Sr/Ca ratios and oxygen isotopes from sclerosponges

We investigate aragonitic skeletons of the Caribbean sclerosponge Ceratoporella nicholsoni from Jamaica, 20 m below sea level (mbsl), and Pedro Bank, 125 mbsl. We use d18O and Sr/Ca ratios as temperature proxies to reconstruct the Caribbean mixed layer and thermocline temperature history since 1400 A.D. with a decadal time resolution. Our age models are based on U/Th dating and locating of the radiocarbon bomb spike. The modern temperature difference between the two sites is used to tentatively calibrate the C. nicholsoni Sr/Ca thermometer. The resulting calibration points to a temperature sensitivity of Sr/Ca in C. nicholsoni aragonite of about -0.1 mmol/mol/K. Our Sr/Ca records reveal a pronounced warming from the early 19th to the late 20th century, both at 20 and 125 mbsl. Two temperature minima in the shallow water record during the late 17th and early 19th century correspond to the Maunder and Dalton sunspot minima, respectively. Another major cooling occurred in the late 16th century and is not correlatable with a sunspot minimum. The temperature contrast between the two sites decreased from the 14th century to a minimum in the late 17th century and subsequently increased to modern values in the early 19th century. This is interpreted as a long-term deepening and subsequent shoaling of the Caribbean thermocline. The major trends of the Sr/Ca records are reproduced in both specimens but hardly reflected in the d18O records.

Agaete revisited: new data on the Gran Canaria tsunamiites.

The tsunami deposits of the valley of Agaete (Pérez-Torrado et al., 2006), north-western Gran Canaria, attributed to the Guimar flank collapse in Tenerife, have been revisited and new data are presented here. Besides the occurrences reported by Pérez-Torrado et al. (2006) a new outcrop was found and named “La Ruina” (at 28º 05’ 47,41” N; 15º 41’ 52,04” W; 71 m asl). The above-mentioned authors suggested the possibility that more than one marine conglomerate deposit could be present in the outcrops of “Llanos de Turmán” and “Berrazales”. At “La Gasolinera” and “La Aldea 1” the conglomerates are formed by a single layer representing one depositional event; at “La Aldea 2”, the conglomerates are composed of two layers directly contacting with each other, but evidence of a time hiatus between them was not found. Although the hypothesis of stacking of two depositional units within the same episode versus deposition of two distinct layers in different time-moments is debatable at the present state of knowledge, the first possibility is favoured. The field evidence at “Llanos de Turman” and “Berrazales” unquestionably shows that terrestrial sediments (colluvia; paleosols) are present and separate two marine conglomerate deposits, indicating that at least two distinct tsunami inundations are needed to explain the stratigraphy. However, at the new “La Ruina” outcrop, besides the two deposits mentioned above, a third and older marine conglomerate was found, clearly separated in time from the ones cited above. The existence of marine conglomerates emplaced in different moments is evidenced by the occurrence of intercalated paleosols, colluvia and other subaerial materials, implying significant time intervals between the emplacement of marine conglomeratic layers. A number of gastropod operculae from the tsunamiites were sent for U-Th dating to try to further constrain the age span of these deposits. The field evidence presented above shows that the emplacement of the deposits is related to, at least, three tsunami events. The lateral correlation between different outcrops is difficult due to variable number of deposits in each outcrop, lateral discontinuity and variability, and to compositional and textural similarity between distinct tsunami sediments. The occurrence of three Pleistocene tsunami deposits in the same area points to a relatively high frequency of tsunamis (generated by landslides, surface rupturing earthquakes, fast entry of voluminous volcanic deposits into the sea or large submarine eruptions). It is possible that this recurrence of tsunami inundations may reflect multiple-phased landslides responsible for the mega-landslide scars prominent in the geomorphology of the neighbouring island of Tenerife. This is a contribution from project “Estabilidad de los edificios volcánicos en Canarias: análisis de los factores geológicos, geomecánicos y paleoclimáticos. Aplicación a los flancos N y S de la isla de Tenerife” financed by MCT, Spain.

(Table 2) Uranium and thorium isotopic composition, activity ratios and ages of bivalvia shells in sediment core GIK14350, northern Germany

A new chemical procedure for cleaning marine carbonates was applied to remove detritus as well as metaloxide contaminations of marine shells from Eemian deposits and adjoining succession of a sediment core from Dagebüll, Schleswig- Holstein. Hence, one can significantly reduce the contamination with detrital uranium and thorium. Thermal ionisation mass spectrometry was applied to determine the uranium and thorium activities used for 230Th/U dating of these shells. At least ten samples of marine bivalves of five different core sections were analysed. Samples located below a five meter thick clay layer at 19-24 m yielded an average age of 132±18 ka. Shells located above the clays at 15-20 m depth were strongly influenced by percolating groundwaters of an open system. Therefore, a reliable dating of these samples was not possible.

