998 resultados para CARBON-MINERAL ADSORBENTS


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Os sistemas de manejo do solo modificam a dinâmica do fósforo alterando o conteúdo das diferentes formas de P. Objetivou-se avaliar o efeito de sistemas de cultivo em longo prazo (16 anos de plantio) sobre as diferentes formas de P no solo. Os tratamentos constaram de combinações entre dois sistemas de cultivo: milho exclusivo (M) e milho consorciado com feijão (MF), com duas doses (0 e 40 m³ ha-1 ano-1) de adubo orgânico (AO), e três doses (0, 250 e 500 kg ha-1) de N-P-K, 4-14-8 (AM). Solo sob um fragmento de Floresta Atlântica foi utilizado como referência de um estado em equilíbrio. Os valores de P orgânico total (Pot) variaram de 184,2 a 280,2 e de 147,9 a 282,9 mg kg-1, em amostras de solo das camadas de 0-10 e 10-20 cm, respectivamente, sendo os maiores valores observados para combinação 500 kg ha-1 + adubação orgânica, correspondendo, em média, a 26,4 % do P total no solo. Houve tendência da relação C/Pot manter-se constante, entre os tratamentos, constatando-se aumento dos valores de Pot com o aumento do teor de carbono orgânico total no solo. O adubo mineral promoveu incremento do P na biomassa microbiana (Pbm) apenas no sistema de milho exclusivo. Em média, o aumento do Pbm foi de 262 e 164 % para o sistema que recebeu o composto orgânico no sistema de milho exclusivo e consorciado com feijão, respectivamente. Em média, a fração de P orgânico solúvel em meio ácido correspondeu a 90 % do Pot predominando sobre a fração solúvel em base. Nos tratamentos com 500 kg ha-1 de 4-14-8 e 500 kg ha-1 + composto orgânico, no sistema de consórcio, foram obtidos aumentos nos valores de P total lábil de 53 e 157 %, respectivamente, comparados aos da testemunha. O P orgânico lábil (Pol) correspondeu, em média, a 3,7 % do Pot para os sistemas de cultivo, já para a Floresta Atlântica, esta relação foi de 10,7 %, nas duas profundidades. Os aumentos nos teores das formas mais lábeis de P, proporcionados pela adubação orgânica, evidenciam a importância deste sistema de manejo no favorecimento da ciclagem de P.

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Carbon isotope ratios in marine carbonate rocks have been shown to shift at some of the time boundaries associated with extinction events; for example, Cretaceous/Tertiary and Ordovician/ Silurian. The Permian/Triassic boundary, the greatest extinction event of the Phanerozoic, is also marked by a large d13C depletion. New carbon isotope results from sections in the southern Alps show that this depletion did not actually represent a single event, but was a complex change that spanned perhaps a million years during the late Permian and early Triassic. These results suggest that the Permian/Triassic (P/Tr) extinction may have been in part gradual and in part 'stepwise', but was not in any case a single catastrophic event.

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Este trabalho teve como objetivo avaliar os efeitos das lâminas brutas de irrigação na concentração de nutrientes de mudas de Eucalyptus grandis, produzidas em diferentes substratos. O experimento foi realizado na Camará - Mudas Florestais, em Ibaté, SP, e constituiu-se de um fatorial 5 x 4, sendo cinco lâminas brutas de irrigação diárias (6, 8, 10, 12 e 14 mm), aplicadas em diferentes horários (10, 13 e 16 h), e quatro substratos (FB - fibra de coco; CPV - casca de pinus e vermiculita; CATV - casca de pinus, carvão, turfa e vermiculita; e um MIX - 70 % de CPV e 30 % de FB). Foram determinadas os conteúdos dos nutrientes na parte aérea e no sistema radicular das mudas. Os resultados indicaram que houve influência das lâminas de irrigação e dos substratos no conteúdo dos nutrientes das mudas com maior acúmulo dos mesmos à medida que o fornecimento de água foi maior. As plantas crescidas nos substratos FB e CPV registraram os maiores acúmulos de nutrientes. CPV foi o melhor em se tratando do acúmulo dos macronutrientes nas raízes e também, juntamente com FB, o melhor para o acúmulo dos micronutrientes nas raízes e na parte aérea. Não houve influência dos substratos no acúmulo dos macronutrientes na parte aérea, porém houve das lâminas de irrigação.

