Self-Structuring of Lamellar Bridged Silsesquioxanes with Long Side Spacers

Diurea cross-linked bridged silsesquioxanes (BSs) C(10)C(11)C(10) derived from organosilane precursors, including decylene chains as side spacers and alkylene chains with variable length as central spacers (EtO)(3)Si- (CH(2))(10)-Y(CH(2))(n)-Y-(CH(2))(10)-Si(OEt)(3) (n = 7, 9-12; Y = urea group and Et = ethyl), have been synthesized through the combination of self-directed assembly and an acid-catalyzed sol gel route involving the addition of dimethylsulfoxide (DMSO) and a large excess of water. This new family of hybrids has enabled us to conclude that the length of the side spacers plays a unique role in the structuring of alkylene-based BSs, although their morphology remains unaffected. All the samples adopt a lamellar structure. While the alkylene chains are totally disordered in the case of the C(10)C(7)C(10) sample, a variable proportion of all-trans and gauche conformers exists in the materials with longer central spacers. The highest degree of structuring occurs for n = 9. The inclusion of decylene instead of propylene chains as side spacers leads to the formation of a stronger hydrogen-bonded urea-urea array as evidenced by two dimensional correlation Fourier transform infrared spectroscopic analysis. The emission spectra and emission quantum yields of the C(10)C(n)C(10) Cm materials are similar to those reported for diurea cross-linked alkylene-based BSs incorporating propylene chains as side spacers and prepared under different experimental conditions. The emission of the C(10)C(n)C(10) hybrids is ascribed to the overlap of two distinct components that occur within the urea cross-linkages and within the siliceous nanodomains. Time-resolved photoluminescence spectroscopy has provided evidence that the average distance between the siliceous domains and the urea cross-links is similar in the C(10)C(n)C(10) BSs and in oxyethylene-based hybrid analogues incorporating propylene chains as side spacers (diureasils), an indication that the longer side chains in the former materials adopt gauche conformations. It has also allowed us to demonstrate for the first time that the emission features of the urea-related component of the emission of alkylene-based BSs depend critically on the length of the side spacers.

Influência da acurácia de instrumentos de medidas na comparação de métodos de estimativa da evapotranspiração de referência

The aim of this investigation was to evaluate four reference methods to estimate evapotranspiration (Makkink, Hargreaves, Class A pan and Radiation), compared tb Penman-Monteith method, that is considered standard by the Food and Agricultural Organization of the United Nations (FAO). Errors due to variable measurements in the reference evapotranspiration estimate were taken into consideration. The research was developed in an experimental area of the Department of Rural Engieering of the School of Agricultural and Veterinarian Sciences, Campus of Jaboticabal, São Paulo State University. An automated weather station was used and it was equipped with sensors to measure global and net radiation, temperature, relative humidity, and wind speed. The aftermath showed a better adjustment to Hargreaves. Makkink, Class A pan and Radiation methods are different from Penman-Monteith, therefore, they cannot be compared. To evaluate methods to estimate evapotranspiration and avoid possible evaluation errors, ETo estimate errors must be considered.

Avaliação de duas estações meteorológicas automatizadas, para estimativa diária da evapotranspiração de referência obtida pelo método de penman-monteith

The objective of this study was to evaluate and compare measurements and estimates from Davis and Campbell Scientific Instruments in two automatic weather stations. Integrity of meteorological data for estimates of evapotranspiration of reference crop (ETo) from both stations was also evaluated. The following meteorological data were evaluated: air temperature, air humidity, wind speed, precipitation, net radiation and global solar radiation. The Penman-Monteith reference method to estimate ETo was evaluated daily. The weather stations were set up in an experimental area of the Rural Engineering Department-FACV/ UNESP, in Jaboticabal, State of Sao Paulo. Data were collected daily and statistical analysis was performed using linear regression analysis. The integrity of meteorological data to estimate ETo was evaluated. The results of the study in the stations using linear regression analysis showed that daily estimates for ETo had acceptable differences. The technique which evaluates the integrity of meteorological data revealed that data of relative humidity from both stations and of precipitation using Campbell Instruments were not good.

