Análise do potencial pozolânico da cinza de casca de arroz (CCA) através da técnica de refinamento de Rietveld

É um consenso que a cinza de casca de arroz é um resíduo agrícola com comprovada eficiência pozolânica. Contudo, por se tratar de um resíduo, apresenta problemas de variabilidade decorrente dentre outras coisas de sua origem e dos diferentes processos de geração, fator este que dificulta sua comercialização. Hoje em dia, a determinação da atividade pozolânica do resíduo e determinada pela NBR 5752^[3] (ABNT, 2012) e NBR 5751⁽²⁾(ABNT, 2012). A desvantagem com relação a estes ensaios é o tempo que se leva para ter uma resposta. Nesse sentido, este trabalho visa analisar a eficiência do refinamento de Rietveld para avaliar a pozolanicidade através do parâmetro denominado de índice de amorfismo. Por meio desse refinamento é possível dizer, de forma quantitativa, a porcentagem de elementos reativos que o resíduo apresenta, operadores com conhecimento da técnica de análise levam em torno de dois dias para apresentar os resultados. Para avaliação dessa técnica, as cinzas foram produzidas através da queima em diferentes temperaturas (500, 600, 800, 900 e 1100 ºC). Fixou-se o tempo de queima do material em três horas e a taxa de aquecimento em 5 ºC/min, e resfriamento lento. Posteriormente realizou-se a moagem da cinza e quantificação do índice de amorfismo por meio de refinamento Rietveld. Os resultados demonstraram que o índice de amorfismo pode ser utilizado como parâmetro de controle de cinzas residuais, visto que cinzas com elevado índice de amorfismo apresen-tam uma boa pozolanicidade.

Análise da durabilidade do concreto de alto desempenho com adição de cinza de casca de arroz e borracha de pneu

Since the Seventies, there has been a growing degradation of concrete structures in Brazil. For that reason, much research has been made on the durability of those structures, aiming at contributing towards quality improvement and reduction of maintenance and repair costs. This study evaluates the behavior of the durability of high-performance concrete with additions, replacing part of the cement and aggregates with rice husk ash and tire rubber, respectively. Durability tests were carried out in which concrete was subjected to several degradation processes, such as the action of water, temperature, salts and acid solution. The results indicated that the addition of active silica or rice husk ash, both with tire rubber did not worsen the durability of concrete. In fact, rubber proved to be very effective in preventing the action of chemical agents, high temperatures and the penetration of water. Rice husk ash, despite the larger diameter of particles, had similar results to that of the active silica.

Prediction of the combustion process in fluidized bed based on physical-chemical properties of biomass particles and their hydrodynamic behaviors

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

New method to assess the pozzolanic reactivity of mineral admixtures by means of pH and electrical conductivity measurements in lime:pozzolan suspensions

A very simple method based on electrical conductivity and pH measurements was proposed for assessing reactivity of pozzolans. Calcium hydroxide: pozzolan water suspensions were monitored by means of measurements of electrical conductivity and pH values. In these suspensions, Ca(OH)(2) in solid state was initially present, being them, thus, saturated in this reagent. Three testing temperatures were selected (40, 50 and 60 degrees C). In the experiments carried out, calcium hydroxide was suspended in deionized water for yielding a lime saturated suspension. The addition of siliceous pozzolan (two types of rice husk ash RHA and two types of densified silica fume DSF were tested) to the saturated lime suspension can produce the unsaturation of the system, depending on the testing time, testing temperature and reactivity of pozzolan. When unsaturation was reached, the loss of electrical conductivity was higher than 30% and the variation of pH was higher than 0.15 units. These threshold values were selected for characterizing the reactivity of pozzolans by means of a proposed template, classifying the pozzolan in three different reactivity levels.

