Mineralogical, geochemical, and lipid biomarker study of cabonate precipitates at station GeoB9908-1

Carbonate precipitates recovered from 2,000 m water depth at the Dolgovskoy Mound (Shatsky Ridge, north eastern Black Sea) were studied using mineralogical, geochemical and lipid biomarker analyses. The carbonates differ in shape from simple pavements to cavernous structures with thick microbial mats attached to their lower side and within cavities. Low d13C values measured on carbonates (-41 to -32 per mill V-PDB) and extracted lipid biomarkers indicate that anaerobic oxidation of methane (AOM) played a crucial role in precipitating these carbonates. The internal structure of the carbonates is dominated by finely laminated coccolith ooze and homogeneous clay layers, both cemented by micritic high-magnesium calcite (HMC), and pure, botryoidal, yellowish low-magnesium calcite (LMC) grown in direct contact to microbial mats. d18O measurements suggest that the authigenic HMC precipitated in equilibrium with the Black Sea bottom water while the yellowish LMC rims have been growing in slightly 18O-depleted interstitial water. Although precipitated under significantly different environmental conditions, especially with respect to methane availability, all analysed carbonate samples show lipid patterns that are typical for ANME-1 dominated AOM consortia, in the case of the HMC samples with significant contributions of allochthonous components of marine and terrestrial origin, reflecting the hemipelagic nature of the primary sediment.

Table 1: Station data for the entire survey, including coordinates and description of BPBASE

During GANOVEX VI new gravity data were collected along an east-west profile in North Victoria Land south of the Drygalski Ice Tongue, extending 150 km across the Transantarctic Mountains, and comprising 21 data points. Thirty five additional data points were collected over a small area near Brimstone Peak, near the western end of the regional profile. The survey south of the Drygalski has been connected to northern gravity data (GANOVEX V) by a survey line of 12 points. All data have been terrain corrected, and are further constrained by satellite elevation (GPS) and radar ice-thickness measurements. A pronounced regional Bouguer gravity gradient decreasing to the west by approximately 3 mgal/km is superimposed over a coast-parallel belt of granitoid basement rock. West of this belt the local gravity fields become mote variable. Over Beta Peak (Ferrar dolerite) a 50 mgal spike is obser- ved. Within this area, the Ferrar sills are exposed at the surface. West of Brimstone Peak (Ferrar/Kirk patrick sequences), a smooth regional gradient appears to reassert itself. We interpret the initial gradient east (oceanward) of the break-in-slope to be representative of the crust/mantle boundary within the study area. We interpret the initial break-in-slope and the apparent flattening of the regional gradient to be an effect of the N-S trending zone of dense Ferrar sills and associated deep crusttil fractionate replacing less dense basement. We attribute the variability of the local field to be the product of sub-glacial density contrasts that cannot be removed. The regional gravity gradient of the profile is steeper than that observed to the north (Mt. Melbourne quadrangle) and shallower than that reported to the south (McMurdo Sound). The absolute values of the coastal points of origin south of the Drygalski and within the Mt. Melbourne quadrangle differ by 60 to 100 mgal. In addition, topographic relief within the regional transect area is subdued relative to the Transantarctic Mountains to the north and south. We speculate that the root structure of the Transantarctic Mountains undergoes a change somewhere between the Mt. Melbourne quadrangle and the region south of the Drygalski Ice Tongue.

(Table 1) Summary statistics of in situ sea-ice characteristics of Ice Station Belgica sites Fabra, Patria/Liège and Brussels in October 2007

Three ice type regimes at Ice Station Belgica (ISB), during the 2007 International Polar Year SIMBA (Sea Ice Mass Balance in Antarctica) expedition, were characterized and assessed for elevation, snow depth, ice freeboard and thickness. Analyses of the probability distribution functions showed great potential for satellite-based altimetry for estimating ice thickness. In question is the required altimeter sampling density for reasonably accurate estimation of snow surface elevation given inherent spatial averaging. This study assesses an effort to determine the number of laser altimeter 'hits' of the ISB floe, as a representative Antarctic floe of mixed first- and multi-year ice types, for the purpose of statistically recreating the in situ-determined ice-thickness and snow depth distribution based on the fractional coverage of each ice type. Estimates of the fractional coverage and spatial distribution of the ice types, referred to as ice 'towns', for the 5 km**2 floe were assessed by in situ mapping and photo-visual documentation. Simulated ICESat altimeter tracks, with spot size ~70 m and spacing ~170 m, sampled the floe's towns, generating a buoyancy-derived ice thickness distribution. 115 altimeter hits were required to statistically recreate the regional thickness mean and distribution for a three-town assemblage of mixed first- and multi-year ice, and 85 hits for a two-town assemblage of first-year ice only: equivalent to 19.5 and 14.5 km respectively of continuous altimeter track over a floe region of similar structure. Results have significant implications toward model development of sea-ice sampling performance of the ICESat laser altimeter record as well as maximizing sampling characteristics of satellite/airborne laser and radar altimetry missions for sea-ice thickness.