Thermodynamics of zinc insertion in CuGaS2:Ti, used as a modulator agent in an intermediate-band photovoltaic material

An intermediate-bandphotovoltaicmaterial, which has an isolated metallic band located between the top of the valence band and bottom of the conduction band of some semiconductors, has been proposed as third generation solar cell to be used in photovoltaic applications. Density functional theory calculations of Zn in CuGaS2:Ti have previously shown that, the intermediate-band position can be modulated in proportion of Zn insertion in such a way that increasing Zn concentration can lead to aband-gap reduction, and an adjustment of the intermediate-band position. This could be interesting in the formation of an intermediate-bandmaterial, that has the maximum efficiency theoretically predicted for the intermediate-band solar cell. In this work, the energetics of several reaction schemes that could lead to the decomposition of the modulated intermediate-bandphotovoltaicmaterial, CuGaS2:Ti:Zn, is studied in order to assess the thermodynamic stability of this material. Calculations of the total free energy and disorder entropy have been taken into account, to get the reaction energy and free energy of the compound decomposition, which is found to be thermodynamically favorable

Understanding the selective area growth of GaN nanocolumns by MBE using Ti nanomasks

The influence of the substrate temperature, III/V flux ratio, and mask geometry on the selective area growth of GaN nanocolumns is investigated. For a given set of growth conditions, the mask design (diameter and pitch of the nanoholes) is found to be crucial to achieve selective growth within the nanoholes. The local III/V flux ratio within these nanoholes is a key factor that can be tuned, either by modifying the growth conditions or the mask geometry. On the other hand, some specific growth conditions may lead to selective growth but not be suitable for subsequent vertical growth. With optimized conditions, ordered GaN nanocolumns can be grown with a wide variety of diameters. In this work, ordered GaN nanocolumns with diameter as small as 50 nm are shown.

Understanding the Selective Area Nucleation and Growth of GaN nanocolumns by MBE using Ti nanomasks

•Self- assembled Ga(In)N Nanorods and Nanostructures •Ordered growth of GaN Nanorods: masks issues •Ordered growth of GaN Nanorods: mechanisms •White NanoLEDs

Opus sermonum de aduentu / religiosissimi viri, artiu[m] ac sacre theologie in Parisien[si] academia quondam professoris, et euangelice doctrine co[n]cionatoris celebratissimi Ioannis Raulini ordinis Cluniacen[sis], dilige[n]ti quidem cura mendis o[mn]ibu

Raulin, Jean (O.S.B.), 1443-1514. Itinerarium paradisi religiosissimi patris artium ac sacre pagine p[ro]fessoris Parisien[sis] diuiniq[ue] verbi declamatoris facundissimi magistri Ioannis Raulin ordinis Cluniace[nsis], co[m]plecte[n]s sermones de Penit

Opus sermonum de aduentu / religiosissimi viri, artiu[m] ac sacre theologie in Parisien[si] academia quondam professoris, et euangelice doctrine co[n]cionatoris celebratissimi Ioannis Raulini ordinis Cluniacen[sis], dilige[n]ti quidem cura mendis o[mn]ibu

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