Utilização do cavaco de madeira como combustível alternativo para a produção de vapor de água em uma caldeira aquatubular com grelha fixa do tipo PIN HOLE

The steady increase in the price of oil and its derivatives, carbon credits, the concern with the environment combined with the precipitation of rain water and lack of water resources that Brazil has suffered in 2014 caused a migration of participation sources of energy in the Brazilian energy matrix. The hydropower sector suffered big drop at 2013 and is suffering so far, contributing thus to the generation and cogeneration of thermal energy using renewable energy sources such as: sugarcane bagasse, wood chips, rice husks, among others. The selling price of the electricity market reached the level of R$ 807, 00 MWh in January 2014 (Source: ANEEL), heating the Brazilian thermoelectric sector. Although thermoelectric use in bulk water as vaporizing fluid to produce electricity and use in various processes, water reuse plans have become an important factor in these industries. The increased use of biomass has been the bagasse which is allied to the sugarcane sector, strong market in Brazil, and consists basically use the rest of sugar cane, sugarcane industries that would play out. The sugar and ethanol industry is very unstable and only lasts for 6-8 months a year, and the remaining time in the period known as between crop that corresponds to the planting and harvesting of sugarcane and then enter the period of vintage which is the constant cane harvesting and crushing it. This instability of the market and the thermoelectric idle period leads the thermoelectric industries to seek other sources of renewable energy, such as wood chips (pine, Eucalyptus, Orange), rice husk, sorghum among others, to not be dependent on alcohol sector. The present work aims to study the use of wood chips as an alternative biomass for burning a fuel that essentially uses bagasse, the thermoelectric in question consists of two boilers that produce together 350 t / h ... (Complete Abstract click electronic access below)

Estudo sobre desruptores endócrinos em sistemas aquáticos: detecção e perspectivas de tratamento das águas do Rio Aporé-MS/GO, utilizando-se adsorventes sólidos

Pós-graduação em Ciência dos Materiais - FEIS

Physical-chemical characterization of biomass samples for application iin pyrolysis process

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Concreto autoadensável utilizando cinza de casca de arroz: estudo das propriedades mecânicas

Pós-graduação em Engenharia Civil - FEIS

Evaluation of microwave-assisted pretreatment of lignocellulosic biomass immersed in alkaline glycerol for fermentable sugars production

A pretreatment with microwave irradiation was applied to enhance enzyme hydrolysis of corn straw and rice husk immersed in water, aqueous glycerol or alkaline glycerol. Native and pretreated solids underwent enzyme hydrolysis using the extract obtained from the fermentation of Myceliophthora heterothallica, comparing its efficiency with that of the commercial cellulose cocktail Celluclast (R). The highest saccharification yields, for both corn straw and rice husk, were attained when biomass was pretreated in alkaline glycerol, method that has not been previously reported in literature. Moreover, FTIR, TG and SEM analysis revealed a more significant modification in the structure of corn straw subjected to this pretreatment.Highest global yields were attained with the crude enzyme extract, which might be the result of its content in a great variety of hydrolytic enzymes, as revealed zymogram analysis. Moreover, its hydrolysis efficiency can be improved by its supplementation with commercial beta-glucosidase.

Resíduos agrícolas e argila expandida no cultivo da orquídea Oncidium baueri Lindl.

For orchid cultivation in containers is essential to select the right substrate, since this will influence the quality of the final product, it serve as a support for the root system of the plants. This study aimed to evaluate different agricultural residues and expanded clay in Oncidium baueri Lindl. orchid cultivation. The plants were subjected to treatments: pinus husk + carbonized rice husk, pinus husk + coffee husk, pinus husk + fibered coconut, pecan nut husk, expanded clay, fibered coconut, coffee husk, carbonized rice husk, pinus husk. After eleven months of the experiment, the following variables were evaluated: plant height; largest pseudo-bulb diameter; number of buds; shoot fresh dry matter; the longest root length; number of roots; root fresh matter; root dry matter; and electric conductivity; pH and water retention capacity of the substrates. Except the expanded clay, the other substrates showed satisfactory results in one or more traits. Standing out among these substrates pinus husk + coffee husk and pine bark + fibered coconut, which favored the most vegetative and root characteristic of the orchid. The mixture of pinus husk + coffee husk and pinus husk + fibered coconut, provided the best results in vegetative and root growth of the orchid Oncidium baueri and the expanded clay did not show favorable results in the cultivation of this species.