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Dos métodos de preparo conservacionista do solo, o de semeadura direta é o mais eficaz na redução da perda de solo por erosão hídrica pluvial; entretanto, apresenta comportamento variável no que diz respeito à redução da perda de água. Considerando esses aspectos, realizou-se o presente trabalho com o objetivo de avaliar as perdas de solo e água, a demanda química de oxigênio, a condutividade elétrica e o pH da enxurrada, associados à erosão entre sulcos, sob chuva simulada, em área cultivada sob semeadura direta e submetida às adubações mineral e orgânica. O estudo foi desenvolvido em campo, em outubro de 2003, no município de Marechal Cândido Rondon, na região oeste do Estado do Paraná, sobre um Latossolo Vermelho eutroférrico de textura muito argilosa e declividade de 0,045 m m-1. Utilizando microparcelas (1,0 x 1,0 m) e simulador de chuva de braços rotativos e com o solo previamente umedecido, aplicaram-se as seguintes intensidades de chuva: 70,0, 60,0 e 120,0 mm h-1, cada uma delas com duração de 20 min e espaçadas uma da outra de 30 min. Os tratamentos estudados foram: (a) adubação mineral, constituída de NPK; (b) adubação orgânica, constituída de dejeto líquido de suíno _ DLS; e (c) sem adubação ou testemunha - T. As maiores perdas de solo e água no experimento foram observadas no tratamento DLS, independentemente das chuvas simuladas (exceto a perda de solo na última chuva, que foi a mais elevada), com os tratamentos NPK e T tendo apresentado resultados semelhantes. Os valores mais elevados de demanda química de oxigênio, condutividade elétrica e pH da enxurrada também foram observados no tratamento DLS, enquanto os mais baixos ocorreram no tratamento T (exceto a demanda química de oxigênio no tratamento NPK, que também foi baixa), independentemente das chuvas simuladas.

