N-arylamides from selenium-catalyzed reactions of nitroaromatics and amides in the presence of carbon monoxide and mixed organic bases

N-Arylamides were exclusively obtained in moderate to good yields from selenium-catalyzed reactions of nitroaromatics with amides in the presence of CO and mixed organic bases Et3N and DBU.

Ion recognition: application of symmetric and asymmetric schiff bases and their complexes for the fabrication of cationic and anionic membrane sensors to determine ions in real samples

Schiff base compounds refer to the branch of supra-molecules and can be used as sensing material in the construction of potentiometric ion selective electrodes (ISEs). This relatively modern field has been subject to extensive research in the period of 1999-2007 when more than 100 ISEs employing Schiff bases were constructed. The quantitative high-throughput detection of 29 cations and 7 anions has been demonstrated in various scientific branches, such as biomedicine, pharmacy, biochemistry, pharmacology, environmental chemistry, food technology, and agriculture. This review discusses Schiff base compounds and their applications in the design and development of ion selective sensors and microsensors.

Syntheses and crystal structures of four new organotin complexes with Schiff bases containing triazole

Four new organotin complexes, namely [(Bu2Sn)(2)O(EtO)(L1)](2) (1), [(Bu2Sn)(2)O(EtO)(L2)](2) (2), [(Bu2Sn)(2)O(EtO)(L-3)](2) (3) and [Ph3Sn(L4)]center dot 0.5H(2)O (4), were obtained by reactions of Bu2SnO and Ph3SnOH with 4-phenylideneamino-3-methyl-1,2,4-triazole-5-thione (HL1), 4-furfuralideneamino-3-methyl-1,2,4-triazole-5-thione (HL2), 4-(2-thienylideneamino)-3-ethyl-1,2,4-triazole-5-thione (HL3) and 4-(3,5-di-t-butylsalicylideneamino)-3-ethyl-1,2,4-triazole-5-thione (HL4). Compounds 1-4 were characterized by elemental analysis, IR spectra and their structures were determined by single-crystal X-ray diffraction methods. Complexes 1-3 show similar structures containing a Sn4O4 ladder skeleton in which each of the exo tin atoms is bonded to the N atom of a corresponding thione-form deprotonated ligand. Complex 4 shows a mononuclear structure in which the tin atom of triphenyltin group is coordinated by the S atom of a thiol-form L4(-) anion.

Synthesis of a new series of chiral Schiff's bases and their copper complexes

A new series of chiral Schiff's bases containing 2-hydroxybenzilideneaniline moieties and their copper complexes were synthesized and studied by differential scanning calorimetry, polarized optical microscopy, X-ray diffraction and EPR measurement. The results show that most of the Schiff's bases and only two of the copper complexes exhibited chiral smectic liquid crystal phases.

Bromophenols coupled with nucleoside bases and brominated tetrahydroisoquinolines from the red alga Rhodomela confervoides

Three new bromophenols C-N coupled with nucleoside base derivatives (1-3) and three new brominated 1,2,3,4-tetrahydroisoquinolines (5-7, together with a new brominated tyrosine derivative (4, have been isolated from polar fractions of an ethanolic extract of the red alga Rhodomela confervoides. By spectroscopic and chemical methods including HRMS and 2D NMR data, their structures were determined as 7-[3-bromo-2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxybenzyl]-3,7-dihydro-1H-purine-2,6-dione (1), 7-(2,3-dibromo-4,5-dihydroxybenzyl)-3,7-dihydro-1H-purine-2,6-dione (2, 9-[3-bromo-2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxybenzyl]adenine (3), (-)-8S-(3-bromo-5-hydroxy-4-methoxy)phenylalanine (4), (-)-3S-8-bromo-6-hydroxy-7-methoxy-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid (5), methyl (-)-3S-8-bromo-6-hydroxy-7-methoxy-1,2,3,4-tetrahydroisoquinoline-3-carboxylate (6), and methyl (-)-3S-6-bromo-8-hydroxy-7-methoxy-1,2,3,4-tetrahydroisoquinoline-3-carboxylate (7). Compounds 5-7 were semisynthesized by using 4 as the starting material.

The synthesis and antioxidant activity of the Schiff bases of chitosan and carboxymethyl chitosan

Five kinds of Schiff bases of chitosan and carboxymethyl chitosan (CMCTS) have been prepared according to a previous method and the antioxidant activity was studied using an established system, such as superoxide and hydroxyl radical scavenging. Obvious differences between the Schiff bases of chitosan and CMCTS were observed, which might be related to contents of the active hydroxyl and amino groups in the molecular chains. (c) 2005 Elsevier Ltd. All rights reserved.

