Caracterização dos óleos de algumas sementes de frutas como aproveitamento de resíduos industriais

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Planejamento experimental na otimização da extração dos frutos de Syzygium cumini (L.) skeels

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Substâncias húmicas de turfa: estudo dos parâmetros que influenciam no processo de extração alcalina

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Produção de feijão-fava em função do uso de doses de fósforo

O fósforo é um importante nutriente para as plantas e sua presença no solo promove o crescimento e eleva a produção das hortaliças. O presente trabalho, realizado na Universidade Federal da Paraíba, em Areia, em um NEOSSOLO REGOLÍTICO Psamítico típico no período de dezembro/2001 a julho/2002, teve por objetivo avaliar a resposta do feijão-fava, cultivar Orelha de Vó, a diferentes doses de P2O5. O delineamento experimental utilizado foi em blocos casualizados com cinco tratamentos (0; 100; 200; 300; 400 e 500 kg ha-1 de P2 O5) e com quatro repetições. Cada parcela continha 40 plantas espaçadas em 1,0 m x 0,50 m. As produções máximas estimadas de grãos verdes e secos (5,2 e 2,7 t ha-1), respectivamente, ocorreram com 309 e 302 kg ha-1 de P2O5. As doses de P2O5 que proporcionaram maiores retornos econômicos foram 291 kg ha-1 para a produção de grãos verdes e 281 kg ha-1 para produção de grãos secos, sendo as receitas previstas para a aplicação destas, correspondentes às produtividades de 4,1 e 1,8 t ha-1, respectivamente. As doses mais econômicas compreenderam mais de 80% daquelas responsáveis pelas produções máximas, constituindo um indicativo da viabilidade econômica do emprego de fósforo no cultivo de feijão-fava. As doses de P2O5 com as quais obtiveram-se as máximas produções e retornos econômicos quanto a produção de grãos verdes e secos, se correlacionam, respectivamente, com 57,1 e 56,3 e com 55,0 e 53,8 mg dm-3 de P disponível pelo extrator de Melich 1. Probabilidades minimizadas de ocorrência de resposta dessa cultura à adubação fosfatada em solos semelhantes ao do presente estudo, para a produção de grãos verdes e secos, serão obtidas quando os teores de P disponível forem superiores a 55,0 e 53,8 mg dm-3. A concentração média de P nas folhas do feijão-fava, aos 120 dias após a semeadura, em função das doses de P2O5 foi de 3,4 g kg-1. As doses de 291 e 281 kg ha¹ de P2O5, respectivamente, devem ser as recomendadas para aplicação no solo em estudo, visando a produção de grãos verdes e secos de feijão-fava.

Polymeric organic-inorganic hybrid material containing iron(III) porphyrin using sol-gel process

Here we describe the preparation of iron(II) porphyrinosilica in a simple one-pot reaction, where the -SO2Cl groups present in the phenyl rings of FeTDCSPP+ react with 3-aminopropyltriethoxysilane and tetraethoxysilane in the presence of a nitrogenous base, leading to iron(III) porphyrinosilica. In this same procedure, molecular cavities containing regularly spaced functional groups are created through the molecular imprinting technique, in which the nitrogenous base coordinated to the iron(III) porphyrin serves as a template. The removal of such template in a Soxhlet extractor leads to a cavity with the same shape and size as the nitrogenous base, enabling the construction of shape-selective catalysts mimicking cytochrome P-450. Five different imprinting molecules have been used: imidazole, 1-methylimidazole, 2-methylbenzimidazole, 4-phenylimidazole and miconazole and ultra-violet/visible absorption spectroscopy, thermogravimetric analysis and electron paramagnetic resonance carried out. (C) 1999 Elsevier B.V. B.V. All rights reserved.

Diferentes resposta de cutivares de soja e potássio

Soybean (Glycine max (L.) Merrill) is known to have a high ability as a potassium extractor, and different cultivars show different potassium requirements. An experiment was run to study the potassium nutrition of soybean as related to plant characteristics. Six soybean cultivars (FT-2, Bossier, IAC-11, IAC-17, IAC-18 and IAC-19) were grown in 6 kg pots filled with the topsoil of a Dark Red Latosol (sandy loam), either with and without K fertilization. The plants were harvested 70 days after emergence. Soybean response to potassium was not related to growth habit or group of maturation. There was a different response to K. The cultivars IAC-18 and FT-2 were less tolerant to K deficiency. Potassium deficiency in the leaves was not related to top dry matter production. With K fertilization soybean plants showed small root volume and higher ratio canopy/root. With high K in soil, all of the cultivars showed higher nodulation.

