Poluentes orgânicos persistentes em ar interior: desenvolvimento de método de extração em adsorvente para amostragem ativa

Persistent Organic Pollutants (POPs) are chemical substances extraordinarily toxic and persistent in the environment. Due to these properties, POPs are targets of the Stockholm Convention which aims to provide means to eliminate production and use by encouraging the reduction and, where possible, eliminating the release of these contaminants to the environment. One of the articles of this _Convention aims to assess the basal levels of such substances in the environment to monitor both the reduction of release to the environment, and to assess human exposure, using analyzes of milk and air for example. Although efforts to control POPs production and release to the environment have been made, data about their levels in Brazil are still scarce, mainly in the atmosphere or indoor environment. Considering the permanence of people inside its house, this study presents a method for POP extraction from XAD-2 sorbent employed in indoor air sampling, with identification and quantification by GC-ECD. GC-ECD linear range of the studied analytes, congeners of polychlorinated biphenyls (PCB) (28, 52, 101, 118, 138, 153 and 180), DDTs and their metabolites (DDDs, DDEs) and endosullan (isomers c - and 13 - and metabolite endosulfan sulfate) ranged between 0.5 and 16.0 ng mL-I with r2 > 0.967. The method developing consist of selecting the extraction solvent system by agitation (90 rpm, 1 hour) with n-hexan,e (2 mL) or n-hexane:acetone (1:1, v/v) (2 mL), concentration the extract with a gentle N2 stream, and evaluation of breakthrough with passage or air through the fortified XAD-2 cartridge before extraction, employing a low volume air suction pump (Pump Model 224 universal-PCXR8; 5-5000 mL min-1, SKC Inc., Eighty Four, PA, USA), Calibrator Dry-Cal DC-Lite (BIOS, Butler, NJ, USA)). Two fortification levels were employed, 15 and 30 ng. After selecting n-hexane as extraction solvent, with accuracy and precision ranging...

Análise hormonal, imunolocalização e quantificação dos receptores de andrógenos (AR) e estrógenos (ER-α E ER-β) em ovário e útero de ratas submetidas a diferentes doses de decanoato de nandrolona: avaliação nos períodos pós-tratamento e pós-recuperação

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo hidrodinâmico quali-quantitativo de uma unidade de flotação por ar dissolvido (FAD): o efeito do dispositivo de coleta de água flotada

The main article aim was to investigate the collecting system of a dissolved air flotation (DAF) unit in pilot scale. Referring to the collecting system position, two options were analyzed: (i) top manifold and (ii) bottom manifold, pipes or plates. Qualitative and quantitative essays were performed, as image and stimulusresponse tests, respectively. The results of the essays standardized were adjusted by N-continuous stirred tank reactors in series and theoretical models of dispersion (low and high). The bottom manifold (plates with orifices) was more appropriate. The results pointed out that the N-continuous stirred tank reactors in series model was more adequate to describe the hydrodynamic behavior of the DAF unit.

Variabilidade espacial da umidade relativa do ar no interior de uma casa de vegetação em clima tropical

Greenhouse with natural ventilation is widely used in tropical countries, and little knowledge is available about how this type of structure affects the spatial variability of agroclimatic variables. The aim of this study was to analyse the spatial variability of relative humidity inside a greenhouse with natural ventilation. The measurement of relative humidity was done at 114 points inside the greenhouse at 9, 12 and 16 hours and on heights of 0.3, 1.2 and 2.0 m. The acquired data were processed by the geostatistical software GS+ and maps were generated and displayed for each time and height using the Surfer 10.3.705 software. The results showed that there were variations in the spatial distribution of relative humidity inside the greenhouse.

