Preparation and characterization of the stable nc-Si/a-Si : H films

High-quality nc-Si/a-Si:H diphasic films with improved stability were prepared by using the plasma-enhanced chemical vapor deposition technology. In comparison with typical amorphous silicon, the diphasic silicon films possess higher photoconductivity (two orders larger than that of the amorphous silicon film) and fairly good photosensitivity(the ratio of the photo-to dark-conductivity is about 10) and higher stability (the degradation of the photoconductivity is less than 10% after 24h long light soaking with 50 mW/cm(2) intensity at room temperature). In addition, the diphasic silicon film has a better light spectra response in the longer wavelength range. The improvement in photoelectronic properties may be attributed to: the existence of the disorder within the amorphous matrix, which breaks the momentum selection rule in the optical transition and, consequently, results in the large light absorption coefficient and high photosensitivity; the improved medium range order and low gap states density. Excess carriers generated in the amorphous matrix tend to recombine in the embedded crystallites, which suppresses nonradiative recombination within the amorphous matrix and reduces the subsequent defect creation.

基于仿生模式识别的DOA估计方法

该文就仿生模式识别(拓扑模式识别)在非感性抽象对象的信息处理方面的应用作了一些探索,提出了一种基于仿生模式识别的DOA估计方法.这种方法的建模过程是用在实际环境下采集的训练样本构造人工神经网络模型,对环境的适应能力较强,且这种方法的计算量较小,可以实现系统实时处理.实验结果表明:在信噪比为20 dB和0 dB时,该方法的正确估计率可达100%;在信噪比降为-20 dB时,该方法仍有83%的可识别率.

稳定、优质nc-Si/a-Si:H薄膜的研制和特性分析

利用等离子体增强化学气相沉积技术研制出了优质稳定的氢化非晶-纳米晶两相结构硅薄膜.薄膜的光电导率相对于器件质量的非晶硅有两个数量级的提高;光敏性也较好,光、暗电导比可以达到104,此外薄膜的光电导谱具有更宽的长波光谱响应.更为重要的是薄膜的光致退化效应远小于典型的非晶硅薄膜,在光强为50mW/cm2的卤钨灯光照24h后,光电导的衰退小于10%.这种薄膜优良的光电性能源于薄膜中的非晶母体的存在使其在光学跃迁中的动量选择定则发生松弛,因而具有大的光学吸收系数和较高的光敏性;相对于典型非晶硅而言,薄膜的中程有序度得到了较大的改善,并具有小的深隙态密度;薄膜中存在的纳米尺寸的微晶颗粒,提供了光生载流子的复合通道,在非晶母体中的电子空穴对可以转移到微晶颗粒中进行复合,这样抑制了非晶母体中的非辐射复合,从而降低了光致亚稳缺陷产生的概率.

西安地区不同厚度土层土壤co2释放量的差异研究

IEECAS SKLLQG

pH值、碱类型及预停留时间对铁砷共沉淀物长期稳定性的影响

Fe(Ⅲ)-As(Ⅴ)共沉淀法作为一种经济的除砷方法,被广泛应用于处理有色冶金含砷废水。为防止处理后的含砷废渣二次污染,必须进一步研究其稳定性。本文通过室内模拟实验,研究了不同pH值、碱类型及在pH4条件下的预停留时间等对铁砷共沉淀物稳定性的影响。结果表明,在pH4条件下,共沉淀物稳定性最好;在pH4条件下延长预停留时间能增强砷的稳定程度;使用石灰或添加Ca2+明显增加了共沉淀物中砷的稳定性。

An infrared study on Langmuir-Blodgett films of octadecylammonium octadecanoate: FWHM and the vibrational coupling

