Síntese e caracterização de NiO-CGO para anodo e eletrólitos sólidos e base de Céria para SOFC

The direct use of natural gas makes the Solid Oxide Fuel Cell (SOFC) potentially more competitive with the current energy conversions technologies. The Intermediate Temperature SOFC (IT-SOFC) offer several advantages over the High Temperature SOFC (HT-SOFC), which includes better thermal compatibility among components, fast start with lower energy consumption, manufacture and operation cost reduction. The CeO2 based materials are alternatives to the Yttria Stabilized Zirconia (YSZ) to application in SOFC, as they have higher ionic conductivity and less ohmic losses comparing to YSZ, and they can operate at lower temperatures (500-800°C). Ceria has been doped with a variety of cations, although, the Gd3+ has the ionic radius closest to the ideal one to form solid solution. These electrolytes based in ceria require special electrodes with a higher performance and chemical and termomechanical compatibility. In this work compounds of gadolinia-doped ceria, Ce1-xGdxO2-δ (x = 0,1; 0,2 and 0,3), used as electrolytes, were synthesized by polymeric precursors method, Pechini, as well as the composite material NiO - Ce0,9Gd0,1O1,95, used as anode, also attained by oxide mixture method, mixturing the powders of the both phases calcinated already. The materials were characterized by X ray diffraction, dilatometry and scanning electronic microscopy. The refinement of the diffraction data indicated that all the Ce1-xGdxO2-δ powders were crystallized in a unique cubic phase with fluorite structure, and the composite synthesized by Pechini method produced smaller crystallite size in comparison with the same material attained by oxide mixture method. All the produced powders had nanometric characteristics. The composite produced by Pechini method has microstructural characteristics that can increase the triple phase boundaries (TPB) in the anode, improving the cell efficiency, as well as reducing the mass transport mechanism effect that provokes anode degradation

Perspetivas de utilização do potencial eólico em Timor-Leste

A exigência energética global está mais orientada para a utilização das fontes de Energias Renováveis (FERs), comprometendo e garantindo um desenvolvimento sustentável. Este trabalho tem como objetivo contribuir para o atingir das metas do PED 2011-2030, no que refere à utilização das FER, em particular do potencial eólico em Timor-Leste. Timor-Leste tem apresentado um grande interesse na política de aproveitamento de FER para alcançar a meta de longo prazo de PED 2030, comprometendo-se com o desenvolvimento sustentável através de ERs. Este trabalho pretende contribuir em particular com o estudo do aproveitamento de energia eólica. Com base no clima do vento de longo termo entre 2004 – 2012, da estação meteorológica (EM) de Díli e conjugando estes com os dados da campanha experimental de Martifer cedidos, de Dezembro 2008 - Novembro 2009, obteve-se o coeficiente de variabilidade (Cvariab.) inter-anual. Foi assim possível construir o mapa médio do vento de longo termo, com modelo atmosférico de mesoscala, numa resolução refinada de 3×3 km. Para a identificação dos locais mais favoráveis do vento, foi utilizado o modelo ArcGIS para georreferenciação do recurso. A filtragem das restrições e os constrangimentos do terreno permitiu construir o mapa do vento sustentável de Timor-Leste, por distritos, subdistritos, sucos, do enclave de Oecússi e a ilha de Atauro, o que conduziu à hierarquização de cinco zonas favoráveis (zona 1 - 5). A contribuição para o plano energético de Timor-Leste consiste em duas fases: - a 1ª fase o aproveitamento eólico em três PEs nas zonas monitorizadas (3 e 5) oriundo de dados cedidos pela Martifer, contabilizou-se um total de 424.694 MWh de produção de energia anual, tendo-se verificado o custo normalizado de energia (LCOE) no valor médio calculado de 0,046 €/kWh; - na 2ª fase a construção de acesso e o desenvolvimento de PEs nas zonas 1, 2 e 4 para o Cenário de Max-Renovável. Assim sendo, viabilizam a "Perspetiva de Utilização da Energia Eólica" no quadro do PED 2011 - 2030 de Timor-Leste, que viria reduzir o custo de produção de energia atual, e a emissão de CO2; Abstract: Prospects of Using Wind Energy in Timor-Leste The demand for global energy is more focused on the use of Reneweable Energy sources (REs), ensuring and committing itself to sustainable development. This study was prompted by the wish to contribute to the achievement the goals of the Strategic Development Plan (PED 2011-2030) regarding the use of REs, particularly the wind energy in Timor-Leste. Timor-Leste has presented a great interest in the use of renewable energy sources policy to achieve the long term goal of the PED 2030, committing to a sustainable development through renewable energy. This thesis intends to contribute in particular with the study of the use of wind energy. Based on the long term wind climate between 2004 and 2012 of the Díli weather station and combining these data with the Martifer campaign experimental data of December 2008 - November 2009, the interannual variation coefficient (Cv) was obtained. Thus, it was possible to build the map of long term average wind with atmospheric mesoscale model in a refined resolution of 3×3 km. The ArcGIS model was used for the identification of the most favorable locations of the wind for its georeferencing. The constraining of filtering and the constraints of the terrain allowed to construe the sustainable wind map of Timor-Leste in distritos, subdistritos, sucos, and also of the enclave of Oecussi and Atauro island, which led to the ranking of five favorable areas (zone 1-5) for an immediate experimental campaign of wind characterization and utilization of this resource in wind parks. The contribution to Timor-Leste's energy plan consists of two phases: - the first phase of three wind farms in zone (3 and 5) from data provided by Martifer, a total of 424,694 MWh, and levelyzed cost of electricity (LCOE) in the calculated average value of 0.046 €/kWh; - in the second phase the construction of access and development of wind farms in zones 1, 2 and 4 for the Max-Renewable Scenario. As such, they make possible the "Perspective of Wind Energy Use" in Timor Leste’s PED 2011 - 2030, which would reduce current energy production costs and CO2 emissions.

