Characterisation of ion transport in sulfonate based ionomer systems containing lithium and quaternary ammonium cations

Two sulfonated ionomers based on poly(triethylmethyl ammonium 2-acrylamido-2-methyl-1-propane sulfonic acid) (PAMPS) and containing mixtures of Li⁺ and quaternary ammonium cations are characterised. The first system contains Li⁺ and the methyltriethyl ammonium cation (N1222) in a 1:9 molar ratio, and the ⁷Li NMR line widths showed that the Li⁺ ions are mobile in this system below the glass transition temperature (105°C) and are therefore decoupled from the polymer segmental motion. The conductivity in this system was measured as 10^-5 Scm^-1 at 130°C. A second PAMPS system containing Li⁺ and the dimethylbutylmethoxyethyl ammonium cation (N114(2O1)) in a 2:8 molar ratio showed much lower conductivities despite a significantly lower Tg (60°C), possibly due to associations between the Li⁺ and the ether group on the ammonium cation, or between the latter cations and the sulfonate groups.

A demandeur-centric theory of regime design in transnational commercial law

Recent scholarship on international agreement design has almost exclusively focused on the public international law area. The literature on regime design in the area of international private law lacks a solid theoretical foundation. Academic writing on public international law's state-centric approach is only amenable to crude transplantation and poses several puzzles in the international private law context. Resolving these puzzles is important because of the proliferation of transnational commercial agreements in areas that were traditionally the province of domestic law. This paper attempts to provide a starting point to address the theoretical vacuum. Part I argues that functionalist, liberal, and realist theories cannot fully explain transnational commercial law agreement design. Part II puts forth a demandeur-centric approach with the aid of examples that span the spectrum from hard law to soft law. Part III concludes that agreement design in transnational commercial law is premised on demandeur preferences and relative power.

Towards a theory of landscape iconoclasm

The destruction of Indigenous rock art sites in the Pilbara district in Western Australia has become a natural sight within the mining landscape of the area. Whilst much of the destruction is explained as acts of vandalism and as a result of the industrial activities that are propelling the Australian economy, I claim that a new theory of iconoclasm is needed to explain fully this disastrous example of heritage conservation. Henceforth, in order to explain the destruction of the Murujuga/Burrup Peninsula petroglyphs, the largest archaeological site in the world, this paper develops the theory of landscape iconoclasm. This theory states that the destruction of Indigenous landscapes can be compared to the destruction of religious images, by analysing the inherent symbolic functions of iconoclasm, together with those of heritage, the better to elucidate the state of affairs in the Murujuga/Burrup Peninsula. Furthermore, by drawing from Aboriginal mythology and art-historical and anthropological theories, the theory of landscape iconoclasm is able to explain the destruction of archaeological sites within a framework that falls outside prevalent discourses of heritage.

Individual differences in intention to fake job interviews: Personality, self-monitoring, and the theory of planned behaviour

When job applicants lie in job interviews, they can deprive a more honest candidate of a job and deprive an organisation of the best employees. To better understand job interview faking, the present study examined the effect of general dispositions and domain-specific beliefs on the intention to fake job interviews. A community sample of 313 participants completed measures of personality (i.e., extraversion, neuroticism, conscientiousness) and self-monitoring, and a domain-specific measure of beliefs about faking job interviews based on the theory of planned behaviour, which measured attitudes, subjective norms, and perceived behavioural control. Results indicated that the measure of attitudes was the strongest predictor of intention to fake. In line with the compatibility principle, the domain-specific measures based on the theory of planned behaviour correlated much more strongly with intentions to fake job interviews than did the general measures of personality or self-monitoring. Of the dispositional measures, lower conscientiousness, higher neuroticism, and higher self-monitoring was associated with greater intention to fake job interviews. The findings support a model whereby the effect of personality on intentions is partially mediated by domain-specific beliefs.

Numerical Simulation Of Sediment Transport And Bedmorphology Around A Hydraulic Structure On A River

Scour around hydraulic structures is a critical problem in hydraulic engineering. Under prediction of scour depth may lead to costly failures of the structure, while over prediction might result in unnecessary costs. Unfortunately, up-to-date empirical scour prediction formulas are based on laboratory experiments that are not always able to reproduce field conditions due to complicated geometry of rivers and temporal and spatial scales of a physical model. However, computational fluid dynamics (CFD) tools can perform using real field dimensions and operating conditions to predict sediment scour around hydraulic structures. In Korea, after completing the Four Major Rivers Restoration Project, several new weirs have been built across Han, Nakdong, Geum and Yeongsan Rivers. Consequently, sediment deposition and bed erosion around such structures have became a major issue in these four rivers. In this study, an application of an open source CFD software package, the TELEMAC-MASCARET, to simulate sediment transport and bed morphology around Gangjeong weir, which is the largest multipurpose weir built on Nakdong River. A real bathymetry of the river and a geometry of the weir have been implemented into the numerical model. The numerical simulation is carried out with a real hydrograph at the upstream boundary. The bedmorphology obtained from the numerical results has been validated against field observation data, and a maximum of simulated scour depth is compared with the results obtained by empirical formulas of Hoffmans. Agreement between numerical computations, observed data and empirical formulas is judged to be satisfactory on all major comparisons. The outcome of this study does not only point out the locations where deposition and erosion might take place depending on the weir gate operation, but also analyzes the mechanism of formation and evolution of scour holes after the weir gates.