The monolayer of the mixture of octadecanoic acid and octadecylamine with molar ratio 1: 1 has been investigated at the air-water interface. It was found that the monolayer shows a rather stable state at the surface pressure of 30 mN/m and this monolayer can be transferred onto a CaF2 plate by Langmuir-Blodgett (LB) technique. The infrared spectra of LB films indicated that octadecyl ammonium octadecanoate is formed by an intermolecular proton exchange between adjacent carboxylic and aminic groups (COO- and NH3+). In three-layer LB film, the CH2 scissoring mode of the long hydrocarbon chains of octadecyl ammonium octadecanoate shows a broad band feature at about 1468 cm(-1) while this vibrational mode of three-layer LB film of the mixture (1: 1) of deuterated stearic acid and octadecylamine (octadecylammonium octadecanoate-d35, C18H37NH3+C17D35COO-) only shows a narrow band. The broad feature of the CH2 scissoring mode in octadecylammonium octadecanoate probably originates from the coupling between the chain of stearic acid and that of octadecylamine while this kind of coupling could be completely removed in octadecylammonium octadecanoate-d35.

流动注射石英管原子吸收法测定微量总汞

建立了一套流动注射石英管原子吸收光谱法测定土壤、植物和药品等样品中微量Hg的方法,研究了酸度、载液和还原液流速及其浓度、氩气流量等条件对测定结果的影响.采用五氧化二钒、硝酸、硫酸进行消解,可获得可靠的分析结果.方法特征量为59 pg,检出限为0.028 μg/L;相对标准偏差为1.60%～3.86%;回收率为94%～102%.

Determination of mercury with a flow injection quartz tube atomic absorption spectrometry

A method was developed for the determination of micro mercury in the soil, plants and the traditional Chinese medicine using flow injection quartz tube-atomic absorption spectrometry. The effect of the factors such as acidity,. the carrier solution, the flow rate of reductive solution and argon gas, etc. on the determination was studied. When vanadic oxide, nitric acid and sulfuric acid were used to decompose the sample reliable result could be obtained. The characteristic mass of the method is 59 pg, the detection limit is 0.028 mug/L, RSD is < 3.9% and the recovery is in the range of 94% &SIM; 102%.

胸苷酸合成酶和二氢叶酸还原酶mRNA亲和肽的发现及mRNA体外展示技术的优化

胸苷酸合成酶（thymidylate synthase，简称TS）和二氢叶酸还原酶（dihydrofolate reductase, 简称DHFR）都是叶酸依赖性酶，在维持DNA合成和DNA修复上发挥关键作用，并且多年来一直是肿瘤研究和化疗的重要靶点。我们前期的研究发现，TS和DHFR在翻译水平上存在负反馈调控机制。人TS和DHFR可以与其自身的mRNA结合，从而抑制mRNA的表达，化疗药物可以与TS或者DHFR相互作用，形成的复合物不能与TS mRNA结合， 使负反馈机制丧失。因此深入研究TS和DHFR的翻译调控机理，对阐明肿瘤抗药性机制，对发现新的抗肿瘤药物和肿瘤的治疗都具有十分重要的意义。 本论文利用mRNA体外展示技术，构建多肽库（约10万亿种多肽分子），利用多种实验手段将mRNA体外展示技术进行优化，提高了多肽库融合肽的产量，提高了mRNA体外展示技术筛选的特异性。将TS mRNA分子上的顺式因子TS30 RNA固定于磁珠上，将融合肽库与顺式因子作用，经过6轮循环，由多肽库中获得了与TS mRNA高度亲和的多肽序列，体外结合实验证明亲和肽可以与TS全长mRNA结合，体外翻译实验证明多肽可以抑制TS mRNA的翻译。并且利用phage display技术由噬菌体肽库（12个氨基酸随机肽库）经过四轮筛选，分别筛选到TS和DHFR的亲和肽，凝胶阻滞实验证明它们分别能与TS和DHFR mRNA结合。 本论文利用的展示技术可以广泛应用于特异靶点的蛋白质筛选，并且本论文筛选到的TS和DHFR亲和肽可以作为TS和DHFR的抑制剂，从而为获得新型的抗肿瘤药物奠定基础。