Fast chromatographic determination of polycyclic aromatic hydrocarbons in aerosol samples from sugar cane burning

Sugar cane burning in Brazil causes remarkable amounts of organic compounds to be emitted amongst which the polycyclic aromatic hydrocarbons (PAHs) represent serious health hazards. Therefore, 24-h aerosol samples (< 10 mum aerodynamic diameter) were collected in Araraquara city (São Paulo state) during the harvest season using a Hi-Vol sampler. PAHs were recovered using an Accelerated Solvent Extractor and analyzed by low-pressure gas chromatography-ion trap mass spectrometry (LP-GC-IT-MS). The fully automated extraction process was performed in less than 25 min with a solvent consumption of approximately 20 ml. The use of a deactivated 0.6 m x 0. 10 mm i.d. restrictor coupled to a 10 m wide-bore analytical column allowed most of the 16 PAHs in EPA's priority list to be identified and quantified in only 13 min. Concentrations of PAHs in Nraraquara aerosols ranged between 0.5 and 8.6 ng m(-3). (C) 2003 Elsevier B.V. All rights reserved.

Rede neural não supervisionada baseada em transformada Karhunen-Loève para processamento, compressão e reconhecimento de imagens

The merit of the Karhunen-Loève transform is well known. Since its basis is the eigenvector set of the covariance matrix, a statistical, not functional, representation of the variance in pattern ensembles is generated. By using the Karhunen-Loève transform coefficients as a natural feature representation of a character image, the eigenvector set can be regarded as an feature extractor for a classifier.

Níveis críticos de fósforo no solo e nas folhas para a implantação de Eucalyptus grandis Hill ex Maiden, em quatro tipos de solos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Efeitos do fósforo do solo no desenvolvimento inicial de Genipa americana L.

A greenhouse experiment was carried out to evaluate the effects of soil phosphorus in the development of plants of Genipa americana L. Five doses of P (0, 50, 100, 200, and 400 mg dm -3) were applied in pots with 10 dm 3 of three Neossolos Quartzarênicos (NQ 1, NQ 2 and NQ 3) and one Latossolo Vermelho (LV), that were used in an experiment with Eucalyptus plants during three months. After this period, the soils were analyzed and a 30 cm height seedling of G. americana was planted in each pot. The experiment design was completely randomized, in 5 × 4 factorial scheme, with five replications. The largest biomass of the stem was obtained with 45 mg dm -3 of P in the soil NQ 1 (9% of clay) and 59 mg dm -3 in the soil NQ 3 (14% of clay). In the LV (40% of clay), the biomass of the stem increased linearly in the band of 3 to 148 mg dm -3 of P. The phosphorus critical level in the soil for 80% of the steam and leaves dry matter production of G. americana at planting phase is 15 mg dm -3, using an anion-exchange resin as extractor.

Concentração de sais da soluçtiao avaliada pela condutividade elétrica na zona radicular do crisântema sob irrigação por gotejamento

The effects of salt concentration levels in electrical conductivity (EC) were evaluated in chrysanthemum root, cultivated in substrate using two sampling methods, under greenhouse conditions. The experiment was carried out in Paranapanema, São Paulo using the experimental design in randomized blocks and four replications. The treatments consisted of eight sampling periods of substrate solutions in pots: 7, 14, 21, 28, 35, 42, 49 and 56 days after strike root and five salt concentration levels of applied saline solution: 1.42; 1.65; 1.89; 2.13 and 2.36 dS m -1 in the vegetative period and during the reproduction period of flower budding: 1.71; 1.97; 2.28; 2.57 and 2.85 dS m -1. The substrate solution EC monitoring was done using two methods: solution extractors and 1:2 water diluted solution. The use of solution extractors and 1:2 water diluted solution allowed substrate solution EC monitoring along the culture cycle; the amount of salt concentration applied in the substrate caused the substrate salinity increase; the method using solution extractors presented higher EC values in the substrate.

