999 resultados para Lead magnesium niobate


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Consumption of wrought magnesium products wax reduced by half between 1971 and the 1990s. To increase the use of wrought magnesium, several challenges must be overcome: its formability at room temperature is lower than steel or aluminum; its productivity is lower than steel or aluminum; and extruded magnesium exhibits a marked anisotropy of yield when comparing tension and compression. This article describes research on the rapid evaluation of the extrusion behavior of wrought magnesium alloys. The work aims to establish a methodology for rapid prototyping of alloys and to assess the effects of aluminum on the behavior of AZ-series magnesium alloys.

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Background and Purpose. Obstacle crossing is compromised following stroke. The purpose of this study was to quantify modifications during obstacle clearance following stroke.

Subjects. Twelve subjects with stroke and 12 subjects without stroke participated in the study.

Methods. Kinematic variables were measured while participants crossed a 4-cm-high obstacle. Subjects with stroke walked at a self-selected speed; subjects without stroke walked at a comparable speed and at a self-selected speed.

Results. Several modifications were observed following stroke with both groups walking at self-selected speeds. The affected lead limb was positioned closer to the obstacle before crossing. Affected trail-limb clearance over the obstacle was reduced. Both affected and unaffected lead and trail limbs landed closer to the obstacle after clearance. Swing time was increased in the affected lead limb after obstacle clearance. Fewer modifications were detected at matched walking speed; the trail limb still landed closer to the obstacle.

Discussion and Conclusion. Modifications during obstacle crossing following stroke may be partly related to walking speed. The findings raise issues of safety because people with stroke demonstrated reduced clearance of a 4-cm obstacle and limb placement closer to the obstacle after clearance.

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A description of the key solidification steps in the formation of the as-cast microstructure of magnesium alloys is presented. The focus is on the two common magnesium alloy groups: Mg-Al alloys and Mg-Zn-rare earth alloys. The key elements described are: nucleation (including grain refinement), growth of the primary phase and the formation of the eutectic phases. In addition the effect of casting process (e.g. high-pressure diecasting and sand casting) on the outcomes from solidification are discussed. This includes consideration of the formation of banded defects during solidification in the dynamic environment of high pressure die casting.

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Owing to the limited solubility of zirconium in molten magnesium, almost all of the zirconium contained in the Zirmax® master alloy (Mg-33.3Zr) is present in the form of nearly pure zirconium particles. Of them, zirconium particle clusters and individual zirconium particles greater than 5

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The present work examines the microstructure that evolves during the annealing of hot worked magnesium alloy AZ31. First, the influences of deformation and annealing conditions on the microstructures are assessed. It is found that the annealing behaviour is consistent with what one would expect for a recrystallization type reaction. Whilst both the deformation and annealing conditions influence the time required to reach a stable annealed microstructure, the grain size attained is governed solely by the prior deformation conditions employed. At the highest temperature and strain rate examined, the rate of recrystallization is quite high and the grain size was found to be approximately double when annealed for only 1 s prior to quenching. Finally, semi-empirical equations are developed to predict the kinetics of recrystallization, as well as the evolution of grain size, during annealing.

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The present work combines electron backscattering diffraction and Schmid analysis to investigate secondary twinning in the magnesium alloy Mg–3Al–1Zn. Inspection of the misorientations between the parent and {1011} - {1012} doubly twinned volumes reveals that there are four possible variants. One of these variants (the one that forms a misorientation with the matrix characterized by 38°⟨1210⟩ ) is favoured much more than the others. This variant involves the activation of secondary twinning systems quite inconsistent with Schmid-type behaviour. For the secondary twin to grow significantly it must take on a shape enforced by the primary twin. This is non-optimal for strain compatibility. It is argued that the 38°⟨1210⟩ variant occurs most because it provides the closest match between the primary and secondary twinning planes, thus minimizing the compatibility strain.

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A series of alloys have been produced with microalloying additions of rare-earth (RE) elements in the range of 0.1–0.4 wt.%. The alloys have been extruded to produce grain sizes of 23 ± 5 μm. The texture of the extruded alloys was measured, and it was found that the extrusion texture was weakened by the addition of RE elements. The samples with weakened extrusion textures exhibited an increase in the tensile elongation.

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The energy absorbed by magnesium alloys (high-pressure die-cast (HPDC) AM20, AM50, AM60, and extruded AZ31) in a buckling test was significantly greater than the aluminum alloy 6061 T6 and particularly mild steel of a similar weight, but was less than that of the aluminum alloy and steel for the same thickness (Figure 6).26 This indicates that mass savings can be achieved by the substitution with magnesium alloys to achieve similar energy-absorbing characteristics.

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One ZM61 alloy (6·2%Zn, 1·2%Mn) and two magnesium alloys containing nominally 3% of neodymium and yttrium respectively have been prepared in the form of hot extruded flat strips. Their textures and microstructures have been quantified and series of mechanical tests were carried out to determine plane stress yield loci in both the solution treated and aged conditions. The ZM61 alloy had a sharp texture and marked anisotropy of strength that could be rationalised in terms of deformation by basal <a> slip and {1012}<1011> twinning. This material was much weaker in compression than in tension. Precipitation hardening on aging caused a greater impedance to twinning than to slip with the result that the anisotropy was somewhat reduced. The Mg–3Nd alloy had a very weak and different texture but nevertheless demonstrated a pronounced anisotropy of strength. Aging increased the yield stress by about 80% and also inhibited twinning to some extent although the degree of anisotropy remained almost unaffected. The Mg–3Y alloy which showed a texture of intermediate strength was different in type from either of the others. Its strength behaviour was close to isotropic; in particular, no difference existed between tensile and compressive loading, and aging produced only a marginal increase in strength. Twins were relatively infrequent in the deformed Mg–3Y alloy but its mechanical behaviour could not be rationalised according to simple models.

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This paper reports on a two staged staff development exercise to help new academic staff to integrate Web 2.0 technologies including web-based communication and some digital technologies into their curricula. It involved professional development for the teaching staff in the first stage followed by these teachers providing professional development for the course participants. The teachers engaged in a blended community of inquiry with face-to-face sessions and online work while the professional development for the course participants included technical support, training and a peer group environment with formal allocation of time for the course, finally leading to an institutionally recognised qualification. Evaluations conducted through focus group interviews revealed that collegial networks and time were important for effective professional development. The paper reflects on the successes and limitations of the model and its potential for further development. It also highlights the importance of providing professional development in a safe environment for academics to adopt technologies for teaching and learning.

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The present work combines electron backscatter diffraction, transmission electron microscopy and Schmid analysis to investigate secondary twinning in the magnesium alloy Mg-3AI-1Zn. Inspection of the misorientations between the parent matrix and {1011} - {1012} doubly twinned volumes reveals that there are four possible variants. One of these variants characterized by 38°< 1210 > misorientation with the matrix is favoured much more than the others. This variant involves activation of the secondary twinning systems that are quite inconsistent with the Schmid-type behaviour. For the secondary twin to grow significantly it must take on a shape enforced by the primary twin, however, this is not optimal for strain compatibility. It is argued that the 38° < 1210 > variant occurs most frequently because it provides the closest match between the primary and secondaty twinning planes, thus minimizing the compatibility strain. This conjecture is confirmed by the simulations of twin activity m ellipsoidal grains performed using the visco-plastic self-consistent crystal plasticity model.