Results of biogeochemical studies in the Russian Arctic seas: isotope and radioisotope data

Comprehensive biogeochemical studies including determination of isotopic composition of organic carbon in both suspended matter and surface layer (0-1 cm) bottom sediments (more than 260 determinations of d13C-Corg) were carried out for five Arctic shelf seas: White, Barents, Kara, East Siberian, and Chukchi Seas. The aim of this study is to elucidate causes that change isotopic composition of particulate organic carbon at the water-sediment boundary. It is shown that isotopic composition of organic carbon in sediments from seas with high river run-off (White, Kara, and East Siberian Seas) does not inherit isotopic composition of organic carbon in particles precipitating from the water column, but is enriched in 13C. Seas with low river run-off (Barents and Chukchi Seas) show insignificant difference between d13C-Corg values in both suspended load and sediments because of low content of isotopically light allochthonous organic matter in suspended matter. Biogeochemical studies with radioisotope tracers (14CO2, 35S, and 14CH4) revealed existence of specific microbial filter formed from heterotrophic and autotrophic organisms at the water-sediment boundary. This filter prevents mass influx of products of organic matter decomposition into the water column, as well as reduces influx of OM contained in suspended matter from water into sediments.

Composition of organic matter from black shales drilled in the Cape Verde Basin in DSDP Hole 41-367

Results of geochemical studies of organic matter in black shales from the Cape Verde Basin are reported. Based on these results, in combination with data of petrographic analysis, conclusions are made about sapropelic nature of their organic matter and low degree of its coalification. It corresponds to the proto-catagenetic substage of sedimentary rocks. Black shales of the Cape Verde Basin are classified as potential oil source strata.

Magnetic susceptibility of bottom sediments from the Middle and South Caspian Sea

Dependence of magnetic susceptibility of bottom sediments from the Caspian Sea on composition of magnetoactive minerals contained in the heavy subfraction of fine-grained sand (0.125-0.100 mm grain size fraction) was established. Changes in the curve shape and magnetic susceptibility values reflect a pulsating pattern of input of different (in magnetic properties) magmatic and metamorphic clastic minerals into sediments, as well as different intensities of formation of authigenic magnetoactive iron sulfides under conditions of multiple alternation of transgressive and regressive phases in marine basins. Values of magnetic susceptibility and shapes of magnetic susceptibility curves for studied sedimentary sequences show that sediments in the South and Middle Caspian Basins are characterized by different specific features.

(Table 1) Results of X-ray radiographic analyses of authigenic phosphorites from the Southwest Africa shelf

In the biologically productive area on the Southwest Africa shelf a current process of diagenetic phosphorite formation occurs. Remains of phytoplankton are the main source of phosphorus in host bottom sediments. Phosphorus concentrates in nodules due to its redistribution in bottom sediments and precipitation from interstitial waters. Accumulation of the phosphate nodules, as well as of scattered fish bone debris in sediments occurs at sudden change in hydrological conditions and removal of fine sediment fractions due to increased bottom currents or during transgressions.