Sea surface temperature variations recorded on coralline Sr/Ca ratios during Mid-Late Holocene in Leizhou Peninsula

High-resolution Sr/Ca ratios of two Porites corals from Leizhou Peninsula were measured using inductively coupled plasma atomic spectrometry (ICP-AES). TIMS U-Th dating reveals that the life-spans of the two corals are 489500 AD and 539-530 BC, respectively. Monthly sea surface temperatures (SSTs) during these two periods can be reconstructed from their skeletal Sr/Ca ratios. The results reveal that SSTs during 539-530 BC were roughly the same as those during 1990-2000 AD in this area, indicating a relative warm climate period. However, the period of 489-500 AD was significantly cooler, with annual mean SST, the 10-a average of minimum monthly winter SSTs and the 10-a average of maximum monthly summer SSTs being about 2, 2.9 and 1degreesC lower than that in the 1990s, respectively. Such climate patterns agree well with the phenological results recorded in the historic documents in other areas of China.

Dating of the quaternary terraces close to the Chenab river (Western Himalaya)

A morphotectonic study has been performed in the Pir Panjal Range (Southern Kashmir, Western Himalaya) to characterised the active tectonics. Along the Chenab River, we mapped 7 strath terraces at the hanging wall of the Medlicott Wadia Thrust, and dated 3 regional alluviation events using 3 methods (53 10Be samples, 12 OSL and 3 14C). The 3 methods are briefly presented and data are shown in a table. The three alluviation events correspond to the end of maximum monsoon phases.

The last glacial cycle from the humid tropics of northeastern Australia: comparison of a terrestrial and a marine record

A detailed pollen record from the Ocean Drilling Program Site 820 core, located on the upper part of the continental slope off the coast of northeast Queensland, was constructed to compare with the existing pollen record from Lynch's Crater on the adjacent Atherton Tableland and allow the production of a regional picture of vegetation and environmental change through the last glacial cycle. Some broad similarities in patterns of vegetation change are revealed, despite the differences between sites and their pollen catchments, which can be related largely to global climate and sea-level changes. The original estimated time scale of the Lynch's Crater record is largely confirmed from comparison with the more thoroughly dated ODP record. Conversely, the Lynch's Crater pollen record has assisted in dating problematic parts of the ODP record. In contrast to Lynch's Crater, which reveals a sharp and sustained reduction in drier araucarian forest around 38,000 yrs BP, considered to have been the result of burning by Aboriginal people, the ODP record indicates, most likely, a stepwise reduction, dating from 140,000 yrs BP or beyond. The earliest reduction shows lack of a clear connection between Araucaria decline and increased burning and suggests that people may not have been involved at this stage. However, a further decline in araucarian forest, possibly around 45,000 yrs BP, which has a more substantial environmental impact and is not related to a time of major climate change, is likely, at least partially, the result of human burning. The suggestion, from the ODP core oxygen isotope record, of a regional sea-surface temperature increase of around 4 degrees C between about 400,000 and 250,000 yrs BP, may have had some influence on the overall decline in Araucaria and its replacement by sclerophyll vegetation. (C) 2000 Elsevier Science B.V. All rights reserved.

Geochronological constraints on the age of a Permo-Triassic impact event: U-Pb and Ar-40/Ar-39 results for the 40 km Araguainha structure of central Brazil

Impact cratering has been a fundamental geological process in Earth history with major ramifications for the biosphere. The complexity of shocked and melted rocks within impact structures presents difficulties for accurate and precise radiogenic isotope age determination, hampering the assessment of the effects of an individual event in the geological record. We demonstrate the utility of a multi-chronometer approach in our study of samples from the 40 km diameter Araguainha impact structure of central Brazil. Samples of uplifted basement granite display abundant evidence of shock deformation, but U/Pb ages of shocked zircons and the Ar-40/Ar-39 ages of feldspar from the granite largely preserve the igneous crystallization and cooling history. Mixed results are obtained from in situ Ar-40/Ar-39 spot analyses of shocked igneous biotites in the granite, with deformation along kink-bands resulting in highly localized, partial resetting in these grains. Likewise, spot analyses of perlitic glass from pseudotachylitic breccia samples reflect a combination of argon inheritance from wall rock material, the age of the glass itself, and post-impact devitrification. The timing of crater formation is better assessed using samples of impact-generated melt rock where isotopic resetting is associated with textural evidence of melting and in situ crystallization. Granular aggregates of neocrystallized zircon form a cluster of ten U-Pb ages that yield a "Concordia" age of 247.8 +/- 3.8 Ma. The possibility of Pb loss from this population suggests that this is a minimum age for the impact event. The best evidence for the age of the impact comes from the U-Th-Pb dating of neocrystallized monazite and Ar-40/Ar-39 step heating of three separate populations of post-impact, inclusion-rich quartz grains that are derived from the infill of miarolitic cavities. The Pb-206/U-238 age of 254.5 +/- 3.2 Ma (2 sigma error) and Pb-208/Th-232 age of 255.2 +/- 4.8 Ma (2 sigma error) of monazite, together with the inverse, 18 point isochron age of 254 +/- 10 Ma (MSWD = 0.52) for the inclusion-rich quartz grains yield a weighted mean age of 254.7 +/- 2.5 Ma (0.99%, 2 sigma error) for the impact event. The age of the Araguainha crater overlaps with the timing of the Permo-Triassic boundary, within error, but the calculated energy released by the Araguainha impact is insufficient to be a direct cause of the global mass extinction. However, the regional effects of the Araguainha impact event in the Parana-Karoo Basin may have been substantial. (C) 2012 Elsevier Ltd. All rights reserved.

