Fracture behavior of a Zr-metallic glass under dynamic compression

Dynamic planar compressive experiments on a typical tough Zr-BMG (Bulk Metallic Glass) were carried out under impact velocity of 500-600 m/sec and strain rate of 10(6)/s. The fracture surface of samples exhibits different fracture patterns at different parts of the sample. At a corner close to the front loading boundary, fracture patterns from the free edge toward the centre changed from equiaxial veins in microscale to periodic corrugations in nanoscale; in the middle of the sample, the fracture surface contains glazed zones laid out orderly along the same boundary. FEM simulation was performed to investigate the stress distributions in the impacted sample under a short duration impact loading. It has revealed that the fracture patterns changing from the free edge toward the centre were resulted from the fracture modes' changing from the tensile dominant fracture to the shear dominant fracture. Whereas at the middle part of the sample, fracture initiated from several parallel shear bands propagating close to the same boundary is due to a large strain or much higher shear stress in this area.

Ar~(16+)与Zr作用产生的X射线谱

本工作对超导离子源(SECRAL)上的10~20 kV/q Ar16+和Ar17+入射到金属Zr表面进行实验研究。实验结果表明,高电荷态Ar16+在金属表面存在着多电子激发过程。Ar空心原子的K层发射X射线强度随入射离子的动能减少,靶原子Zr的L壳层发射X射线强度随入射离子动能的增加而增强。Ar17+单离子的K-αX射线产额比Ar16+单离子的K-αX射线产额大5个数量级。

Use of Zr/Rb ratios in Chinese loess sequences to trace paleo-winter monsoon winds strength

IEECAS SKLLQG

~(85)Zr核的高自旋态研究

利用102MeV的28Si束流,通过60Ni(28Si,2pn)熔合蒸发反应布居了85Zr核的高自旋态,测量了γ-γ符合及DCO比值,建立了一个有43条能级,75条γ跃迁的能级纲图,新增加了36条γ跃迁,25条能级.将能级自旋推高到(49/2+),首次观察到了转晕带的第二回弯.并确认了一条建立在17/2-负宇称带上的磁转动带.

~(85)Zr的高自旋态和磁转动带研究

<正>质量数80区的过渡性核表现了集体性和单粒子性的能级结构。对质子数Z为37～40、中子数N=45的原子核,如81Kr,87Mo核,在中低自旋时显示了单粒子特性,而在高自旋态时表现出较多的集体性。 近些年来,在过渡区在束γ谱学,如83Rb、83Y等核研究中,观察到了一串建立在较高K态的增强的△I=1的M1跃迁。它被认为是一种新的激发模式,叫做磁转动带。我们对85Zr的研究目的,一是将其能级推到更高自旋,另一个是寻找该核的磁转动带。

L-shell x-ray yields and production cross sections of Zr and Mo bombarded by slow highly charged Ar16+ ions

The L-shell x-ray yields of Zr and Mo bombarded by slow Ar16+ ions are measured. The energy of the Ar16+ ions ranges from about 150keV to 350keV. The L-shell x-ray production cross sections of Zr and Mo are extracted from these yields data. The explanation of these experimental results is in the framework of the adiabatic directionization and the binding energy modified BEA approximation. We consider, in the slow asymmetric collisions such as Ar and Mo/Zr, the transient united atoms (UA) are formed during the ion-surface interaction and the direct-ionization is the main mechanism for the inner-shell vacancy production. Generally, the theoretical results are in good agreement with the experimental data.

X-ray spectra produced by interaction of Ar16+ and Ar17+ with Zr

The 10-20 qkeV Ar16+ and Ar17+ ions produced by SECRAL enter on metallic surface of Zr. In this interaction, the multi-electron excitation possibly occurred in the neutralization of the highly charged Ar16+ ions, which produced vacancy in the K shell. Electron of the high n state de-excited to K vacancy gives off X-ray. The experimental results show that X-ray intensities for the Ar hollow atom decrease with increase of incidence energy, and L beta X-ray intensities of target atom Zr increase with increasing incidence energy. K alpha X-ray yield per ion for Ar17+ was five orders of magnitude greater than that for Ar16+

Identification of a quasiparticle band in very neutron-rich Zr-104

The high spin levels of a very neutron-rich Zr-104 nucleus have been reinvestigated by measuring the prompt. rays in the spontaneous fission of Cf-252. The ground-state band has been confirmed. A new sideband has been identified with a band-head energy at 1928.7 keV. The projected shell model is employed to investigate the band structure of Zr-104. The results of calculated levels are in good agreement with the experimental data, and suggest that the new band in Zr-104 may be based on the neutron nu 5/2(-)[532] circle times nu 3/2(+)[411] configuration.

Electrocatalytic properties of Cu-Zr amorphous alloy towards the electrochemical hydrogenation of nitrobenzene

The Cu-Zr amorphous alloy was studied as an electrocatalyst towards the electrochemical hydrogenation of nitrobenzene. The electrocatalyst was activated by chemical etching in HF solution. Resulted changes in the morphology, chemical composition and crystalline structure of the electrocatalyst surface were characterised by scanning electron microscopy, X-ray diffraction and Auger electron spectroscopy. The electrocatalytic properties of the Cu-Zr amorphous alloy were assessed by voltammetric measurements. Due to the formation and aggregation of Zr residue modified Cu nanocrystals on the surface caused by the selective dissolution of Zr components in the chemical etching, the activated amorphous alloy is an effective electrocatalyst for the electrochemical reduction reaction of nitrobenzene with aniline as the main product. The positive shift of the peak potential and accompanying increase in the value of peak current in voltammograms with increasing Cu content and decreasing Zr content of the alloy surface in the chemical etching are indicative of improved electrocatalytic activity. (C) 2002 Elsevier Science B.V. All rights reserved.