was the most important factor affect the development of spring bloom both at site A and B in time series.

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Waste cooking oil (WCO) is the residue from the kitchen, restaurants, food factories and even human and animal waste which not only harm people's health but also causes environmental pollution. The production of biodiesel from waste cooking oil to partially substitute petroleum diesel is one of the measures for solving the twin problems of environment pollution and energy shortage. In this project, synthesis of biodiesel was catalyzed by immobilized Candida lipase in a three-step fixed bed reactor. The reaction solution was a mixture of WCO, water, methanol and solvent (hexane). The main product was biodiesel consisted of fatty acid methyl ester (FAME), of which methyl oleate was the main component. Effects of lipase, solvent, water, and temperature and flow of the reaction mixture on the synthesis of biodiesel were analyzed. The results indicate that a 91.08% of FAME can be achieved in the end product under optimal conditions. Most of the chemical and physical characters of the biodiesel were superior to the standards for 0(#)diesel (GB/T 19147) and biodiesel (DIN V51606 and ASTM D-6751).

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Acid oil, which is a by-product in vegetable oil refining, mainly contains free fatty acids (FFAs) and acylglycerols and is a feedstock for production of biodiesel fuel now. The transesterification of acid oil and methanol to biodiesel was catalyzed by immobilized Candida lipase in fixed bed reactors. The reactant solution was a mixture of acid oil, water, methanol and solvent (hexane) and the main product was biodiesel composed of fatty acid methyl ester (FAME) of which the main component was methyl oleate. The effects of lipase content, solvent content, water content temperature and flow velocity of the reactant on the reaction were analyzed. The experimental results indicate that a maximum FAME content of 90.18% can be obtained in the end product under optimum conditions. Most of the chemical and physical properties of the biodiesel were superior to the standards for 0(#) diesel (GB/T 19147) and biodiesel (DIN V51606 and ASTM D6751).

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LnCl(3) reacted with C6H5CH2C5H4Na in THF (tetrahydrofuran) in the ratio 1.1 at room temperature for 1 h giving C(6)H(5)CH(2)C(6)H(4)LnCl(2) . nTHF, which reacted with C8H8K2/THF and the crystals obtained were recrystallized in DME to yield the title complex. The crystal structure of (C8H8) Ln (C6H5CH2C5H4). DME was determined revealing that the Gd complex has one conformation. One benzylcyclopentadienyl (eta(5)), one cyclooctatetraenyl (eta(8)) and the two oxygen atoms of DME (dimethoxyethane) are coordinated to Gd with the effective coordination number of 10.

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The impact of the Huanghe (Yellow) River outflows on its estuary was investigated with river gauging and shipboard hydrographic observations. The river flux has been decreasing dramatically; the discharges of water and sediment in the 1990s dropped to 27.4% and 31.9% of those in the 1950s, respectively, resulting in frequent and lengthy events of downstream channel dry-up since the 1970s. There were accumulatively 897 zero-flow days during the 1990s in the river course below the Lijin Hydrological Station, 100 km upstream from the river mouth, which is 82.4% of that in 1972. As freshwater input decreases, river-borne nutrients to the estuarine increased significantly. Concentration of dissolved inorganic nitrogen (DIN) in the 1990s was four times of that in 1950s. Changes in amount and content of the riverine inputs have greatly affected the estuarine ecosystem. Over the past several decades, sea surface temperature and salinity in the estuary and its adjacent waters increased and their distribution pattern altered in response to the reduction of freshwater inflow. The distribution of and seasonal succession in nutrient concentrations in the surface layer have also changed with a shift of river outlet and the decrease in riverine nutrient loads. Furthermore, deterioration of estuarine ecosystem by less river input has decreased primary productivity in the deltaic region waters, and in turn depressed the fishery. (C) 2008 Published by Elsevier Ltd.

