Nanocrystalline titanium to mesoporous anatase with high bioactivity

In present study, the formation of bioactive anatase on bulk titanium (Ti) by hybrid surface mechanical attrition treatment (SMAT) is reported. A commercial pure Ti plate first underwent SMAT in a vacuum for 1 h to produce a nanocrystalline layer with a thickness of about 30 µm, and then the nanocrystalline Ti (30 nm) was transformed into mesoporous anatase with a grain size 10 nm by chemical oxidation and calcination. The mesoporous anatase showed excellent bioactivity while being soaked in simulated body fluid, which could be attributed to the unique nanostructure on the SMAT Ti surface.

Surface evolution of a gradient structured Ti in hydrogen peroxide solution

In this work, the interaction between hydrogen peroxide (H₂O₂) and a gradient structured Ti was investigated extensively. The gradient structured Ti (SMAT Ti) was produced by surface mechanical attrition treatment (SMAT), and then it was immersed in H₂O₂ solution for different time until 48 h at room temperature (25 °C). The structure and surface morphology evolution were examined by Raman spectra and scanning electron microscopy (SEM). The formation mechanism of nanoporous titania was discussed based on above results.

Design of secure watermarking scheme for watermarking protocol

Watermarking technique enables to hide an imperceptible watermark into a multimedia content for copyright protection. However, in most conventional watermarking schemes, the watermark is embedded solely by the seller, and both the seller and the buyer know the watermarked copy, which causes unsettled dispute at the phase of arbitration. To solve this problem, many watermarking protocols have been proposed using watermarking scheme in the encrypted domain. In this paper, we firstly discuss many security aspects in the encrypted domain, and then propose a new method of homomorphism conversion for probabilistic public key cryptosystem with homomorphic property. Based on our previous work, a new secure watermarking scheme for watermarking protocol is presented using a new embedding strategy in the encrypted domain. We employ an El Gamal variant cryptosystem with additive homomorphic property to reduce the computing overload of watermark embedding in the encrypted domain, and RA code to improve the robustness of the watermarked image against many moderate attacks after decryption. Security analysis and experiment demonstrate that the secure watermarking scheme is more suitable for implementing the existing watermarking protocols.

Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand

The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.