Antifungal properties of Schiff bases of chitosan, N-substituted chitosan and quaternized chitosan

Schiff bases of chitosan, N-substituted chitosan, and quaternized chitosan were synthesized and their antifungal properties were analyzed against Botrytis cinerea Pers. (B. cinerea pers.) and Colletotrichum lagenarium (Pass) Ell.et halst (C. lagenarium (Pass) Ell.et halst) based on the method of D. Jasso de Rodriguez and co-workers. The results showed that quaternized chitosan had better inhibitory properties than chitosan, Schiff bases of chitosan, and N-substituted chitosan. (c) 2007 Elsevier Ltd. All rights reserved.

Bases metodológicas para a reorganização da ocupação das terras do assentamento Cambucaes, Silva Jardim, RJ.

1999

Reflexões sobre a implantação de um programa de TI-Verde para a Embrapa: bases conceituais e metodológicas.

A Embrapa Informática Agropecuária, neste documento, oferece sua contribuição trazendo à tona uma reflexão sobre a implementação de um Programa de TI-Verde coorporativo. A ideia central é introduzir essa problemática no escopo das iniciativas de gestão ambiental que vêm sendo exercitadas pela empresa de maneira que sirva como um ponto de partida para se ampliar discussões sobre como a empresa pode produzir uma gestão sustentável dos recursos tecnológicos da informação.

Branqueamento Dentário

Projeto de Pós-Graduação/Dissertação apresentado à Universidade Fernando Pessoa como parte dos requisitos para obtenção do grau de Mestre em Medicina Dentária

Aplicação de MonetDB na avaliação de desempenho de bases de dados verticais

Dissertação apresentada à Universidade Fernando Pessoa como partes dos requisitos para a obtenção do grau de Mestre em Engenharia Informática, ramo de Sistemas de Informação e Multimédia

Réseaux et bases de données

info:eu-repo/semantics/published

Tolerancia a la inundación de especies gramíneas forrajeras megatérmicas : bases ecofisiológicas relacionadas con su instalación y producción

La inundación es un factor importante que afecta la implantación y producción de especies forrajeras en ecosistemas de pastizales anegables. Chloris gayana K. y Panicum coloratum L. son dos gramíneas tropicales cuyo uso como forrajera en ambientes templados se ha incrementado recientemente. En esta tesis se realizaron dos experimentos para evaluar la tolerancia de estas especies a eventos de inundación en los estadíos de plántula (implantación, Exp. 1) y de planta adulta (producción, Exp. 2). En el primer experimento plántulas de dos semanas de ambas especies fueron sometidas a tratamientos i) control, ii) sumersión parcial (SP) y iii) sumersión completa (SC) por 14 días, seguidos de un período de recuperación de 12 días. Ambas especies presentaron aerénquima constitutivo en sus raíces, que aumentó considerablemente bajo tratamientos de sumersión. La altura de plántulas sólo difirió de los controles en SC: C. gayana aumentó su altura rápidamente emergiendo del agua mientras P. coloratum no creció, manteniéndose siempre bajo el agua. La respuesta de "escape. exhibida por C. gayana se asoció a una asignación preferencial de biomasa hacia la parte aérea y un marcado alargamiento de las láminas foliares. P. coloratum no mostró cambios en la asignación de biomasa y sus hojas fueron más pequeñas. La biomasa final de C. gayana fue similar bajo SP y SC; mientras que P. coloratum redujo notablemente la biomasa bajo SC incluso al final del experimento, indicando que los daños provocados fueron persistentes. Así, C. gayana parece ser más prometedora para su implantación en pastizales propensos a inundaciones de mayor intensidad. En el segundo experimento se evaluó tolerancia a inundación de plantas adultas en diferentes momentos del ciclo de crecimiento (inundación invernal durante el reposo vegetativo vs. inundación primaveral durante el rebrote). Plantas de 10 meses (mayor a 30 cm altura) fueron sujetas a tratamientos (i) control (ii) inundación invernal por 50 días durante el reposo vegetativo (I), (iii) inundación primaveral por 20 días durante el rebrote (P) y (iv) inundación continua por 70 días (I+P). Luego, se dejaron crecer las plantas por 30 días para evaluar su recuperación. La inundación durante el invierno provocó una reducción del 43-57 por ciento en la biomasa aérea y radical de C. gayana; mientras que P. coloratum no fue afectado. C. gayana mostró una leve mejor tolerancia a la inundación primaveral en comparación a P. coloratum mientras que cuando fue inundada en ambos períodos se detectaron efectos aditivos depresores sobre su biomasa, efecto que en P. coloratum no fue registrado. Al final del período de recuperación las plantas de ambas especies lograron recuperarse completamente, alcanzando una biomasa equivalente a los controles independientemente del tratamiento previo de inundación. Estos resultados sugieren que ambas especies son tolerantes a la inundación en fase adulta, con un compromiso en la reducción de biomasa que no supera el 30 por ciento. Se concluye que ambas especies resultan promisorias para su introducción en los pastizales anegables de la Pampa Deprimida, destacándose C. gayana para sitios donde la intensidad de inundación puede comprometer la sumersión completa en las primeras fases del establecimiento de las plantas.