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沿海工农业生产的快速发展和人类活动对近海生态系统产生了很大影响,大量化肥的使用和工业污水、生活污水的排放导致近海环境污染,海水富营养化,赤潮频发。另外,由于近海养殖活动的迅猛发展以及养殖的不规范和不科学性导致近海生态系统结构和功能改变,一方面加重了海水富营养化,另一方面养殖动植物病害经常发生,严重影响了海产品的质量和效益。 大型海藻是海区重要的初级生产者,生命周期长、生长快,能通过光合作用吸收固定水体的C、N、P等营养物质来合成自身,同时增加水体溶解氧。因此,大型海藻被称为海洋环境中的生物过滤器。另外,由于大型藻类自身营养成分的复杂性和与藻共生的微生物多样性,大型海藻还可对生态系统中的浮游生物和微生物产生直接和间接影响。 在海洋环境,尤其是海水养殖水体环境存在着两个主要问题:海水富营养化和病源微生物控制,本文针对海洋环境中存在的这两个问题进行了探索研究。 以大型经济藻种长心卡帕藻(Kappaphycus alvarezzi)作为实验材料,分别在实验室内、室外藻类处理系统和海湾养殖现场三种条件下,进行藻类去除海水氮磷的一次性实验、半连续实验和连续实验,研究了其对海水中无机氮、无机磷的吸收速率和去除能力,初步评估了其生态价值。 构建了一种半封闭海域富营养化治理模式,以长心卡帕藻为实验材料,研究了其去除海水富营养化的能力,主要结果如下: (1)室内实验研究发现,长心卡帕藻对氮、磷的吸收速率随底物浓度升高而升高。在氮磷比为10:1,温度28℃条件下,氮浓度为50μmol • L-1时,藻对氮、磷的吸收速率达到最大,分别为0.93µmol • g-1(FW)• h-1和0.072µmol • g-1(FW)• h-1。 (2)人工修建的藻类养殖系统中进行的长心卡帕藻去除氮、磷的半连续实验,结果表明该藻具有连续去除海水DIN、DIP的能力。只要保持足够的底物浓度,长心卡帕藻对无机氮、无机磷的吸收速率达到最大,分别为0.3µmol • g-1(FW) • h-1和0.03µmol • g-1(FW)• h-1。但是对氮磷的吸收速率较室内实验有所降低。 (3)自然条件下,通过调查黎安海湾水质情况发现,长心卡帕藻具有较大的生态效益。在整个海湾大面积养殖卡帕藻,通过收获藻体,每年大约可以从海水中带走33吨氮素,7.5吨磷素。由于在海湾长心卡帕藻的作用,全年海湾水质保持在1-2级国家海水质量标准,产生了明显的生态效益。 另外,我们对大型藻类浒苔(Ulva clathrata)吸收氮磷和抑制鳗弧菌(Vibrio anguillarum)的效果进行了初步探索,结果表明:浒苔不仅对培养系统内无机氮和磷具有明显的去除作用,而且在异养细菌总量没有降低的情况下,对鳗弧菌有显著抑制作用,该抑制作用还受到水体中氮磷营养盐浓度的影响。在10g • L-1海藻的条件下,鳗弧菌以105-107 cfu • mL-1接入2天后,无论是否添加外源氮磷,鳗弧菌密度降到10 cfu • mL-1以下,鳗弧菌去除率几乎达到100%。实验数据还显示,添加氮磷营养盐可以增强浒苔对鳗弧菌的抑制作用,但没有降低其中的异养菌群数量,系统内异养细菌总量均维持在较高水平。进一步研究表明,培养浒苔24h后的海水,也对鳗弧菌65#产生抑制作用,这说明浒苔代谢释放到水体中某种化学成分或与藻共栖的微生物对鳗弧菌生长产生了抑制。

