Carbon and carbonate analyses of DSDP Leg 27 samples

Leg 27 sediments were analyzed for total carbon and acid-insoluble (organic) carbon using a LECO acid-base Analyzer. The 3-cc sediment samples were first dried at 105°-110°C and then ground to a homogeneous powder. The ground sediment was redried and two samples, a 0.1-g and a 0.5-g sample, were then weighed into LECO clay crucibles. The 0.5-g sample was acidified with diluted hydrochloric acid and washed with distilled water. The sample was then dried and analyzed for acid-insoluble carbon, listed in the table as "organic" carbon. The 0.1-g sample was analyzed for total carbon without further treatment. If the result showed less than 10% CaCO3, an additional 0.5-g sample was analyzed for greater accuracy. The calcium carbon percentages were calculated as follows: (% total C-% organic C) * 8.33 = % CaCO3. Although other carbonates may be present, all acid-soluble carbon was calculated as calcium carbonate. All results are given in weight percent.

Multi-proxy analyses of sediment cores from the Pakistan continental margin

Late Holocene laminated sediments from a core transect centred in the oxygen minimum zone (OMZ) impinging at the continental slope off Pakistan indicate stable oxygen minimum conditions for the past 7000 calendar years. High SW-monsoon-controlled biological productivity and enhanced organic matter preservation during this period is reflected in high contents of total organic carbon (TOC) and redox-sensitive elements (Ni, V), as well as by a low-diversity, high-abundance benthic foraminiferal Buliminacea association and high abundance of the planktonic species Globigerina bulloides indicative of upwelling conditions. Surface-water productivity was strongest during SW monsoon maxima. Stable OMZ conditions (reflected by laminated sediments) were found also during warm interstadial events (Preboreal, Bølling-Allerød, and Dansgaard-Oeschger events), as well as during peak glacial times (17-22.5 ka, all ages in calendar years). Sediment mass accumulation rates were at a maximum during the Preboreal and Younger Dryas periods due to strong riverine input and mobilisation of fine-grained sediment coinciding with rapid deglacial sea-level rise, whereas eolian input generally decreased from glacial to interglacial times. In contrast, the occurrence of bioturbated intervals from 7 to 10.5 ka (early Holocene), in the Younger Dryas (11.7-13 ka), from 15 to 17 ka (Heinrich event 1) and from 22.5 to 25 ka (Heinrich event 2) suggests completely different conditions of oxygen-rich bottom waters, extremely low mass and organic carbon accumulation rates, a high-diversity benthic fauna, all indicating lowered surface-water productivity. During these intervals the OMZ was very poorly developed or absent and a sharp fall of the aragonite compensation depth favoured the preservation of pteropods. The abundance of lithogenic proxies suggests aridity and wind transport by northwesterly or northeasterly winds during these periods coinciding with the North Atlantic Heinrich events and dust peaks in the Tibetan Loess records. The correlation of the monsoon-driven OMZ variability in the Arabian Sea with the rapid climatic fluctuations in the high northern latitudes suggests a close coupling between the climates of the high and low latitudes at a global scale.