Cambio de paradigma energético y las nuevas tecnologías

Considering the wide implications of global warming it is evident the need, not only of diminishing the energy consumption patterns, but of diversifying to “sustainable” energy resources. Moreover, within the frame of national security, this requires tore-think the managing and use of available resources, because any change of the energy paradigm will depend, at least at the beginning, on fossil energy.Considering the above, the following paper opens a discussion about energy, entropy and the limits of economic growth, following the premises of the school of ecological economics. It offers several empirical data about the situation of the current energy pattern, mostly about its socio-environmental aspects. The paper ends discussing the characteristics and limitations of the main available alternative energies; meanwhile it highlights the relevance of contemporary patterns of territorial organization. It concludes pointing out the inherent need of diminishing the type and rhythm of current energy consumption.

Energy systems and their impacts on marine ecosystem services

Global warming and its link to the burning of fossil fuels has prompted many governments around the world to set legally binding greenhouse gas reduction targets which are to be partially realised through a stronger reliance on renewable (e.g. wind) and other lower carbon (i.e. natural gas and nuclear) energy commodities. The marine environment will play a key role in hosting or supporting these new energy strategies. However, it is unclear how the construction, operation and eventual decommissioning of these energy systems, and their related infrastructure, will impact the marine environment, the ecosystem services (i.e. cultural, regulating, provisioning and supporting) and in turn the benefits it provides for human well-being. This uncertainty stems from a lack of research that has synthesised into a common currency the various effects of each energy sector on marine ecosystems and the benefits humans derive from it. To address this gap, the present study reviews existing ecosystem impact studies for offshore components of nuclear, offshore wind, offshore gas and offshore oil sectors and translates them into the common language of ecosystem service impacts that can be used to evaluate current policies. The results suggest that differences exist in the way in which energy systems impact ecosystem services, with the nuclear sector having a predominantly negative impact on cultural ecosystem services; oil and gas a predominately negative impact on cultural, provisioning, regulating and supporting ecosystem services; while wind has a mix of impacts on cultural, provisioning and supporting services and an absence of studies for regulating services. This study suggests that information is still missing with regard to the full impact of these energy sectors on specific types of benefits that humans derive from the marine environment and proposes possible areas of targeted research.

Impact of Energy Quantization on the Performance of Current-Biased SET Circuits

The current-biased single electron transistor (SET) (CBS) is an integral part of almost all hybrid CMOS SET circuits. In this paper, for the first time, the effects of energy quantization on the performance of CBS-based circuits are studied through analytical modeling and Monte Carlo simulations. It is demonstrated that energy quantization has no impact on the gain of the CBS characteristics, although it changes the output voltage levels and oscillation periodicity. The effects of energy quantization are further studied for two circuits: negative differential resistance (NDR) and neuron cell, which use the CBS. A new model for the conductance of NDR characteristics is also formulated that includes the energy quantization term.