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滤食性贝类以水体中的浮游植物和有机碎屑为主要食物,养殖海域的初级生产力水平、水动力学特性等生态环境因子的差异,不仅直接影响养殖贝类的产量,而且也与贝类养殖活动对生态环境的压力密切相关。由于养殖的种类、密度、方式及养殖海域的特性不同,关于贝类对生态环境的影响往往有不同的结果。本文以我国北方大连獐子岛扇贝底播海区和荣成桑沟湾贝类筏式养殖区为研究对象,采用现场调查、室内受控实验及生态数值模型模拟方法,分析研究了滤食性贝类对海域生态系统的影响,对这两个海域贝类养殖的生态容量进行了初步的评价。 主要结果: 1. 獐子岛海域底播贝类养殖活动对该海域生态系统的影响较小。非参数统计—符号检验的结果显示,养殖区与非养殖区之间的溶解性无机氮、磷酸盐浓度、氮磷摩尔比及浮游植物群落结构没有统计学上的差异(p>0.05)。但是从变化的趋势上来看,贝类养殖活动对水域环境的某些参数有一定程度的影响。例如,獐子岛底播贝类养殖海域的溶解性无机氮以氨氮为主,可能与贝类的代泄活动有关;不论是叶绿素浓度,还是网采浮游植物的生物量都是贝类高密度养殖区<贝类低密度养殖区<非养殖区(7月份除外),这种趋势可能与贝类的摄食压力有关。 桑沟湾各环境指标表现出明显的区域性。除春季外,非养殖区的DIN浓度高于各养殖区。在春季和冬季,贝类区的磷酸盐浓度显著降低;而硅酸盐浓度在夏季和秋季显著增大。综合分析DIN、PO4-P及SiO3-Si三个参数的四季变化,海带区、贝藻区及贝类区发生显著性变异的概率分别为25%,42%和50%,贝类区的变异较大。浮游植物、小型浮游动物的生物多样性指数都是以非养殖区为最高,贝类区的多样性指数最低。尤其是浮游动物的丰度,贝类区显著低于非养殖区。 2. 利用挪威的MOM (Modelling-Ongrowing fish farms-Monitoring)评价系统,评价了桑沟湾长期大规模的贝藻筏式养殖活动对底质环境的压力。在桑沟湾设10个取样站位,共获得66个底泥样品。比较了MOM-B评价系统的3组参数的季节变化特性。结果显示,底质条件属于1级,说明桑沟湾贝藻长期大规模的养殖活动对底质环境的压力较低。结合桑沟湾的环境及养殖特点,分析了压力较低的原因。 3. 经计算,2006年中国海水养殖的贝类和藻类使用浅海生态系统的碳可达396万吨,并通过收获从海中移出至少136.9万吨的碳。从1995年至2006年,养殖大型藻类和贝类累计移出的碳分别约为365万吨和893万吨,总计达1258万吨。证明了浅海的贝类和藻类养殖活动直接或间接地使用了大量的海洋碳,提高了浅海生态系统吸收大气CO2的能力。 4. 采用模拟现场生物沉积法测定了虾夷扇贝的滤水率、摄食率等生理指标及其与贝类个体大小、水温的关系。虾夷扇贝单位个体的滤水率与组织干重的关系符合幂函数方程CR=a×DWb,b值在0.45~0.65范围内;水温对虾夷扇贝滤水率的影响极其显著(p<0.01),温度(T)与滤水率(CR)呈抛物线的关系:CR=-0.0009T2+0.0188T-0.0306,水温为10℃时,虾夷扇贝的滤水率、摄食较大。 5. 采用模拟现场流水法测定了3种滤食性贝类的食物选择性。紫贻贝、长牡蛎及栉孔扇贝分别对直径4m, 6m 和 8m颗粒的保留效率达到最大值;对小颗粒(直径2m)的保留效率分别为17%, 19% 和 8%。栉孔扇贝对食物数量和质量浓度的变化相对敏感,随着数量浓度的增加,栉孔扇贝倾向于摄食较大的颗粒;随着颗粒食物质量浓度的增加,倾向于摄食较小的颗粒。 6. 獐子岛海域四个航次的调查结果显示,叶绿素浓度在1.23~2.85mg.m-3范围内,均值为1.78±0.57 mg.m-3;初级生产力的变化范围为30.4~117.0 mg C. m-2.d-1,平均值为76.6±41.9 mg C. m-2.d-1。通过虾夷扇贝生物量断面调查,获得了虾夷扇贝的壳高频率分布情况,7月份的众数值出现在100 mm,10月份壳高的众数值为80 mm。利用以上测定的虾夷扇贝的滤水率等基本生物学特性,结合虾夷扇贝的年产量、海域面积和有关的水文状况等数据,计算了滤水效率、摄食压力、调节比率3个食物限制性指标参数,全年的均值分别为0.048, 0.31和 0.16,都小于1,说明目前该海域虾夷扇贝的养殖量未达到养殖容量。 7. 利用STELLA软件,建立的桑沟湾贝藻养殖的数值模型,模拟了叶绿素a浓度及氮磷营养盐的周年变化情况,及其对贝类养殖生物量变化的响应。以叶绿素a浓度为指标,初步探讨了桑沟湾贝类的生态容量。