Desempenho de pontas de pulverização quanto a indução de ar nas gotas

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Influência de adjuvantes no espectro de gotas de ponta com indução de ar

This study aimed to verify the influence of adjuvants on the droplet spectrum of an air induction nozzle. The experiment used nine spray solutions, one including only water and eight containing adjuvants: Nimbus® (mineral oil), Óleo vegetal Nortox (vegetal oil), Li-700® (a mixture of lecithin and propionic acid), Agral® (nonyl phenoxy poly ethanol), In-Tec® (nonyl phenol ethoxylate), Antideriva (nonyl phenol ethoxylate), Silwet® L-77 Ag (copolymer polyester and silicon) and TA 35 (sodium lauryl ether sulfate). A flat fan air induction nozzle Hypro® Guardian Air 110 03 was used for the droplet spectrum evaluation. The study was conducted at the Laboratory for Particle Size Analysis (Lapar), at FCAV/UNESP, Jaboticabal/SP - Brazil. The determination of the droplet spectrum characteristics (Volume Median Diameter/VMD, percentage of droplets smaller than 100 micrometers and span) was carried out by a particle size analyzer by laser diffraction Mastersizer S (Malvern Instruments). For statistical analysis the mean values were compared using Confidence Interval at 95% (CI 95%). The results showed that for the Hypro® GA air induction nozzle the oil based adjuvants (Óleo Vegetal Nortox e Nimbus®) increased the VMD. The percentage of droplets smaller than 100 micrometers was lower for the Agral®, Antideriva, In-Tec® e TA 35, in comparison with the Óleo Vegetal Nortox and Li-700®. The span was higher for the oil based adjuvants (Óleo Vegetal Nortox e Nimbus®) and lower for the TA 35 (sodium lauryl ether sulfate), showing that the TA 35 adjuvant has a potential to improve the quality of the droplet spectrum of the Hypro® GA 11003 nozzle.

As características da temperatura do ar em bairros com produção do espaço urbano distintas: uma análise do Parque Higienópolis e Jd. Morada do Sol em Presidente Prudente-SP

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Modelagem e simulação de ciclos a gás com resfriamento de ar na entrada

The optimization of energy generation systems has become a key issue for technological and social development, mainly in developing countries, where the electricity consumption rises sharply. Gas turbine cycle is an electricity generating system, which studies have demonstrated that inlet air cooling increases net power and thermal efficiency. Thus, this study intends to quantify these parameters for environments with different ambient temperature and relative humidity. Two types of air cooling were used: evaporative and absorption systems. The configuration parameters only with the gas turbine cycle were compared to those whose configuration allowed cooling. First, it was analyzed only evaporative cooling. Next, the absorption system was used for analysis. The last configuration mixed these two methods, dividing equally its flow. The results showed that thermal efficiency and net power increase in any case of cooling, with absorption system more advantageous in terms of generated energy, where an increase between 1 and 2 MW was observed, depending on the ambient conditions . When the two methods were working together at low relative humidity, it showed a thermal efficiency increase compared to absorption system, up to 2.4%. Evaporative cooling was less effective, but it is a good and cheap possibility to increase the cycle parameters at high temperature and low relative humidity

As características da temperatura do ar em bairros com produção do espaço urbano distintas: uma análise do Parque Higienópolis e Jd. Morada do Sol em Presidente Prudente-SP

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Modelagem e simulação de ciclos a gás com resfriamento de ar na entrada

The optimization of energy generation systems has become a key issue for technological and social development, mainly in developing countries, where the electricity consumption rises sharply. Gas turbine cycle is an electricity generating system, which studies have demonstrated that inlet air cooling increases net power and thermal efficiency. Thus, this study intends to quantify these parameters for environments with different ambient temperature and relative humidity. Two types of air cooling were used: evaporative and absorption systems. The configuration parameters only with the gas turbine cycle were compared to those whose configuration allowed cooling. First, it was analyzed only evaporative cooling. Next, the absorption system was used for analysis. The last configuration mixed these two methods, dividing equally its flow. The results showed that thermal efficiency and net power increase in any case of cooling, with absorption system more advantageous in terms of generated energy, where an increase between 1 and 2 MW was observed, depending on the ambient conditions . When the two methods were working together at low relative humidity, it showed a thermal efficiency increase compared to absorption system, up to 2.4%. Evaporative cooling was less effective, but it is a good and cheap possibility to increase the cycle parameters at high temperature and low relative humidity