ELECTROACTIVE COATINGS OF DICYANO-BIS(1,10-PHENANTHROLINE)IRON(II) ATTACHED TO NAFION POLYMER FILM-MODIFIED ELECTRODES VIA ADSORPTION

A dicyano-bis(1,10-phenanthroline)iron(II) modified elecrode was prepared. The voltammetric and the spectroelectrochemical behavior of this electrode were investigated. The influence of pH and the amount of Nafion and dicyano-bis(1,10-phenanthroline) iron(II) (DBPI) used in the electrode preparation on the electrochemical behavior is presented.

AN EXTENSION OF THE METHOD FOR PREDICTING PERMEABILITY THROUGH POLYMER MEMBRANES FROM SIMPLE GASES TO WATER-VAPOR

It is found that there is a linear relationship between log P-w, and the parameter term V-f/0.5 E(coh) [1+(delta(w) - delta(p))(2)/delta(p)(2), from the water permeability (P-w) data of 21 polymers covering 4 orders of magnitude. This correlation may be useful in choosing membrane materials for dehumidification of gases.

IN-SITU COMPOSITE - PHENOLPHTHALEIN POLYETHERSULFONE-THERMOTROPIC LIQUID-CRYSTALLINE POLYMER BLENDS

Phase behavior, thermal, theological and mechanical properties plus morphology have been studied for a binary polymer blend. The blend is phenolphthalein polyethersulfone (PES-C) with a thermotropic liquid crystalline polymer (LCP), a condensation copolymer of p-hydroxybenzoic acid with ethylene terephthalate (PHB-PET). It was found that these two polymers form optically isotropic and homogeneous blends by means of a solvent casting method. The homogeneous blends undergo phase separation during heat treatment. However, melt mixed PES-C/PHB-PET blends were heterogeneous based upon DSC and DMA analysis and SEM examination. Addition of LCP in PES-C resulted in a marked reduction of melt viscosity and thus improved processability. Compared to pure PES-C, the charpy impact strength of the blend containing 2.5% LCP increased 2.5 times. Synergistic effects were also observed for the mechanical properties of blends containing < 10% LCP. Particulates, ribbons, and fibrils were found to be the typical morphological units of PHB-PET in the PES-C matrix, which depended upon the concentration of LCP and the processing conditions.

SYNTHESIS AND CHARACTERIZATION OF CROSS-LINKED 2ND-ORDER NONLINEAR-OPTICAL POLYMER

The present paper reports the synthesis of glycidyl monoether of 4-[(p-nitrophenyl) azo] phenol (GMNA) and crosslinking reaction of GMNA with hexamethylene diisocyanate biuret (HDIB). The Tg of crosslinked polymer was investigated by DSC. The orientation and stability of the poled and crosslinked polymer film were studied by UV-Vis spectra and Maker fringe method.

CURE AND IONIC-CONDUCTIVITY OF A 2-COMPONENT EPOXY NETWORK POLYMER ELECTROLYTE

In order to raise the room temperature ionic conductivity and improve the mechanical strength of a PEO-based polymer electrolyte, a non-crystalline two-component epoxy network was synthesized by curing diglycidyl ether of polyethylene glycol (DGEPEG) with triglycidyl ether of glycerol (TGEG) in the presence of LiClO4 salt, which acts in this system as both a ring opening catalyst and a source of ionic carrier. The structure of the precursors, the curing process and the cured films have been characterized by C-13 NMR, IR, DSC and ionic conductivity measurement techniques. The electrolyte system exhibits an ionic conductivity as high as similar to 10(-5) S/cm at 25 degrees C and is mechanically self-supportable. The dependence of ionic conductivity was investigated as a function of temperature, salt content, MW of PEG segment in DGEPEG and the proportion of DGEPEG in DGEPEG/TGEG ratio.

Study on comblike polymer electrolyte

New comblike polymers(CP) have been synthesized by reacting monomethyl ether of polyethylene glycol(PEGME) with poly(methyl vinyl ether-alt-maleic anhydride)(MA) and endcapping the residual carboxylic acid with methanol. Butanone was selected as a solvent for the esterification reaction in order to obtain a completely soluble product. They were characterized by IR, C-13 NMR and elemental analysis.

Study on new comb polymer electrolyte(III)

A new solid polymer electrolyte has been prepared using NaClO4 and a comb-branch polymer with oligo(ethylene oxide) side chains. The thermal and ionic conductive properties of the electrolytes were investigated. The profile of conductivity at various temperatures follows the VTF plots.

Study on a new comb polymer electrolyte(II)

A comb polymer(CP350) with oligo-oxyethlene side chains was prepared from methyl vinyl ether/maleic anhydride copolymer. Homogeneous amorphous polymer electrolyte were made from the comb polymer and LiCF3SO3 by solvent casting from acetone, and their conductivities were measured as a function of temperature and salt concentration. Maximum conductivity close I to 5.08 x 10(-5)S/cm was achieved at room temperature at [Li]/[EO] ratio of about 0.12.

MOLECULAR-STATE OF GRAFT-COPOLYMERS IN THE INTERFACIAL AREA OF POLYOLEFIN AND POLAR POLYMER

In order to characterize the interface in polymer blends, a new method is suggested, in which the interface is exposed by selectively dissolving in solvent. By means of X-ray photoelectron spectrometry, we studied the molecular state in the interfacial ar