Fükelman, Cristina. La cultura visual en el Río de la Plata, 1834-1852: innovaciones a partir de la configuración y de la función de la imagen política y costumbrista, La Plata, Archivo Histórico de la Provincia de Buenos Aires, 2013, 138 p.

Fil: Reitano, Emir. Universidad Nacional de La Plata. Facultad de Humanidades y Ciencias de la Educación. Instituto de Investigaciones en Humanidades y Ciencias Sociales (UNLP-CONICET); Argentina.

Late Neogene time scale for ODP Leg 138 sites

The sediments recovered during Leg 138 provide a remarkable opportunity to improve the geological time scale of the late Neogene. We have developed new time scales in the following steps. First, we constructed age models on the basis of shipboard magnetostratigraphy and biostratigraphy, using the time scale of Berggren, Kent, and Flynn (1985). Second, we refined these age models using shipboard GRAPE density measurements to provide more accurate correlation points. Third, we calibrated a time scale for the past 6 m.y. by matching the high-frequency GRAPE density variations to the orbital insolation record of Berger and Loutre (1991); we also took into account d18O records, where they were available. Fourth, we generated a new seafloor anomaly time scale using our astronomical calibration of C3A.n (t) at 5.875 Ma and an age of 9.639 Ma for C5n.1n (t) that is based on a new radiometric calibration (Baksi, 1992). Fifth, we recalibrated the records older than 6 Ma to this new scale. Finally, we reconsidered the 6- to 10-Ma interval and found that this could also be partially tuned astronomically.

Phosphorus partition and acumulation rates in sediments of ODP Legs 130 and 138

Understanding phosphorus (P) geochemistry and burial in oceanic sediments is important because of the role of P for modulating oceanic productivity on long timescales. We investigated P geochemistry in seven equatorial Pacific sites over the last 53 Ma, using a sequential extraction technique to elucidate sedimentary P composition and P diagenesis within the sediments. The dominant P-bearing component in these sediments is authigenic P (61-86% of total P), followed in order of relative dominance by iron-bound P (7-17%), organic P (3-12%), adsorbed P (2-9%), and detrital P (0-1%). Clear temporal trends in P component composition exist. Organic P decreases rapidly in younger sediments in the eastern Pacific (the only sites with high sample resolution in the younger intervals), from a mean concentration of 2.3 µmol P/g sediment in the 0-1 Ma interval to 0.4 µmol/g in the 5- 6 Ma interval. Over this same time interval, decreases are also observed for iron-bound P (from 2.1 to 1.1 µmol P/g) and adsorbed P (from 1.5 to 0.7 µmol P/g). These decreases are in contrast to increases in authigenic P (from 6.0-9.6 µmol P/g) and no significant changes in detrital P (0.1 µmol P/g) and total P (12 µmol P/g). These temporal trends in P geochemistry suggest that (1) organic matter, the principal shuttle of P to the seafloor, is regenerated in sediments and releases associated P to interstitial waters, (2) P associated with iron-rich oxyhydroxides is released to interstitial waters upon microbial iron reduction, (3) the decrease in adsorbed P with age and depth probably indicates a similar decrease in interstitial water P concentrations, and (4) carbonate fluorapatite (CFA), or another authigenic P-bearing phase, precipitates due to the release of P from organic matter and iron oxyhydroxides and becomes an increasingly significant P sink with age and depth. The reorganization of P between various sedimentary pools, and its eventual incorporation in CFA, has been recognized in a variety of continental margin environments, but this is the first time these processes have been revealed in deep-sea sediments. Phosphorus accumulation rate data from this study and others indicates that the global pre-anthropogenic input rate of P to the ocean (20x10**10 mol P/yr) is about a factor of four times higher than previously thought, supporting recent suggestions that the residence time of P in the oceans may be as short as 10000-20000 years.