Geochemistry and sedimentology of IODP Hole 307-U1317E

The Plio-Pleistocene intensification of Northern Hemisphere continental ice-sheet development is known to have profoundly affected the global climate system. Evidence for early continental glaciation is preserved in sediments throughout the North Atlantic Ocean, where ice-rafted detritus (IRD) layers attest to the calving of sediment-loaded icebergs from circum-Atlantic ice sheets. So far, Early-Pleistocene IRD deposition has been attributed to the presence of high-latitudinal ice sheets, whereas the existence and extent of ice accumulation in more temperate, mid-latitudinal regions remains enigmatic. Here we present results from the multiproxy provenance analysis of a unique, Pleistocene-Holocene IRD sequence from the Irish NE Atlantic continental margin. There, the Challenger coral carbonate mound (IODP Expedition 307 site U1317) preserved an Early-Pleistocene record of 16 distinctive IRD events, deposited between ca 2.6 and 1.7 Ma. Strong and complex IRD signals are also identified during the mid-Pleistocene climate transition (ca 1.2 to 0.65 Ma) and throughout the Middle-Late Pleistocene interval. Radiogenic isotope source-fingerprinting, in combination with coarse lithic component analysis, indicates a dominant sediment source in the nearby British-Irish Isles, even for the oldest, Early-Pleistocene IRD deposits. Hence, our findings demonstrate, for the first time, repeated and substantial (i.e. marine-terminating) ice accumulation on the British-Irish Isles since the beginning of the Pleistocene. Contemporaneous expansion of both high- and mid-latitudinal ice sheets in the North Atlantic region is therefore implied at the onset of the Pleistocene. Moreover, it suggests the recurrent establishment of (climatically) favourable conditions for ice sheet inception, growth and instability in mid-latitudinal regions, even in the earliest stages of Northern Hemisphere glacial expansion and in an obliquity-driven climate system.

Carbonate conical mounds of the eastern Anti-Atlas(Morocco) and their relationship with potential analogues on Mars

Longstanding debates concerning the origin of the Kess Kess Emsian carbonate mounds exposed at Hamar Laghdad Ridge (eastern Anti-Atlas, Morocco) centre around the processes that induced precipitation of carbonate mud and the preservation of steep morphologies. Although in the last years an origin related to hydrothermalism seemed to be more likely, to date the Kess Kess are still considered controversial vent deposits. This study combines in updated research review information from previous work and new detailed field observations coupled with new analytical results to define a consistent framework and some new insight of current knowledge about the origin of these mounds. We obtain a complete minero-petrographic and palaeobiological data set and a detailed geochemical characterization of the different lithologies and facies of the Hamar Laghdad stratigraphic succession, including mounds, and we compared the results with the data from Maïder Basin mounds (Anti-Atlas, Morocco). Our data support the hydrothermal model proposed for the genesis and development of the Kess Kess mounds. The mechanisms linked to the mounds formation and growth are discussed in the light of the new finding of fluid-sediment interaction within a scenario driven by late magmatic fluids circulation. Conical mounds and other fluids related morphologies were also reported from Crommelin crater area (Arabia Terra, Mars). These mounds consist in meter-sized conical buildups hosted in the Equatorial Layered Deposits (ELDs) deposed during a regional groundwater fluid upwelling. Geometries and geological conditions that might have controlled the development of such morphologies were discussed. According to our data the morphological and stratigraphical characteristics of Crommelin area mounds are most consistent with a formation by fluids advection. Then we compare terrestrial and Martian data and examine the geological settings of hydrothermal mound occurrences on Earth in order to describe potential target areas for hydrothermal structures on Mars.

Carbonate cements in contemporaneous beachrocks, Jaguaribe beach, Itamaracá island, northeastern Brazil: petrographic, geochemical and isotopic aspects

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

(Table 1) Uranium and Thorium concentrations, activity ratios and calcium carbonate content of DSDP Site 54-424

The geochemical behaviour of uranium and thorium in metalliferous sediments and hydrothermal deposits has been widely studied and the main results have been summarised by Boström and Rydell. These isotopes may be used to clarify how the metal-rich solutions are introduced into sediment cover and seawater. Using radiochemistry followed by alpha spectrometry, we have measured uranium concentrations as high as several hundred p.p.m., which must clearly be associated with ocean ridge thermal activity, in sediments interbedded between the basaltic basement and the green hydrothermal mud at DSDP Site 424. These high uranium concentrations indicate the path followed by the hydrothermal fluid which, debouching at the sediment-water interface, formed the green mud.

Carbonate mineralogy and stable isotope composition of cool-water bryozoans from sediments of ODP Leg 182 sites

The carbon and oxygen isotopic compositions of selected bryozoan skeletons from upper Pleistocene bryozoan mounds in the Great Australian Bight (Ocean Drilling Program Leg 182; Holes 1129C, 1131A, and 1132B) were determined. Cyclostome bryozoans, Idmidronea spp. and Nevianipora sp., have low to intermediate magnesian calcite skeletons (1.5-10.0 and 0.9-6.4 molar percentage [mol%] MgCO3, respectively), but a considerable number include marine cements. The cheilostome Adeonellopsis spp. are biminerallic, principally aragonite, with some high magnesian calcite (HMC) (6.6-12.1 mol% MgCO3). The HMC fraction of Adeonellopsis has lower d13C and similar d18O values compared with the aragonite fraction. Reexamination of modern bryozoan isotopic composition shows that skeletons of Adeonellopsis spp. and Nevianipora sp. form close to oxygen isotopic equilibrium with their ambient water. Therefore, changes in glacial-interglacial oceanographic conditions are preserved in the oxygen isotopic profiles. The bryozoan oxygen isotopic profiles are correlated well with marine isotope Stages 1-8 in Holes 1129C and 1132B and to Stages 1-4(?) in Hole 1131A. The horizons of the bryozoan mounds that yield skeletons with heavier oxygen isotopic values can be correlated with isotope Stages 2, 4(?), 6, and 8 in Hole 1129C; Stages 2 and 4(?) in Hole 1131A; and Stages 2, 4, 6, and 8 in Hole 1132B. These results provide supporting evidence for a model for bryozoan mound formation, in which the mounds were formed during intensified upwelling and increased trophic resources during glacial periods.