924 resultados para Gibbs energy of mixing
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By equilibrating condensed DNA arrays against reservoirs of known osmotic stress and examining them with several structural probes, it has been possible to achieve a detailed thermodynamic and structural characterization of the change between two distinct regions on the liquid-crystalline phase diagram: (i) a higher density hexagonally packed region with long-range bond orientational order in the plane perpendicular to the average molecular direction and (ii) a lower density cholesteric region with fluid-like positional order. X-ray scattering on highly ordered DNA arrays at high density and with the helical axis oriented parallel to the incoming beam showed a sixfold azimuthal modulation of the first-order diffraction peak that reflects the macroscopic bond-orientational order. Transition to the less-dense cholesteric phase through osmotically controlled swelling shows the loss of this bond orientational order, which had been expected from the change in optical birefringence patterns and which is consistent with a rapid onset of molecular positional disorder. This change in order was previously inferred from intermolecular force measurements and is now confirmed by 31P NMR. Controlled reversible swelling and compaction under osmotic stress, spanning a range of densities between approximately 120 mg/ml to approximately 600 mg/ml, allow measurement of the free-energy changes throughout each phase and at the phase transition, essential information for theories of liquid-crystalline states.
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"This paper takes a look at Beverly Rosen’s artistic work, providing an overview of the various periods and styles she explored, while introducing new details and expanding established interpretations of her work. It is an attempt at documenting Rosen’s many activities in addition to her personal art and professional development. Special attention is given to exhibitions and programming held at Rosen’s gallery, St. Charles on Wazee"
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Thesis t.-p. attached to the cover of the reprint from the Journal of the American chemical society, vol. XL, no. 3, March 1918, by Gilbert N. Lewis and Donald B. Keyes.
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"Serial no. 100-86."
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"Serial no. 100-47."
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"Serial no. 100-88."
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"Serial no. 100-89."
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"Serial no. 100-92."
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"Serial no. 100-87."
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"Serial no. 100-90."
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Mode of access: Internet.
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"Serial no. 97-QQ."
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"Serial no. 97-AAA."
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"Serial no. 97-I."
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"Serial no. 97-C."