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Abstract:During my doctoral research, I focused on deciphering the interactions between sea-level and climate change during the Late Barremian-Early Aptian, their expression in the Tethys basin and in the Helvetic carbonate platform. The research highlights are summarized here in three points: In the Helvetic Alps, the transition between the Lower Schrattenkalk (Upper Barremian) and the Rawil Member (Lowermost Aptian) is characterized by a change from a predominantly photozoan to a heterozoan carbonate-producing system, which coincides in time with a general increase in detrital and nutrient input. The clay mineral record shows the appearance of kaolinite within the Rawil Member, whereas this mineral is absent from the uppermost Lower and lowermost Upper Schrattenkalk Members. This indicates the installation of a warmer and more humid climate during this time period. A negative peak in 513C is recorded at the top of the Lower Schrattenkalk Member, and correlates with the well-known negative excursion of -l%o occurring in other basins and dated as latest Barremian, thus confirming a latest Barremian and earliest Aptian age for the Lower Schrattenkalk and Rawil Members, respectively. Furthermore, a sequence stratigraphie framework has been defined for the Rawil Member, based on both the ecology of faunal and floral assemblages, and their palaeoenvironmental interpretation, as well as on the stacking pattern of limestone beds observed during field prospection. The presence of a sequence boundary is postulated near the top of the Lower Schrattenkalk Member, which is correlated with the earliest Aptian SbAl defined in Vercors (France). The SbAl is characterized by a maximum of proximal assemblages and by the disappearance of several benthic foraminiferal species. Within the Rawil Member itself, the stacking pattern and microfacies trends are interpreted to represent the TST of the first Aptian sequence. With regards to the pelagic setting in the Tethyan realm, I investigated the Gorgo a Cerbara section (central Italy). There, thin organic-rich layers occur episodically in pelagic carbonates of the upper Barremian portion of the Maiolica Formation. They are associated with high Corg:Ptot ratios, which indicate the presence of intermittent dysoxic to anoxic conditions. Coarse correlations are also observed between TOC, Ρ and biogenic silica contents, indicating links between Ρ availability, productivity, and organic matter preservation. The corresponding 813Ccarb and δ180 records remain, however, quite stable, indicating that these brief periods of enhanced TOC preservation did not have sufficient impact on the marine carbon household to deviate 6,3C records, and are probably not the consequence of major climate change. On the other hand, organic-rich layers become more frequent around the Barremian-Aptian boundary in both pelagic and hemi-pelagic environments (Gorgo a Cerbara and La Bédoule, France), which are correlated with negative excursions in 6l3Ccarb and 613Corg records. During the earliest Aptian, at Gorgo a Cerbara, the frequency of organic-rich intervals progressively increases and redox-sensitive trace-element enrichments become more frequent, until the highest TOC-enriched level just below the "Livello Selli", indicator of Oceanic Anoxic Event la (OAEla). The latter is associated with the well-known negative spike in 613Ccarb and S,3Corg records, a diminution in the δ,80 record interpreted as the consequence of a wanning interval, an important peak in Ρ accumulation and high Cor::Ptot ratios indicating the prevalence of anoxic conditions. The Selli Level (OAEla) documents a general cooling phase and coincides with maximum RSTE enrichments as well as high Corg:Ptot ratios, which confirm the importance of anoxic conditions during OAE1 a at this site.During the Early Aptian, environmental change on the platform is expressed by orbitolinids proliferation that may be induced by both climate change and sea-level rise. In the basin, the successive black shales horizons from the Late Barremian until the OAE la are interpreted as the progressive impact of palaeoenvironmental change probably linked to the formation of the Ontong- Java plate-basalt plateau.RésuméCe travail de thèse a permis d'investiguer les interactions entre les variations du niveau marin et les changements climatiques sur la plate-forme helvétique ainsi qu'en domaine pélagique à la limite Barrémien-Aptien (Crétacé).Dans les Alpes helvétiques, la limite Barrémien-Aptien est marquée par la transition du Schrattenkalk inférieur, caractérisé par des carbonates photozaires, au Membre de Rawil caractérisé par des carbonates héterozoaires. Cette transition est marquée par une arrivée massive d'éléments détritiques et un apport de nutriments ayant entraîné la prolifération de foraminifères agglutinés tels que les orbitolines. L'analyse des minéraux argileux indique l'apparition de la kaolinite durant le Membre de Rawil, interprétée comme l'installation d'un climat plus chaud et humide. Un pic négatif en 513C est enregistré au sommet du Schrattenkalk inférieur correspond à l'excursion négative de -1%0 bien connue en domaine pélagique et datée comme Barrémien terminal. Cette corrélation apporte un contrôle chronostratigraphique supplémentaire permettant de dater le Schrattenkalk inférieur du Barrémien sup. et le Membre de Rawil de l'Aptien inf. D'autre part, une étude stratigraphique, basée sur des observations de terrain et sur l'interprétation d'assemblages floristiques et faunistiques en terme de paléoenvironnement a permis de mettre en évidence une limite de séquence au sommet du Schrattenkalk inf., corrélable avec la SbAl définie dans le Vercors. Durant la mise en place du Membre de Rawil, l'évolution des microfaciès est interprétée comme le « Transgressive System Tract » de la première séquence aptienne.En domaine pélagique, de minces couches riches en matière organique (MO) apparaissent dès le Barrémien sup. dans la coupe de Gorgo a Cerbara (Italie). Elles sont associées à un ratio C:P élevé indiquant des conditions épisodiquement dysoxiques à anoxiques. De plus, une corrélation nette entre Carbone Organique Total (TOC), phosphore (P) et silice biogénique est observée correspondant à un lien entre Ρ disponible, productivité et préservation de la MO. Pourtant, dans le même temps, le ÔI3C et le δ1βΟ restent constants indiquant des conditions environnementales stables et un cycle du carbone non perturbé par la préservation de MO qui ne serait pas la conséquence d'un changement climatique global mais juste d'un effet local.Ala limite Barrémien-Aptien, en domaine hémi-pélagique (La Bédoule, France) et pélagique (Gorgo a Cerbara), les couches riches en MO sont plus fréquentes et plus épaisses, elles se sont déposées en même temps qu'un pic négatif en 513CCARB et ô13Coib probablement dû à un épisode volcanique. A l'Aptien inf. le TOC des niveaux riches en MO augmente progressivement en même temps que la teneur en éléments traces jusqu'au dernier enrichissement avant l'événement anoxique océanique la (OAE la) correspondant au « niveau critique inf. », indiquant des conditions anoxiques moins restreintes. Celui-ci est également caractérisé par le fameux pic négatif en Ô13C (C3), une diminution du δ180 interprétée comme un réchauffement, par un pic en Ρ et un ratio C:P élevé. L'OAE 1 a, quant à lui, enregistre un refroidissement et coïncide avec le maximum en éléments traces ainsi qu'un fort ratio C:P mettant en valeur l'importance des conditions anoxiques pendant 1ΌΑΕ la dans cette coupe alors qu'aucune perturbation n'est enregistrés à La Bédoule probablement à cause de conditions paléogéographiques locales.Durant l'Aptien inf., les changements environnementaux sur la plate-forme se marquent par la prolifération d'orbitolines due à un changement climatique et une hausse du niveau marin. En domaine profond, la succession de niveaux riches en MO du Barrémien sup. jusqu'à l'OAE la documente l'impact progressif de changements paléoenvironnementaux, probablement liés à la formation du plateau d'Ontong Java à l'ouest de l'océan Pacifique.