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本文以我国长江口水域富营养化为研究对象,对长江水体溶解态无机氮、磷分布特点和通量变化进行了分析,基于长江流域氮“输入-输出”关系模型探索了水体氮的来源;分析了长江口水域富营养化长期演变及特点;探索了长江口海域低氧区的发生机制。结果如下: 长江水体中NO3--N、NH4+-N、DIN和DIP浓度从上游往下游呈增加趋势,但存在季节差异。长江流域从上游往下游的DIN输送通量的变化主要受水流量的影响,但从上游往下游单位面积年产N量逐渐升高;DIP输送通量从上游往下游呈增加趋势,同时也主要受水流量控制,但从季节变化来讲,DIP的月输送通量受其浓度的控制更加明显。自20世纪60年代来,长江水体中NO3--N、NO2--N、DIN和DIP浓度都处于缓慢上升趋势,但到80年代上升速度明显加快;不同历史时期DIN和DIP的季节变化特点也不尽相同,反映出其来源的差异。同时,本研究采用长江流域氮“输入-输出”关系模型(污染负荷统计模型)对长江水体氮来源进行了分析,估算了各种氮源对水体氮的贡献率。结果表明,2006年向长江流域输入氮的总量为17.6 Tg,其中20%的输入氮转移到了水体(3.5 Tg)。本年度长江大通水文站实测氮输送通量为1.8 Tg,表明约50%的氮在水体输送过程中发生了生物、化学、物理损耗。对于长江水体氮的来源来讲,饲养牲畜粪便氮流失和大气干/湿沉降氮的贡献率较大,分别为26%和25%;农业氮肥流失和城市生活污水排放的贡献率相同,都为17%;农村人口粪便氮流失和工业废水排放的贡献率分别为6%和9%。 自20世纪60年代以来,长江口口门内和外海(盐度>30psu)水体中营养盐浓度增加显著。在表层水体盐度大于22psu海域DIN: PO43--P值表现出了明显升高的历史变化趋势。SiO3: PO43--P值从1959年到1985-86年显著下降,然后到2003-06年有所上升。根据SiO3: PO43--P值和DIN: PO43--P值的长期变化趋势,可以推出,SiO3: DIN值从20世纪50-60年代以后呈现下降趋势。在长江口海域,随着营养盐浓度的增加,浮游生物量的大幅度升高在本研究中得到证实。同时,长江口水域浮游植物种群结构对营养盐结构的长期变化产生响应,研究结果表明,硅藻种类比重从1985-86年84.6% 下降到2004-05年69.8%;年均硅藻丰度占浮游植物总丰度比重在1985-86年达到99.5%,但到2004-05年降低为75.5%,而甲藻丰度比重则由0.7%增大到25.4%。 底层水体DO浓度与Delta S(底层水体与表层水体的盐度之差)和Delta T(表层水体与底层水体的温度之差)成显著负相关,这表明了水体层化或者垂直水体交换是控制长江口水域底层水体溶解氧变化的主要因素,但水体温度层化要比盐度层化在控制低氧区形成上起到更大的作用。上升流在该海域低氧的形成和分布上起到很重要的作用,显著影响低氧水团的垂直分布,也显著影响到溶解氧的水平分布。现场生产的浮游植物可能是低氧区的形成的生物基础,日益增加的叶绿素a浓度和大规模的有害藻华可能是长江口低氧区逐渐增大的原因。本研究认为,此海域低氧区的形成主要受长江冲淡水、台湾暖流的入侵、地形、尤其是温跃层的形成和现场生产的有机物质控制。