Laakerikipinöintilaskurin toteuttaminen FPGA- piirillä

FPGA- piirit ovat viime vuosina kehittyneet tehokkaammiksi, mutta samalla niiden hinta on laskenut tasolle, jolloin ne ovat vaihtoehto yhä useampiin sovelluksiin. Kandidaatintyöni aiheena oli suunnitella ja mahdollisesti toteuttaa sulautettu laite, joka laskisi signaalissa esiintyvien pulssien lukumäärää. Sitä käytettäisiin mitattaessa kipinöintiä sähkömoottorin laakeroinnissa. Kipinät havaitaan moottorin ulkopuolelta UHF- antennilla. Antennisignaalista poimittavat pulssit ovat hyvin nopeita, joten digitaaliselta logiikalta vaaditaan myös erityistä nopeutta. Tämän takia laitetta lähdettiin toteuttamaan esimerkiksi mikrokontrollerin sijasta FPGA- piirin avulla. Pulssilaskurin toteutus onnistui suhteellisen vaivattomasti FPGAlla, ja sen toimivuutta käytännössä päästiin testaamaan todellisissa olosuhteissa.

Reciclagem do lixo de informática: uma oportunidade para a química

Recycling and sustainable development are increasing in importance around the world. In Brazil, the new National Policy on Solid Wastes has prompted discussion on the future of electronic waste (e-waste). Brazil generates the greatest amount of e-waste among Latin American countries. Nevertheless complete recycling, including end processing of e-waste, does not occur in Brazil. This paper discusses the physical and chemical technologies currently used worldwide and in Brazil for printed circuit board recycling, with emphasis on metal recovery and plastic processing. The goal is to put in evidence the important role that chemistry can play in developing cheaper processes to recycle e-waste.

Processamento de placas de circuito impresso de equipamentos eletroeletrônicos de pequeno porte

A hydrometallurgical process applicable to printed circuit boards of small electrical and electronic devices was developed. This involved three leaching steps (60 ºC, 2 h): 6 mol L-1 NaOH, 6 mol L-1 HCl and aqua regia. NaOH removed the resin and flame retardant that covered the circuit boards. HCl dissolved the most electropositive metals and a small amount of copper (~0.3 wt%). Aqua regia dissolved the noble metals. Silver precipitated as AgCl. Gold and platinum were quantitatively extracted with pure methyl-isobutylketone and Alamine 336 (10 % vol. in kerosene), respectively. Slow evaporation of the raffinate crystallized CuCl2.4H2O (89% yield).

Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods

This work presents the use of potentiometric measurements for kinetic studies of biosorption of Cd2+ ions from aqueous solutions on Eichhornia crassipes roots. The open circuit potential of the Cd/Cd2+ electrode of the first kind was measured during the bioadsorption process. The amount of Cd2+ ions accumulated was determined in real time. The data were fit to different models, with the pseudo-second-order model proving to be the best in describing the data. The advantages and limitations of the methodology proposed relative to the traditional method are discussed.

APARATO ELETROQUÍMICO PARA SISTEMA DE AQUISIÇÃO DE DADOS MULTICANAL COM RESOLUÇÃO ESPAÇO-TEMPORAL

Spatiotemporal pattern formation in reaction-transport systems takes place spontaneously when the system is kept far from thermodynamic equilibrium. Targets, reaction fronts, waves, spirals, spots and stripes are some typical examples of selforganized structuring. In electrochemical systems, monitoring spatiotemporal patterns of potential in the solid/liquid interface can be done by the use of equally distributed microprobes located close to the working electrode. However, the physical size of each probe can limit the spatial resolution and alter mass transport properties. In contrast, the direct measurement of discrete electrodes does not suffer from this limitation and allows the accurate manipulation of the spatial coupling through changes in resistors connected to the electric circuit. In this paper, the development of an electrochemical setup for multichannel data acquisition with spatiotemporal resolution is described, especially to monitor low levels of currents usually observed in the electro-oxidation of small organic molecules.

LOW COST ANALYZER FOR THE DETERMINATION OF PHOSPHORUS BASED ON OPEN-SOURCE HARDWARE AND PULSED FLOWS

The need for automated analyzers for industrial and environmental samples has triggered the research for new and cost-effective strategies of automation and control of analytical systems. The widespread availability of open-source hardware together with novel analytical methods based on pulsed flows have opened the possibility of implementing standalone automated analytical systems at low cost. Among the areas that can benefit from this approach are the analysis of industrial products and effluents and environmental analysis. In this work, a multi-pumping flow system is proposed for the determination of phosphorus in effluents and polluted water samples. The system employs photometric detection based on the formation of molybdovanadophosphoric acid, and the fluidic circuit is built using three solenoid micropumps. The detection is implemented with a low cost LED-photodiode photometric detection system and the whole system is controlled by an open-source Arduino Uno microcontroller board. The optimization of the timing to ensure the color development and the pumping cycle is discussed for the proposed implementation. Experimental results to evaluate the system behavior are presented verifying a linear relationship between the relative absorbance and the phosphorus concentrations for levels as high as 50 mg L-1.

Antenna Design for Contactless IC Card Applications

Contactless integrated circuit cards are one form of application of radio frequency identification. They are used in applications such as access control, identification, and payment in public transport. The contactless IC cards are passive which means that both the data and the energy are transferred to the card without contact using inductive coupling. Antenna design and optimization of the design for contactless IC cards defined by ISO/IEC14443 is studied. The basic operation principles of contactless system are presented and the structure of contactless IC card is illustrated. The structure was divided between the contactless chip and the antenna. The operation of the antenna was covered in depth and the parameters affecting to the performance of the antenna were presented. Also the different antenna technologies and connection technologies were provided. The antenna design process with the parameters and the design tools isillustrated and optimization of the design is studied. To make the design process more ideal a target of development was discovered, which was the implementation of test application. The optimization of the antenna design was presented based on the optimization criteria defined in this study. The solution for the implementation of these criteria and the effect of each criterion was found. For enhancing the performance of the antenna a focus for future study was proposed.

Impedanssisovituksen tarkkailu jännitevälipiirillisessä taajuusmuuttajakäytössä

Invertterikäyttöjen pitkissä kuormakaapeleissa jännitteen aaltomuodossa on havaittavissa ylijännitteitä. Ylijännitteet johtuvat invertterikäytön käyttämien kytkinten ohjaamisesta pulssinleveysmodulaatiolla, niiden nopeista kytkeytymisistä ja itse järjestelmästä. Ylijännitteet ovat haitallisia järjestelmässä, joten niitä pyritään estämään esim. suodattamalla. Yksi käytännön sovellus sähkökoneen suotimena on RC-suodin. RC-suotimen toimintakyvyn aleneminen on kuitenkin oletettavaa, joten sähkökone altistuu tällöin ylijännitteille. Mittaamalla RC-suotimen kuntoa voidaan valvoa generaattorin kokemia ylijännitteitä. Työssä tarkastellaan järjestelmän häiriöitä ja ylijännitteitä, RC-suodinta sekä suotimen vajaatoimintatiloja, ja kehitetään mittaus tarkkailemaan vajaatoimintaa.