Nickel in a tropical soil treated with sewage sludge and cropped with maize in a long-term field study

Sewage sludge produced by the SABESP wastewater treatment plant (Companhia de Saneamento Básico do Estado de São Paulo), located in Barueri, SP, Brazil, may contain high contents of nickel (Ni), increasing the risk of application to agricultural soils. An experiment was carried out under field conditions in Jaboticabal, SP, Brazil, with the objective of evaluating the effects on soil properties and on maize plants of increasing rates of a sewage sludge rich in Ni that had been applied for 6 consecutive years. The experiment was located on a Typic Haplorthox soil, using an experimental design of randomized blocks with four treatments (rates of sewage sludge) and five replications. At the end of the experiment the accumulated amounts of sewage sludge applied were 0.0, 30.0, 60.0 and 67.5 t ha-1. Maize (Zea mays L.) was the test plant. Soil samples were collected 60 d after sowing at depths of 0-20 cm for Ni studies and from 0 to 10 cm and from 10 to 20 cm for urease studies. Sewage sludge did not cause toxicity or micronutrient deficiencies to maize plants and increased grain production. Soil Ni appeared to be associated with the most stable fractions of the soil organic matter and was protected against strong extracting solutions such as concentrated and hot HNO3 and HCl. Ni added to the soil by sewage sludge increased the metal concentration in the shoots, but not in the grain. The Mehlich 3 extractor was not efficient to evaluate Ni phytoavailability to maize plants. Soil urease activity was increased by sewage sludge only in the layer where the residue was applied. © 2006 Elsevier Ltd. All rights reserved.

Posicionamento de Extratores de Cápsula Porosa em Solo Arenoso Na Citricultura Fertirrigada Por Gotejamento

The efficiency of monitoring fertigation by means of porous capsule extractors is directly related to its correct placement, since the nutrients applied through fertigation have different mobility throughout the soil profile. The objective of this study was to evaluate the distributions of NO3, P, and K in the soil solution, when applied in citrus in sandy soil through drip fertigation systems, aiming to define the proper placement of the solution extractors. In order to measure the concentration of ions in the soil solution, the extractors were installed at four different distances (5, 15, 25, and 35 cm) and depths (15, 30, 60, and 90 cm) with an emitter located under the projection of the tree canopy. The experiment was conducted in a Valencia orange orchard on citrumelo Swingle rootstock, in Reginópolis/SP. The experimental design was randomized blocks and the treatment arrangement was a 4 x 4 factorial design with five repetitions. Sixteen soil solution extractors were installed per block, with a total of 80 extractors in the experiment. According to the obtained results, to determine P and K, it is recommended to install the solution extractor at 15 cm horizontal and 30 cm depth from the emitter. For NO3, the extractor recommended placement is 25 cm horizontal and 30 cm depth. The soil solution extractor proved to be a sensitive tool, capable of determining the ions mobility in the wet bulb.

Condutividade elétrica da solução nutritiva e acúmulo de macro e micronutrientes no cultivo de crisântemo

The study of growth and uptake of nutrients is important to determine the times of increased demand in order to schedule the fertigation. The present research was developed with the objective of evaluating the effects of different levels of electrical conductivity on growth and accumulation of nutrients in chrysanthemum plants under greenhouse conditions. The electrical conductivity levels on the applied solution were 1.42, 1.65, 1.89, 2.13 and 2.36 dS m-1 (bud vegetative stage); 1.71, 1.97, 2.28, 2.57 and 2.85 dS m-1 (bud stage). The dry mass of the aerial portion of the plant and the contents of macronutrients and micronutrients were determined every 14 days. The nutrient accumulation in chrysanthemum plant showed similar trend as compared to dry matter accumulation. The nutrients presented the following order of absorption: K>N>Ca>Mg>P>S (1425, 892, 184, 150, 110 and 59 mg plant-1) and Fe>Zn>B>Mn>Cu (2254, 2219, 1725, 1287, 210 μg plant-1). The content of most nutrients increased with increase in electrical conductivity of the solution, without salt effect up to EC of 2.85 dS m-1.

Crescimento da grama bermudas sob diferentes lâminas de irrigação

The objective of the present study was to analyze the most appropriate water depth for maintaining a good quality of Bermudas Grass (Cynodon dactylon) for soccer fields while saving water and electrical resources. Four treatments were used: T1 - irrigated with a water depth of 50% of evapotranspiration (ETo), T2 - irrigated with a water depth of 75% of ETo, T3 - irrigated with a water depth of 100% of ETo and T4 - irrigated with a water depth of 150% of ETo, all treatments were irrigated daily. The reference ETo was obtained by the Penman-Monteith method. The study was conducted in an experimental area of the Instituto Federal de Educação, Ciência e Tecnologia do Triângulo Mineiro - Campus Uberaba, Uberaba, Minas Gerais, Brazil, from June to September 2010 and from January to March 2011. Three evaluations of the variables were performed during the experimental period. The samples were obtained with the help of a cylindrical extractor with 10 cm in diameter and 30 cm in height. In each sample height and dry organic matter (leaf, root and organic material) were analyzed. The experimental design was randomized block with four treatments in five blocks. No significant differences were observed for dry matter and height (roots and organic material). The best results were those for T4 which obtained the greatest height.