Habitat mapping effort at the Olympic Coast National Marine Sanctuary – Current status and future needs

With elevating interest to establish conservation efforts for groundfish stocks and continued scrutiny over the value of marine protected areas along the west coast, the importance of enhancing our knowledge of seabed characteristics through mapping activities is becoming increasingly more important, especially in a timely manner. Shortly after the inception of the Seabed Mapping Initiative instituted with the US Geological Survey (USGS), the National Marine Sanctuary Program (NMSP) assembled a panel of habitat mapping experts. They determined that the status of existing data sets and future data acquisition needs varied widely among the individual sanctuaries and that more detailed site assessments were needed to better prioritize mapping efforts and outline an overall joint strategy. To assist with that specific effort and provide pertinent information for the Olympic Coast National Marine Sanctuary’s (OCNMS) Management Plan Review, this report summarizes the mapping efforts that have taken place at the site to date; calculates a timeframe for completion of baseline mapping efforts when operating under current data acquisition limitations; describes an optimized survey strategy to dramatically reduce the required time to complete baseline surveying; and provides estimates for the needed vessel sea-days (DAS) to accomplish baseline survey completion within a 2, 5 and 10 year timeframe. (PDF contains 38 pages.)

Rescue, rehabilitation, and release of marine mammals: An analysis of current views and practices.

Stranded marine mammals have long attracted public attention. Those that wash up dead are, for all their value to science, seldom seen by the public as more than curiosities. Animals that are sick, injured, orphaned or abandoned ignite a different response. Generally, public sentiment supports any effort to rescue, treat and return them to sea. Institutions displaying marine mammals showed an early interest in live-stranded animals as a source of specimens -- in 1948, Marine Studios in St. Augustine, Florida, rescued a young short-finned pilot whale (Globicephala macrorhynchus), the first ever in captivity (Kritzler 1952). Eventually, the public as well as government agencies looked to these institutions for their recognized expertise in marine mammal care and medicine. More recently, facilities have been established for the sole purpose of rehabilitating marine mammals and preparing them for return to the wild. Four such institutions are the Marine Mammal Center (Sausalito, CA), the Research Institute for Nature Management (Pieterburen, The Netherlands), the RSPCA, Norfolk Wildlife Hospital (Norfolk, United Kingdom) and the Institute for Wildlife Biology of Christian-Albrects University (Kiel, Germany).(PDF contains 68 pages.)

Marine Ranching: Proceedings of the Seventeenth U.S.-Japan Meeting on Aquaculture Ise, Mie Prefecture, Japan October 16, 17, and 18, 1988, Satellite Symposium: October 20

The United States and Japanese counterpart panels on aquaculture were formed in 1969 under the United States-Japan Cooperative Program in Natural Resources (UJNR). The panels currently include specialists drawn from the federal departments most concerned with aquaculture. Charged with exploring and developing bilateral cooperation, the panels have focused their efforts on exchanging information related to aquaculture which could be of benefit to both countries. The UJNR was begun during the Third Cabinet-Level Meeting of the Joint United States-Japan Committee on Trade and Economic Affairs in January 1964. In addition to aquaculture, current subjects in the program include desalination of seawater, toxic microorganisms, air pollution, energy, forage crops, national park management, mycoplasmosis, wind and seismic effects, protein resources, forestry, and several joint panels and committees in marine resources research, development, and utilization. Accomplishments include increased communication and cooperation among technical specialists; exchanges of information, data, and research findings; annual meetings of the panels, a policy-coordinative body; administrative staff meetings; exchanges of equipment, materials, and samples; several major technical conferences; and beneficial effects on international relations. (PDF file contains 186 pages.)

Marine farming and enhancement: Proceedings of the Fifteenth U.S.-Japan Meeting on Aquaculture, Kyoto, Japan October 22-23, 1986

The United States and Japanese counterpart panels on aquaculture were formed in 1969 under the United States-Japan Cooperative Program in Natural Resources (UJNR). The panels currently include specialists drawn from the federal departments most concerned with aquaculture. Charged with exploring and developing bilateral cooperation, the panels have focused their efforts on exchanging information related to aquaculture which could be of benefit to both countries. The UJNR was begun during the Third Cabinet-Level Meeting of the Joint United States-Japan Committee on Trade and Economic Affairs in January 1964. In addition to aquaculture, current subjects in the program include desalination of seawater, toxic microorganisms, air pollution, energy, forage crops, national park management, mycoplasmosis, wind and seismic effects, protein resources, forestry, and several joint panels and committees in marine resources research, development, and utilization. Accomplishments include: Increased communication and cooperation among technical specialists; exchanges of information, data, and research findings; annual meetings of the panels, a policy-coordinative body; administrative staff meetings; exchanges of equipment, materials, and samples; several major technical conferences; and beneficial effects on international relations. (PDF file contains 134 pages.)

