Controlled synthesis of TiO2 hierarchical nanofibre structures via electrospinning and solvothermal processes : photocatalytic activity for degradation of methylene blue

The present article describes a new titanium oxide‐based (TiO2) photocatalyst that shows promise for acceleration of dye degradation. A hierarchical TiO2 nanostructure comprising nanorods on‐nanofibres has been prepared using a sol–gel route and electrospinning. Calcination of electrospun nanobre mats was performed in air at 500 °C. The TiO2 nanofibre surface was then exploited as a ‘seeding ground’ to grow TiO2 nanorods by a solvothermal process in NaOH. The nanofibres had a diameter of approximately 100 nm while the nanorods were evenly distributed on the nanofibre surface with a mean diameter of around 50–80 nm. The hierarchical nanostructure showed enhanced photocatalytic activity when compared to pure TiO2 nanofibres. This improved efficiency in degrading methylene blue through the photocatalytic process was attributed to the larger specific surface area of the TiO2 nanostructures, as well as high surface‐to‐volume ratio and higher reactive surface resulting in enhanced surface adsorption and interfacial redox reaction.

Photo

A print commissioned as part of the Australian Print Workshops annual project including 164 artists, to be part of the permanent collection at the National Gallery of Australia.

Photocatalytic degradation of phenanthrene on soil surfaces in the presence of nanometer anatase TiO2 under UV-light

The effect of nanometer anatase TiO2 was investigated on the photocatalytic degradation of phenanthrene on soil surfaces under a variety of conditions. After being spiked with phenanthrene, soil samples loaded with different amounts of TiO2 (0 wt.%, 1 wt.%, 2 wt.%, 3 wt.%, and 4 wt.%) were exposed to UV-light irradiation for 25 hr. The results indicated that the photocatalytic degradation of phenanthrene followed the pseudo first-order kinetics. TiO2 significantly accelerated the degradation of phenanthrene with the half-life reduced from 45.90 to 31.36 hr for TiO2 loading of 0 wt.% and 4 wt.%, respectively. In addition, the effects of H2O2, light intensity and humic acid on the degradation of phenanthrene were investigated. The degradation of phenanthrene increased with the concentration of H2O2, light intensity and the concentration of humic acids. It has been demonstrated that the photocatalytic method in the presence of nanometer anatase TiO2 was a very promising technology for the treatments of soil polluted with organic substances in the future.

Resistance of nanocrystalline vis-à-vis microcrystalline Fe–Cr alloys to environmental degradation and challenges to their synthesis

This paper presents a hypothesis and its experimental validation that a nanostructure can bring about dramatic improvements in the oxidation/corrosion resistance of iron–chromium alloys. More specifically, a nanocrystalline Fe–10 wt% Cr alloy was found to undergo oxidation at a rate that was an order of magnitude lower than its microcrystalline counterpart. Importantly, the oxidation resistance of nanocrystalline Fe–10 wt% Cr alloy was comparable with that of the common corrosion-resistant microcrystalline stainless steels (having 18–20 wt% chromium). The findings have the potential of leading to the next generation of oxidation-resistant alloys. However, due to poor thermal stability of nanocrystalline structure, synthesis/processing of such alloys is a challenge. Discs of nanocrystalline Fe–10% Cr alloy were produced by ball-milling of Fe and Cr powders and compaction of the powder without considerable grain growth by processing within a suitable time–temperature window. The paper also presents a theoretical treatise to arrive at the minimum chromium content required for establishing a protective layer of chromium oxide in an Fe–Cr alloy of a given nanometric grain size.

Exhibit review : Focus on strangers: photo albums of World War II, Stadtmuseum, Jena, Germany, 2011

Focus on Strangers: Photo Albums of World War II is based on a collaborative research project conducted by two German universities (Carl von Ossietzky Universität Oldenburg and Friedrich Schiller Universität Jena) and was conceptualized in cooperation with four German city museums in Oldenburg, Munich, Frankfurt, and Jena. While the exhibition continues a tradition of museological projects examining Germany’s war history, such as the Wehrmachtsaustellung, which provoked fi erce public debate, Focus on Strangers moves beyond most conventional approaches in a signifi cant way. Th e exhibition pays tribute to the recent development in which private traces of memory have become part of the public perception of history, in this case the history of World War II.

De/composing Gran's photo album

This is the story of my maternal grandmother's photo album as it is seen through the feminist psychoanalytic eyes of her granddaughter. The photos take on particular meanings as my mother and I ponder over them. The photo album, set against the backdrop of the early twentieth century, tells tales of frivolity and young romance, friendship and daughterhood, extended families and holidays. What is most significant, however, is the way in which the photos are framed within the patriarchal Catholic discourse, which enveloped my grandmother's life. Yet, it is argued that there were, and continue to be, momentary fissures and ruptures in this patriarchal discourse as feminist psychoanalytic frames come into view.

Thermal degradation kinetics and mechanism of epoxidized natural rubber

Thermal resistance is one of the most dominative properties for polymer materials. Thermal degradation mechanisms of epoxidized natural rubber (ENR) and NR are studied by thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results show that, the introduction of epoxy groups into the NR molecular main chain leads to a remarkable change in the degradation mechanism. The thermal stability of ENR is worse than that of NR. For the first thermooxidative degradation stage, the thermal decomposition mechanism of ENR is similar to that of NR, which corresponds to a mechanism involving one-dimensional diffusion. For the second stage, the thermal decomposition mechanism of ENR is a three-dimensional diffusion, which is more complex than that of NR. Kinetic analysis showed that activation energy (E?), activation entropy (?H) and activation Gibbs energy (?G) values are all positive, indicating that the thermooxidative degradation process of ENR is non-spontaneous.

Semantic photo synthesis

Composite images are synthesized from existing photographs by artists who make concept art, e.g., storyboards for movies or architectural planning. Current techniques allow an artist to fabricate such an image by digitally splicing parts of stock photographs. While these images serve mainly to “quickly”convey how a scene should look, their production is laborious. We propose a technique that allows a person to design a new photograph with substantially less effort. This paper presents a method that generates a composite image when a user types in nouns, such as “boat”and “sand.”The artist can optionally design an intended image by specifying other constraints. Our algorithm formulates the constraints as queries to search an automatically annotated image database. The desired photograph, not a collage, is then synthesized using graph-cut optimization, optionally allowing for further user interaction to edit or choose among alternative generated photos. An implementation of our approach, shown in the associated video, demonstrates our contributions of (1) a method for creating specific images with minimal human effort, and (2) a combined algorithm for automatically building an image library with semantic annotations from any photo collection.