Resposta produtiva do feijoeiro comum a diferentes manejos de irrigação

The objective of this work was to analyze the most appropriate management to achieve higher productivity for carioca beans (phaseolus vulgaris) and pearll cultivar. The research was developed in the Demonstrative and Experimental Area of Irrigation (ADEI) of FCAV/UNESP, Campus of Jaboticabal, SP. Four treatments were used: T1- irrigation with base in ETo estimated by the method of Class A pan; T2- irrigations based on the readings of tensiometers installed at 0,20 m and 0,40 m of depth; T3- irrigations carried out with base in ETo estimated by the method of Penman-Monteith and T4- witness. The results were submitted to analysis of variance. To compare the averages the test Turkey was used at 5% of probability. The treatment T3 had smaller applied water depth than the treatments T1 and T2, and also smaller productivity. The conclusion is that the treatments irrigated with larger frequency showed higher production of grains.

Hemoparasite and hematological parameters in Nile tilapia

The accelerated growth of finfish aquaculture has resulted in a series of health problems, including blood disorders by hemoparasites; there are scarce studies about these agents and their impact in actual intensive farming. The aim of this study was to identify and quantify the hemoparasites present in monocytes and erythrocytes in the blood of tilapia and their correlation with the hematological profile. Blood samples were collected from caudal vessels of 15 cage-reared Nile tilapia (Oreochromis niloticus), with 70 ± 10 g weight on average, from Itambaracá Municipality, Parana State, Brazil. The total red blood cells, mean corpuscular volume, hematocrit, total and differential white blood cells counts, and the number of thrombocytes were determined in blood smears stained with May-Grünwald-Giemsa-Wright and Quick Panoptic. The results showed the presence of pleomorphic cytoplasmic inclusions with corrugated appearance and basophilic staining, mainly in monocytes, suggesting Anaplasmataceae parasitemia and inclusions with the same morphological characteristics in erythrocytes of one Nile tilapia. The hematological analysis showed no significant difference (P < 0.05) between infected and not infected fish, and therefore, there was no correlation between parasitemia and hematological profile. These observations allow us to infer that the intracytoplasmic inclusions in monocytes and erythrocytes are compatible with the family Anaplasmataceae. There was no correlation between the blood profile and low level of parasitemia. © 2012 Springer-Verlag London.

Crescimento da grama bermudas sob diferentes lâminas de irrigação

The objective of the present study was to analyze the most appropriate water depth for maintaining a good quality of Bermudas Grass (Cynodon dactylon) for soccer fields while saving water and electrical resources. Four treatments were used: T1 - irrigated with a water depth of 50% of evapotranspiration (ETo), T2 - irrigated with a water depth of 75% of ETo, T3 - irrigated with a water depth of 100% of ETo and T4 - irrigated with a water depth of 150% of ETo, all treatments were irrigated daily. The reference ETo was obtained by the Penman-Monteith method. The study was conducted in an experimental area of the Instituto Federal de Educação, Ciência e Tecnologia do Triângulo Mineiro - Campus Uberaba, Uberaba, Minas Gerais, Brazil, from June to September 2010 and from January to March 2011. Three evaluations of the variables were performed during the experimental period. The samples were obtained with the help of a cylindrical extractor with 10 cm in diameter and 30 cm in height. In each sample height and dry organic matter (leaf, root and organic material) were analyzed. The experimental design was randomized block with four treatments in five blocks. No significant differences were observed for dry matter and height (roots and organic material). The best results were those for T4 which obtained the greatest height.

Análise de três métodos de estimativa da evapotranspiração de referência para a região de Pradópolis - SP

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Estimativa da radiação solar direta na incidência nas partições instantânea, horária e diária a partir da radiação solar global

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

A gestão de estoques em sistemas produtivos Engineering-To-Order e Make-To-Stock: estudo de casos em empresas do setor gráfico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Influência de manejo de irrigação sobre aspectos da ecofisiologia e produção da videira CV. Syrah

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Irrigação deficitária em videira de vinho cv. Syrah durante o período chuvoso no semiárido

Pós-graduação em Agronomia (Irrigação e Drenagem) - FCA

Produtividade da cultura do feijão (Phaseolus vulgaris L.) irrigada por aspersão convencional com diferentes métodos de estimativa de lâmina de irrigação

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Determinação da acurácia de instrumentos de medidas para obter a evapotranspiração de referência com erros fixados

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Irrigação no desenvolvimento da grama Bermudas

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Caracterização climática e comparação de métodos de estimativa de evapotranspiração de referência para regiões do Estado do Ceará

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)