Electrical conductivity and glass formation in nitrile-functionalized pyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids: chain length and odd–even effects of the alkyl spacer between the pyrrolidinium ring and the nitrile group

The electrical conductivity of a series of pyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids, functionalized with a nitrile (cyano) group at the end of an alkyl chain attached to the cation, was studied in the temperature range between 173 K and 393 K. The glass formation of the ionic liquids is influenced by the length of the alkyl spacer separating the nitrile function from the pyrrolidinium ring. The electrical conductivity and the viscosity do not show a monotonic dependence on the alkyl spacer length, but rather an odd-even effect. An explanation for this behavior is given, including the potential energy landscape picture for the glass transition.

Polyport. Cultivating Callao

A group of six Queen’s year out students, led by Dr Agustina Martire, worked in the international collaborative project POLYPORT organised by RIBA. Polyport involved 14 schools of architecture in the UK and abroad with the aim of to bringing back the spirit of Cedric Price’s Polyark in the 1970s. We worked on a brief provided by University of Lima for the harbour of Callao as a project for the regeneration of deprived areas. The students worked on a very thorough analysis of the site and were in close communication with students in Lima.
The results of the project were presented in Roma Tre University, with all the other schools involved. All presentations showed a very committed and engaged position towards the sites and very innovative ways of designing and making architecture.