Estudo das propriedades mecânicas do concreto com adição de cinza de casca de arroz

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Compostagem de resíduo sólido de abatedouro avícola

The great demand for animal protein was responsible for the increase on the broilers production and hence, the generation of waste from the poultry slaughter was increased as well, which in turn, propelled the development of techniques that allow the reuse and recycling of these wastes. The objective of this study was to evaluate the efficiency of composting on the treatment and recycling of solid waste from poultry slaughterhouse. The solid waste was from a commercial poultry slaughterhouse and was composed of viscera, muscle, fat, bone, blood and feathers that was mixed with a source of carbon, rice husk. Initially, a windrow with a volume of 1.5m(3) was built, and then some parameters were monitored: temperature, total solids (TS), volatile (VS), N, P, K, organic carbon (C), composting organic matter (COC), organic matter resistant to composting (MORC), chemical oxygen demand (COD), mass and volume of the windrow, most probable number (MPN) of total and fecal coliforms, as well as their reductions during the process. The maximum temperature reached in the center of the windrow was 53.3 degrees C (weekly average) since reductions of weight of TS and VS and volume during the pre-composting were 36.1, 44.3 and 23.3%, respectively and during the composting process was 21.8, 23.8 and 4.4%. The low volume reduction can be associated with high concentrations of MORC (40.1%) which can be mainly related to the quality of the carbon source. The process produced satisfactory total reductions of TS, VS and volume that were respectively, 50.1, 57.5 and 26.7%. However reductions were observed in 43% of amount of nitrogen in the final compound. Despite reductions in nitrogen content, composting proved to be an effective method in the treatment of solid waste from poultry slaughterhouse.

Estudo da influência da cinza de casca de arroz e da cal nas propriedades do solo-cimento auto-adensável

Pós-graduação em Engenharia Civil - FEIS

Study of combustion of different biomass and its atmospheric emissions

One of the energy alternatives that provide utility, flexibility, cleanliness and economy is biomass, such as forest waste (wood) and agricultural (sugarcane bagasse, rice husks, coffee pods, etc.). However, with its increasing supply and use grows also the concern of industries to invest in monitoring and control of emissions into the atmosphere, because during biomass burning are emitted as exhaust gases, fine particles known as particulates, which greatly contribute to the triggering of serious health problems to humans, in addition to the environmental damage. With that, this work aimed to conduct a monitoring of particulate and gaseous pollutants emissions to the atmosphere from the burning of various types of biomass used by industries. The equipment used for sampling were the optical monitor DataRAM 4 and the Unigas3000 + gas sampler. The results showed that biomass coffee pods presented the greatest concentration of particulates (485119 μg m-3) with particle diameters between 0.0602 μm and 0.3502 μm, i.e. the most ultrafine particles, harmful to human health and the environment. The largest emissions of CO and NOx were observed, respectively, for the coffee pods (3500 ppm) and for the rice husk (48 ppm). As for the superior calorific value (PCS), the best of fuel, with higher PCS, was the Eucalyptus grandis.

Lâminas de fertirrigação e substratos na produção e qualidade de gérbera de vaso

Fertigation management of gerbera crop has been many times performed inadequately, and it has been worsened when mixtures of substrates with different physical and chemical characteristics are used. Aiming at evaluating the production and quality of potted gerbera in two substrates and different levels of fertigation, the experiment was conducted in the greenhouse of the DRN/Soil Science, FCA/UNESP, Botucatu (SP). A 5 x 2 factorial randomized block design (5 levels of fertigation and 2 substrates) was adopted with 4 replications. Levels of fertigation corresponded to maintenance of 100% available water (AW) in the substrate; 100 to 80% of AW; 100 to 60% of AW; 100 to 40% of AW and 100 to 20% of AW. The substrates were as follows: 1- mixed coconut fiber (50% pellet coconut fiber and 50% coir fiber), 2- 40% red soil, 40% decomposed pine bark, 10% composition 1 (40% decomposed pine bark, 30% vermiculite and 30% carbonized rice husk) and 10% composition 2 (75% decomposed pine bark and 25% needles of pine). Plants at the marketing stage were evaluated according to the number of leaves; diameter of leaf surface; leaf area; fresh and dry phytomass of leaves, inflorescence and total plant; inflorescence number and diameter, stem diameter, plant height, leaf area rate and electrical conductivity of the substrate solution. Plants of better quality were obtained when they were maintained in levels of 100% available water and the mixed coconut fiber was used as substrate.