Discovery of Highly Excited Long-Lived Isomers in Neutron-Rich Hafnium and Tantalum Isotopes through Direct Mass Measurements

A study of cooled Au-197 projectile-fragmentation products has been performed with a storage ring. This has enabled metastable nuclear excitations with energies up to 3 MeV, and half-lives extending to minutes or longer, to be identified in the neutron-rich nuclides Hf-183,Hf-184,Hf-186 and Ta-186,Ta-187. The results support the prediction of a strongly favored isomer region near neutron number 116.

Neutron-Proton Asymmetry Dependence of Spectroscopic Factors in Ar Isotopes

Spectroscopic factors have been extracted for proton-rich Ar-34 and neutron-rich Ar-46 using the (p, d) neutron transfer reaction. The experimental results show little reduction of the ground state neutron spectroscopic factor of the proton-rich nucleus Ar-34 compared to that of Ar-46. The results suggest that correlations, which generally reduce such spectroscopic factors, do not depend strongly on the neutronproton asymmetry of the nucleus in this isotopic region as was reported in knockout reactions. The present results are consistent with results from systematic studies of transfer reactions but inconsistent with the trends observed in knockout reaction measurements.

Rotation alignment in neutron-rich Cr isotopes: A probe of deformed single-particle levels across N=40

Recent experiments have reached the neutron-rich Cr isotope with N = 40 and confirmed enhanced collectivity near this subshell. The current data focus on low-spin spectroscopy only, with little information on the states where high-j particles align their spins with the system rotation. By applying the projected shell model, we show that rotation alignment occurs in neutron-rich even-even Cr nuclei as early as spin 8 (h) over bar h and, owing to shell filling, the aligning particles differ in different isotopes. It is suggested that observation of irregularities in moments of inertia is a direct probe of the deformed single-particle scheme in this exotic mass region.

Penning trap mass measurements on nobelium isotopes

The Penning trap mass spectrometer SHIPTRAP at GSI Darmstadt allows accurate mass measurements of radionuclides, produced in fusion-evaporation reactions and separated by the velocity filter SHIP from the primary beam. Recently, the masses of the three nobelium isotopes No252-254 were determined. These are the first direct mass measurements of transuranium elements, which provide new anchor points in this region. The heavy nuclides were produced in cold-fusion reactions by irradiating a PbS target with a Ca-48 beam, resulting in production rates of the nuclei of interest of about one atom per second. In combination with data from decay spectroscopy our results are used to perform a new atomic-mass evaluation in this region.

Bi同位素链上原子核α衰变性质的理论研究；Theoretical Study on α Decay Properties for Bi Isotopes

采用结团模型(clustermodel)计算了从10752Te到292116共443个核素α衰变的半衰期,所得结果与实验值符合得很好,显示了结团模型可以成功地应用于研究原子核α衰变的性质。同时研究了Bi同位素链上奇A核α衰变的半衰期,计算结果与已有的实验值的偏差一般在3倍以内,进而对实验上未知α衰变半衰期的原子核的性质进行了预言。这有助于将来在实验室探测与鉴别这些原子核以及研究它们的α衰变性质。理论与实验的比较将加深人们对原子核结构的认识。

Two-quasiparticle K-isomeric states in strongly deformed neutron-rich Nd and Sm isotopes: a projected shell-model analysis

Motivated by recent spectroscopy data from fission experiments, we apply the projected shell model to study systematically the structure of strongly deformed, neutron-rich, even-even Nd and Sm isotopes with neutron number from 94 to 100. We perform calculations for rotational bands up to spin I = 20 and analyze the band structure of low-lying states with quasiparticle excitations, with emphasis given to rotational bands based on various negative-parity two-quasiparticle (2-qp) isomers. Experimentally known isomers in these isotopes are described well. The calculations further predict proton 2-qp bands based on a 5(-) and a 7(-) isomer and neutron 2-qp bands based on a 4(-) and an 8(-) isomer. The properties for the yrast line are discussed, and quantities to test the predictions are suggested for future experiment.

~(12)C与~(209)Bi反应中Au同位素的产额与Q_(gg)的关系；Q_(gg)-Yield Dependence of Au Isotopes in Interaction of 47 MeV/u ~(12)C With ~(209)Bi

用47MeV/u12C离子轰击天然铋靶,通过炮弹和靶核之间的核子转移反应产生Au同位素。使用放射化学方法从大量Bi和复杂反应产物中分离、纯化Au,并制备Au的γ射线测量源。使用HPGe探测器测量放射性Au同位素的γ活性。根据照射结束时Au同位素的活度和其他相关数据,确定每个Au同位素的产生截面。分析发现,缺中子Au同位素的产生截面与Qgg值之间不遵从指数依赖关系,这可用重离子碰撞中的次级过程加以解释。

Gas-phase isothermal chromatography with short-lived technetium isotopes

In order to study the gas-phase chemical behavior of transactinides, an on-line isothermal chromatography apparatus has been developed and applied to separate short-lived technetium isotopes in the form of TcO3 from fission products. The fission products from a Cf-252 source were continuously and rapidly transported through the capillary to the isothermal chromatography apparatus using the N-2/KBr gas-jet techniques. Volatile oxide molecules were formed at the reaction zone kept at 900 degrees C since a trace amount of oxygen existed in the N-2 carrier gas. With the new developed isothermal chromatography apparatus, a selective separation of Tc from fission products was achieved. After isothermal chromatographic separation, Tc-101,Tc-103,Tc-104,Tc-105,Tc-106,Tc-107,Tc-108 were dominantly observed together with their Ru daughters in the gamma-spectrum, The chemical yields of Tc-101, and Tc-104 and Tc-105 isotopes with longer half-lives are about 55-57%, and those of Tc-103, Tc-106 and Tc-108 isotopes with shorter half-lives dropped down to 25-28%. The adsorption enthalpy of the investigated compounds on quartz surfaces was determined to be -150 +/- 5 kJ/mol by fitting the measured retention curves with a Monte Carlo model. The observed species of technetium oxide is attributed to TcO3, which is in good agreement with previous experimental results. That means our system worked properly and it can be used to investigate the gas-phase chemical behavior of transactinides.

Electrochemistry of hydroquinone derivatives at metal and iodine-modified metal electrodes

The difference in the electrochemical behavior of hydroquinone and pyrocatechol. at platinum and gold surfaces was analyzed using voltammetry and attenuated total reflection Fourier transform infrared spectroscopy. The results show that the hydroquinone derivatives are adsorbed on a gold surface with vertical orientation, which makes the electron transfer between the bulk species and the electrode surface easier than that in the case of flat adsorption of hydroquinone derivatives that occurs at a platinum electrode. The formation of the vertical conformation and the rapid process of electron transfer were also confirmed by quantum chemistry calculations. In addition, the pre-adsorbed iodine on the electrodes played a key role on the adsorbed configuration and. electron transfer of redox species.

ON THE IODINE-DOPING OF POLYANILINE AND POLY-ORTHO-METHYLANILINE

The reactions of polyaniline and poly-omicron-methylaniline of different oxidation degrees with I2 were followed by FTIR and electrical conductivity measurements. The results showed that the reaction of common polyanilines with I2 was oxidation in nature whereas that of the fully reduced ones was doping. The latter took place in two steps: oxidation of benzene-diamine units into quinone-diimine units (redox between I2 and the polymer chain) and formation of a conjugated system consisting of four aromatic rings (intramolecular chain redox).