U-Pb zircon in situ dating with LA-MC-ICP-MS using a mixed detector configuration

The LA-MC-ICP-MS method applied to U-Pb in situ dating is still rapidly evolving due to improvements in both lasers and ICP-MS. To test the validity and reproducibility of the method, 5 different zircon samples, including the standard Temora-2, ranging in age between 2.2 Ga and 246 Ma, were dated using both LA-MC-ICP-MS and SHRIMP. The selected zircons were dated by SHRIMP and, after gentle polishing, the laser spot was driven to the same site or on the same zircon phase with a 213 nm laser microprobe coupled to a multi-collector mixed system. The data were collected with a routine spot size of 25 μm and, in some cases, of 15 and 40 μm. A careful cross-calibration using a diluted U-Th-Pb solution to calculate the Faraday reading to counting rate conversion factors and the highly suitable GJ-1 standard zircon for external calibrations were of paramount importance for obtaining reliable results. All age results were concordant within the experimental errors. The assigned age errors using the LA-MC-ICP-MS technique were, in most cases, higher than those obtained by SHRIMP, but if we are not faced with a high resolution stratigraphy, the laser technique has certain advantages.

Fine-silt luminescence dating and mineral composition of sediments from the Arctic Ocean

New geochronometers are needed for sediments of the Arctic Ocean spanning at least the last half million years, largely because oxygen-isotope stratigraphy is relatively ineffective in this ocean, and because other dating techniques require significant assumptions about sedimentation rates. Multi-aliquot luminescence sediment-dating procedures were applied to polymineral, fine-silt samples from 9 core-top and 37 deeper samples from 20 cores representing 19 sites across the Arctic Ocean. Most samples have independent age assignments and other known properties (e.g., % coarse fraction, % carbonate, U-Th isotopes). Thick-source alpha-particle counting indicates that for most regions the contribution of measured unsupported 230Th and 231Pa to calculated dose rates is dating, and suggests that for several regions of the Arctic Ocean, interglacial-stage (foram-'rich') sediments from ridge tops are preferred for the fine-grain luminescence dating methods.

Palaeoclimatic implications of the growth history and stable isotope (delta O-18 and delta C-13) geochemistry of a Middle to Late Pleistocene stalagmite from central-western Italy

The age structure and, stable isotope composition of a stalagmite (CC I) from an upland cave in central-western Italy were studied to investigate regional response to global climatic changes. Four growth phases are constrained by 28 thermal ionization and multi-collector inductively coupled plasma mass spectrometry Th-U ages and reveal intermittent deposition through the period between Marine isotope Stage (MIS) 11 and 3 (similar to380 and similar to43 kyr). Most of the growth took place between similar to380 and similar to280 kyr, a period punctuated briefly by a hiatus in deposition through the glacial maximum of MIS 10. Growth was terminated abruptly at 280 kyr just prior to the MIS 8 glacial maximum. With a present-day chamber temperature of 7.5 degreesC, the timing of hiatuses close to these glacial maxima point to freezing conditions at the time. No deposition was recorded through the entirety of MIS 7 and most of MIS 6, whilst two minor growth phases occurred at similar to141-125 and similar to43 kyr. Growth at 141 kyr indicates temperatures >0 degreesC at a time when MIS 6 ice volumes were close to their maximum. High stable carbon isotope (delta(13)C) values (similar to2.8parts per thousand to +3.1parts per thousand) throughout the stalagmite's growth reflect a persistently low input of biogenic CO2, indicating that the steep, barren and alpine-like recharge area of today ha's been in existence for at least the last similar to380 kyr. During MIS 9, the lowest delta(13)C values occur well after maximum interglacial conditions, suggesting a lag in the development of post-glacial soils in this high-altitude karst. The stable oxygen isotope (delta(18)O) trends match the main structural features of the major climate proxy records (SPECMAP, Vostok and Devils Hole), suggesting that the delta(18)O of CC1 has responded to global-scale climate changes, whilst remarkable similarity exists between CC1 delta(18)O and regional sea-surface temperature reconstructions from North Atlantic core ODP980 and southwest Pacific marine core MD97-2120 through the most detailed part of the CC1 record, MIS 9-8. The results suggest that CC1 and other stalagmites from the cave have the potential to capture a long record of regional temperature trends, particularly in regards to the relative severity of Pleistocene glacial stages. (C) 2004 Elsevier B.V. All rights reserved.