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The trabecular bone score (TBS) is a new parameter that is determined from gray-level analysis of dual-energy X-ray absorptiometry (DXA) images. It relies on the mean thickness and volume fraction of trabecular bone microarchitecture. This was a preliminary case-control study to evaluate the potential diagnostic value of TBS as a complement to bone mineral density (BMD), by comparing postmenopausal women with and without fractures. The sample consisted of 45 women with osteoporotic fractures (5 hip fractures, 20 vertebral fractures, and 20 other types of fracture) and 155 women without a fracture. Stratification was performed, taking into account each type of fracture (except hip), and women with and without fractures were matched for age and spine BMD. BMD and TBS were measured at the total spine. TBS measured at the total spine revealed a significant difference between the fracture and age- and spine BMD-matched nonfracture group, when considering all types of fractures and vertebral fractures. In these cases, the diagnostic value of the combination of BMD and TBS likely will be higher compared with that of BMD alone. TBS, as evaluated from standard DXA scans directly, potentially complements BMD in the detection of osteoporotic fractures. Prospective studies are necessary to fully evaluate the potential role of TBS as a complementary risk factor for fracture.

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In spite of the normally low content of organic matter found in sandy soils, it is responsible for almost the totality of cation exchange capacity (CEC), water storage and availability of plant nutrients. It is therefore important to evaluate the impact of alternative forest exploitation on the improvement of soil C and N accumulation on these soils. This study compared pure and mixed plantations of Eucalyptus grandis and Pseudosamanea guachapele, a N2-fixing leguminous tree, in relation to their effects on soil C and N stocks. The studied Planosol area had formerly been covered by Panicum maximum pasture for at least ten years without any fertilizer addition. To estimate C and N contents, the soil was sampled (at depths of 0-2.5; 2.5-5.0; 5.0-7.5; 7.5-10.0; 10.0-20.0 and 20.0-40.0 cm), in pure and mixed five-year-old tree plantations, as well as on adjacent pasture. The natural abundance 13C technique was used to estimate the contribution of the soil organic C originated from the trees in the 0-10 cm soil layer. Soil C and N stocks under mixed plantation were 23.83 and 1.74 Mg ha-1, respectively. Under guachapele, eucalyptus and pasture areas C stocks were 14.20, 17.19 and 24.24 Mg ha-1, respectively. For these same treatments, total N contents were 0.83; 0.99 and 1.71 Mg ha-1, respectively. Up to 40 % of the soil organic C in the mixed plantation was estimated to be derived from trees, while in pure eucalyptus and guachapele plantations these same estimates were only 19 and 27 %, respectively. Our results revealed the benefits of intercropped leguminous trees in eucalyptus plantations on soil C and N stocks.