Proceedings of the Seventh U.S.-Japan Meeting on Aquaculture, Marine Finfish Culture, Tokyo, Japan, October 3-4, 1978

The United States and Japanese counterpart panels on aquaculture were formed in 1969 under the United States-Japan Cooperative Program in Natural Resources (UJNR). The panels currently include specialists drawn from the federal departments most concerned with aquaculture. Charged with exploring and developing bilateral cooperation, the panels have focused their efforts on exchanging information related to aquaculture which could be of benefit to both countries. The UJNR was started by a proposal made during the Third Cabinet-Level Meeting of the Joint United States-Japan Committee on Trade and Economic Affairs in January 1964. In addition to aquaculture, current subjects in the program are desalination of seawater, toxic microorganisms, air pollution, energy, forage crops, national park management, mycoplasmosis, wind and seismic effects, protein resources, forestry, and several joint panels and committees in marine resources research, development, and utilization. Accomplishments include: Increased communications and cooperation among technical specialists; exchanges of information, data, and research findings; annual meetings of the panels, a policy coordinative body;' administration staff meetings; exchanges of equipment, materials, and samples; several major technical conferences; and beneficial effects on international relations.(PDF file contains 37 pages.)

Current dependence of the energy gap in superconductors : a direct measurement

From the tunneling characteristics of a tin-tin oxide-lead junction, a direct measurement has been made of the energy-gap variation for a superconductor carrying a current in a compensated geometry. Throughout the region investigated – several temperatures near T_c and down to a reduced temperature t = 0.8 –the observed current dependence agrees quite well with predictions based on the Ginzburg-Landau-Gor’kov theory. Near T_c the predicted temperature dependence is also well verified, though deviations are observed at lower temperatures; even for the latter, the data are internally consistent with the temperature dependence of the experimental critical current. At the lowest temperature investigated, t = 0.8, a small “Josephson” tunneling current allowed further a direct measurement of the electron drift velocity at low current densities. From this, a preliminary experimental value of the critical velocity, believed to be the first reported, can be inferred in the basis of Ginzburg-Landau theory. For tin at t = 0.8, we find v_c = 87 m/sec. This value does not appear fully consistent with those predicted by recent theories for superconductors with short electronic mean-free-paths.

Effects of starvation on energy density of juvenile chum salmon (Oncorhynchus keta) captured in marine waters of Southeastern Alaska

We conducted laboratory starvation experiments on juvenile chum salmon (Oncorhynchus keta) captured in the neritic marine waters of northern Southeast Alaska in June and July 2003. Temporal changes in fish energy density (whole body energy content [WBEC], cal/g dry weight), percent moisture content, wet weight (g), length (mm), and size-related condition residuals were measured in the laboratory and were then compared to long-term field data. Laboratory water temperatures and salinities averaged 9°C and 32 psu in both months. Trends in response variables were similar for both experimental groups, although sampling intervals were limited in July because fewer fish were available (n= 54) than in June (n=101). Overall, for June (45-d experimental period, 9 intervals), WBEC, wet weight, and condition residuals decreased and percent moisture content increased, whereas fork length did not change. For July (20-d experimental period, 5 intervals), WBEC and condition residuals decreased, percent moisture content and fork length increased, and wet weight did not change. WBEC, percent moisture content, and condition residuals fell outside the norm of longterm data ranges within 10–15 days of starvation, and may be more useful than fork length and wet weight for detecting fish condition responses to suboptimal environments.

Diets of and trophic relationships among dominant marine nekton within the northern California Current ecosystem

In this study we analyzed the diets of 26 nekton species collected from two years (2000 and 2002) off Oregon and northern California to describe dominant nekton trophic groups of the northern California Current (NCC) pelagic ecosystem. We also examined interannual variation in the diets of three nekton species. Cluster analysis of predator diets resulted in nekton trophic groups based on the consumption of copepods, euphausiids, brachyuran larvae, larval juvenile fishes, and adult nekton. However, many fish within trophic groups consumed prey from multiple trophic levels—euphausiids being the most widely consumed. Comparison of diets between years showed that most variation occurred with changes in the contribution of euphausiids and brachyuran larvae to nekton diets. The importance of euphausiids and other crustacean prey to nekton indicates that omnivory is an important characteristic of the NCC food web; however it may change during periods of lower or higher upwelling and ecosystem production.

Work plan for analytical support of an integrated ecosystem assessment of the California Current Large Marine Ecosystem, FY11 ‐ FY13

NOAA/NCCOS is conducting the following work for the NOAA California Current Integrated Ecosystem Assessment, in support of the NOAA/NMFS Northwest Fisheries Science Center.