獐牙菜植物的引种栽培方法

本发明涉及獐牙菜植物的引种栽培技术，该技术包括种子处理和引种栽培等技术。本发明通过对獐牙菜种子进行物理和化学方法处理，使其种子萌发率达75％以上；通过地膜覆盖技术，即在种子播种前采用地膜覆盖7-28天，可有效地控制杂草数量和生长，为规模化种植奠定可靠的基础；通过在海拔1500—4500米的原产水浇大田或适宜旱耕地的引种栽培途径， 可快速恢复獐牙菜的资源量，并有效地保证獐牙菜的药材品质和药效成分。

北京地区Pc6脉动统计特征及其与TID关系研究

Through the statistical analysis of the geomagnetic data from BMT in 2005, we get the period and frequency characteristic of Pc6 micropulsation in Beijing area. Pc6 micropulsation is a frequently occurred phenomenon in geomagnetism but we still do not have adequate knowledge to it. In this paper, we found that the periods of Pc 6 micropulsation focus on 10 to 30 minutes. They do not have distinct seasonal variation but obtain a little lower occurrence in the winter than other seasons. Then we analysis the geomagnetic data of BMT from 1998 to 2006, which is a solar activity cycle and get some results about the relationship between Pc6 micropulsation and solar activities. In this way, we discuss more about the origin and evolvement mechanism of the Pc6 micropulsation. When the solar is more active than usual years, there are more occurrences of Pc6 micropulsaton observed. The occurrence of Pc6 micropulsation is associated with geomagnetic index. With the increase of AE and Kp index, there are more occurrences of Pc6 micropulsation. Furthermore, we make use of the Doppler data from Peking University in 2005 make a comparative research between TID events and Pc6 micropulsation. There are 42 events can satisfy our request during Dec.23, 2004 to Mar.11, 2006. After the data analysis, we can draw a fundamental conclusion that there are positive links between Pc6 micropulsation and TID event. Moreover, when TID and Pc6 micropulsation occur simultaneously, their occurrences have a positive relationship with AE and Kp index. So we suppose there might be the same source of Pc6 micropulsation and TID event. Finally, we make use of two meridian geomagnetic stations network which has a distance about 1700 km to investigate the transmission characteristic of Pc6 micropulsation when Pc6 micropulsation and TID happened together. We found at that time Pc6 micropulsation is a local phenomenon.

High selectivity of oxidative dehydrogenation of ethane to ethylene in an oxygen permeable membrane reactor

An oxygen permeable membrane based on Ba0.5Sr0.5Co0.8-Fe0.2O3-delta is used to supply lattice oxide continuously for oxidative dehydrogenation of ethane to ethylene with selectivity as high as 90% at 650degreesC.

Estimativa do fator de bioconcentração de pesticidas em maçã.

Com o objetivo de indicar pesticidas que devem ser monitorados em frutas, foi estimado o fator de bioconcentração (BCF) de 36 pesticidas em maçã selecionados do sistema de produção integrada de maçã (PIM). O BCF é um indicador da afinidade de substâncias por organismos. Para estimar o BCF foi utilizado o modelo FTM-p (Fruit Tree Model to Pesticide) [PARAÍBA, L.C. Pesticide bioconcentration modelling for fruit trees. Chemosphere, v.66, p.1468-1475, 2007] e um cultivo hipotético de macieiras. No modelo FTM-p, o valor do BCF foi correlacionado com características fisiológicas da planta e com propriedades físico-químicas dos pesticidas. Na estimativa foram utilizados os tempos de meia-vida no solo e na planta de cada um dos pesticidas. Da planta foram utilizados a biomassa seca, a taxa de transpiração de água e o volume do fluxo de água necessário para produzir um quilo de fruta fresca por planta. O coeficiente de partição tronco-água e o fator de concentração no fluxo de transpiração foram calculados por meio de expressões que correlacionam cada um desses parâmetros com o coeficiente de partição octanol-água do pesticida.