992 resultados para chiral guanidines


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In this communication we present results of a study of chiral symmetry in quark matter using an effective Coulomb gauge QCD Hamiltonian. QCD in Coulomb gauge is convenient for a variational approach based on a quasiparticle picture for the transverse gluons, in which a confining Coulomb potential arises naturally. We show that such an effective Hamiltonian predicts chiral restoration at too low quark densities. Possible reasons for such deficiency are discussed.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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A set of five fungal species, Botrytis cinerea, Trichoderma viride and Eutypa lata, and the endophytic fungi Colletotrichum crassipes and Xylaria sp., was used in screening for microbial biocatalysts to detect monooxygenase and alcohol dehydrogenase activities (for the stereoselective reduction of carbonyl compounds). 4-Ethylcyclohexanone and acetophenone were biotransformed by the fungal set. The main reaction pathways involved reduction and hydroxylations at several positions including tertiary carbons. B. cinerea was very effective in the bioreduction of both substrates leading to the chiral alcohol (S)-1-phenylethanol in up to 90% enantiomeric excess, and the cis-trans ratio for 4-ethylcyclohexanol was 0:100. trans-4-Ethyl-1-(1S-hydroxyethyl)cyclohexanol, obtained from biotransformation by means of an acyloin-type reaction, is reported here for the first time. The absolute configurations of the compounds trans-4-ethyl-1-(1S-hydroxyethyl)cyclohexanol and 4-(1S- and 4-(1R-hydroxyethyl)cyclohexanone were determined by NMR analysis of the corresponding Mosher's esters. (C) 2009 Elsevier Ltd. All rights reserved.

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We describe the derivation of an effective Hamiltonian which involves explicit hadron degrees of freedom and consistently combines chiral symmetry and color confinement. We use a method known as Fock-Tani (FT) representation and a quark model formulated in the context of Coulomb gauge QCD. Using this Hamiltonian, we evaluate the dissociation cross section of J/psi in collision with rho.

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We briefly discuss four different possible types of transitions from quark to hadronic matter and their characteristic signatures in terms of correlations. We also highlight the effects arising from mass modification of hadrons in hot and dense hadronic matter, as well as their quantum statistical consequences: the appearance of squeezed quantum states and the associated experimental signatures, i.e., the back-to-back correlations of particle-antiparticle pairs. We briefly review the theoretical results of these squeezed quanta, generated by in-medium modified masses, starting from the first indication of the existence of surprising particle-antiparticle correlations, and ending by considering the effects of chiral dynamics on these correlation patterns. Nevertheless, a prerequisite for such a signature is the experimental verification of its observability. Therefore, the experimental observation of back-to-back correlations in high energy heavy ion reactions would be a unique signature, proving the existence of in-medium mass modification of hadronic states. on the other hand, their disappearance at some threshold centrality or collision energy would indicate that the hadron formation mechanism would have qualitatively changed: asymptotic hadrons above such a threshold are not formed from medium modified hadrons anymore, but rather by new degrees of freedom characterizing the medium. Furthermore, the disappearance of the squeezed BBC could also serve as a signature of a sudden, non-equilibrium hadronization scenario from a supercooled quark-gluon plasma phase.

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We derive the current algebra of supersymmetric principal chiral models with a Wess-Zumino term. At the critical point one obtains two commuting super-affine Lie algebras as expected, but, in general, them are intertwining fields connecting both right and left sectors, analogously to the bosonic case. Moreover, in the present supersymmetric extension we have a quadratic algebra, rather than an affine Lie algebra, due to the mixing between bosonic and fermionic fields; the purely fermionic sector displays an affine Lie algebra as well.

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1/N(c) expansion in QCD (with N(c) the number of colors) suggests using a potential from meson sector (e.g., Richardson) for baryons. For light quarks a sigma-field has to be introduced to ensure chiral symmetry breaking (chi-SB). It is found that nuclear matter properties can be used to pin down the chi-SB modeling. All masses, M(N), m-sigma, m-omega, are found to scale with density. The equations are solved self-consistently.

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The Nolen-Schiffer anomaly is the long standing discrepancy between theory and experiment of binding energy differences of mirror nuclei. It appears that the anomaly is largely explained by the charge symmetry breaking force generated by the rho(0)-omega mixing. In this paper I discuss the effect of the rho(0)-omega mixing to the binding energy differences in relativistic models of the nucleus. I also discuss the issue of momentum dependence of rho(0)-omega mixing amplitude and present an alternative explanation of the anomaly based on the partial restoration of chiral symmetry in the nucleus.

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In this paper we deal with an alternative approach to the description of massless particles of arbitrary spin. Within this scheme chiral components of a spinor field are regarded as fundamental quantities and treated as independent field variables. The free field Lagrangian is built up from the requirement of chiral invariance; This formulation is parallel to the neutrino theory and allows for a formulation that generalizes, to particles of arbitrary spin, the two-component neutrino theory. We achieve a spinor formulation of electrodynamics. In the case of the photon, the nonzero helicity components satisfy Weyl's equations and are associated to observables (electromagnetic fields) whereas the zero helicity components are related to nonobservables (electromagnetic potentials). Within the spinor formulation of electrodynamics the minimal coupling substitution follows as a consequence of the linearity of the interaction and the preference of nature for chiral components, that is, of the left-right asymmetry of nature. (C) 1996 American Institute of Physics.

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The total synthesis of 8,9-licarinediols was selectively carried out from licarin A, previously obtained by oxidative coupling of (E)-isoeugenol. The corresponding enantiomerically pure (+)- and(-)-licarin A ester derivatives were subjected to Sharpless oxidation to yield the asymmetric C-8, C-9 dihydroxylation products, whose absolute configurations were established by means of the CD and NMR spectroscopic analyses of their Mosher ester derivatives. (C) 2000 Elsevier B.V. Ltd. All rights reserved.

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We report the identification of a potential pheromone for Gnathotrichus materiarius (Fitch) (Col., Scolytidae). The population sex ratio is close to 1:1, and males initiate attacks on host trees. Headspace and hindgut samples from single males showed the presence of the putative pheromone 6-methyl-5-hepten-2-ol, sulcatol. Unmated males released sulcatol for at least 12 days, and ceased producing the pheromone after 20 days. The peak sulcatol release occurred after 2 days. Males cease production of sulcatol 24 h after being paired with females. Single females were unable to initiate galleries, and no sulcatol was detected from their headspace and hindgut samples. The chiral ratio of the pheromone, observed from headspace samples, was 31% (S)-(+)- and 69% (R)-(-)-sulcatol.

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We start this work by revisiting the problem of the soldering of two chiral Schwinger models of opposite chiralities. We verify that, different from what one can conclude from the current literature, the usual sum of these models is, in fact, gauge invariant and corresponds to a composite model, where the component models are the vector and axial Schwinger models. As a consequence, we reinterpret this formalism as a kind of degree of freedom reduction mechanism. This result has led us to discover a second soldering possibility giving rise to the axial Schwinger model. This new result is seemingly rather general. We explore it here in the soldering of two Maxwell-Chern-Simons theories with different masses.