989 resultados para sulfur


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This paper reports laboratory measurements of the spectrum of highly ionized sulfur. The spectrum of S Ⅸ–S ⅩⅢ has been observed in the wavelength range 170–500 Å. A total of 54 lines have been measured. Forty-two of them have been classified as 2s22pk–2s2pk+1and 2s2pk–2pk+1 transitions. Twelve other lines have been ascribed to 2s–2p,4p–5s,5p–6s,5d–6p, and 6p–8d transitions. These spectral lines have been identified, among which 22 are new and accurately measured. The analysis of the spectra was based on a comparison with other experimental results and calculated values.

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Spectra for Delta n = 0 transitions of the type 2s(2)2p(k)-2s2p(k+1) or 2s2p(k)-2p(k+1) from highly ionized sulfur produced in beam-foil excitation are investigated and compared to similar spectra measured with other types of light sources. In the experiment, fifty lines have been identified, of which eleven lines are new and accurately measured. Analysis of spectra was based on comparisons with other experimental results and calculated values.

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The direct reduction of SO2 to elemental sulfur in flue gas by the coupling of cold plasma and catalyst, being a new approach for SO2 reduction, was studied. In this process, CO2 can be disassembled to form CO, which acts as the reductant under the cold plasma. With the coupling of the cold plasma and the catalyst, sulfur dioxide was selectively reduced by CO to elemental sulfur with a byproduct of metal sulfate, e.g., FeSO4. In the present work, Fe2O3/gamma-Al2O3 was employed as the catalyst. The extent of desulfurization was more than 80%, and the selectivity of elemental sulfur is about 55%. The effects of water vapor, temperature, and the components of simulated flue gas were investigated. At the same time, the coupling of thermogravimetry and infrared method and a chemical analysis method were employed to evaluate the used catalyst. In this paper, we will focus on the discussion of the catalyst. The discussions of the detail of plasma will be introduced in another paper.