997 resultados para IR spectrum


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A 3-dimensional non-commutative oscillator with no mass term but with an appropriate momentum-dependent potential admits a conserved Runge-Lenz vector, derived from the dual description in momentum space. The trajectories lie on ellipses. The dynamical symmetry allows for an algebraic determination of the bound-state spectrum and extends to o(4,2). (c) 2010 Elsevier B.V. All rights reserved.

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This paper reports laboratory measurements of the spectrum of the most abundant transition Fe ions in the universe. Spectrum of iron of low-lying excited states has been observed in the wavelength range 250-400 angstrom at Chinese Institute of Atomic Energy on the HI-13 tandem accelerator with beams of 130 MeV. A number of spectral lines have been mainly classified as transitions of magnesium-, sodium-, neon-, fluorine-like ions. A total of 54 lines have been measured. Most of them have been mainly ascribed to 3s3p(k)-3p(k+1), 3s(2)3p(k)-3s3p(k+1), 2p(5)3s-2p(5)3p, 3s3d-3p3d and 2p(5)3p-2p(5)3d resonance transitions. These spectral lines have been identified, among which 21 are new and accurately measured. The analysis of the spectra was based on a comparison with other experimental results and calculated values. (c) 2010 Elsevier Ltd. All rights reserved.

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Calculations of the 4d absolute photoabsorption cross sections of the Xe-like Cs+ ion covering the energy region from 80 to 190 eV have been performed by using the multi-configuration Dirac-Fock method. The calculated cross sections are compared with the absolute experimental photoabsorption cross-section spectrum (Kjeldsen et al 2002 J. Phys. B: At. Mol. Opt. Phys. 35 2845) and other available theoretical results. In the 80-90 eV region, the discrete structure resulting from photoexcitation of a 4d electron into nf and np orbits are successfully identified. Above the 4d threshold, i.e. in the 90-190 eV energy region, a reasonable agreement between experiment and computations is found for the intense 4d -> epsilon f shape resonance.

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The effect of momentum-dependent interaction on the kinetic energy spectrum of the neutron-proton ratio. <(n/p)(gas)>(b)(E-k) for Zn-64 + Zn-64 is studied. It is found that. <(n/p)(gas)>(b)(E-k) sensitively depends on the momentum-dependent interaction and weakly on the in- medium nucleon- nucleon cross section and symmetry potential. Therefore <(n/p)(gas)>(b)(E-k) is a possible probe for extracting information on the momentum-dependent interaction in heavy ion collisions.

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The neutron deficient nuclide Ir-175 was produced by irradiation of Nd-146 with 210 MeV Cl-35 via a fusion-evaporation reaction channel. The reaction products were transported to a low-background location using a helium-jet recoil fast-moving tape-transport system for measurement. The experimental devices and data analysis method are introduced. Based on the decay-curve fitting of the beta-delayed gamma ray from Ir-175, realized by the least-square method, a new long-lived isomeric state of Ir-175 is proposed and briefly discussed.

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A fully consistent relativistic continuum random phase approximation (RCRPA) is constructed in terms of the Green's function technique. In this method the contribution of the continuum spectrum to nuclear excitations is treated exactly by the single particle Green's function, which includes also the negative states in the Dirac sea in the nose aapproximation. The theoretical formalism of RCRPA and numerical details are presented. The single particle Green's function is calculated numerically by a proper product of regular and irregular solutions of the Dirac equation. The numerical details and the formalism of RCRPA in the momentum representation are presented.

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In order to study the gas-phase chemical behavior of transactinides, an on-line isothermal chromatography apparatus has been developed and applied to separate short-lived technetium isotopes in the form of TcO3 from fission products. The fission products from a Cf-252 source were continuously and rapidly transported through the capillary to the isothermal chromatography apparatus using the N-2/KBr gas-jet techniques. Volatile oxide molecules were formed at the reaction zone kept at 900 degrees C since a trace amount of oxygen existed in the N-2 carrier gas. With the new developed isothermal chromatography apparatus, a selective separation of Tc from fission products was achieved. After isothermal chromatographic separation, Tc-101,Tc-103,Tc-104,Tc-105,Tc-106,Tc-107,Tc-108 were dominantly observed together with their Ru daughters in the gamma-spectrum, The chemical yields of Tc-101, and Tc-104 and Tc-105 isotopes with longer half-lives are about 55-57%, and those of Tc-103, Tc-106 and Tc-108 isotopes with shorter half-lives dropped down to 25-28%. The adsorption enthalpy of the investigated compounds on quartz surfaces was determined to be -150 +/- 5 kJ/mol by fitting the measured retention curves with a Monte Carlo model. The observed species of technetium oxide is attributed to TcO3, which is in good agreement with previous experimental results. That means our system worked properly and it can be used to investigate the gas-phase chemical behavior of transactinides.

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本实验工作是在中国原子能科学研究院的HI-13串列加速器国家实验室第二测量厅原子物理实验平台上完成。本工作采用能量为20-50MeV的高电荷态O5+离子去轰击Au, 测量了不同能量下Au的L1、Lα、Lβ、Lγ的X射线谱,计算了不同能量下各条X射线的产生截面,并与ECPSSR理论计算结果进行了比较。实验结果表明σ(Ll)/σ(Lα) 和σ(Lγ)/σ(Lα)与ECPSSR理论计算结果符合比较好,而对于σ(Lβ)/σ(Lα),在较低能区实验值略高于理论值。在中国科学院近代物理研究所320kV高电荷态离子实验研究平台上测量了Xeq+ (q=17-29)入射Al、Ti和Ni等表面诱发的可见光和红外光。通过对靶原子光谱线的研究,实验发现,随着入射离子的电荷态增高,原子和离子的各种光谱线可得到有效地激发。低速高电荷态离子入射金属固体表面,靶原子的特征谱线的激发强度,与入射离子的电荷态q密切相关。qc的实验测量值和理论计算值符合的较好

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随着物理实验要求的提高,利用先进的计算机技术来改造现有的物理实验设备具有重要意义。因此,我们设计研制了光谱测量与能级寿命测量数据获取电子学系统。本文全面论述了这一系统的组成结构。本系统由微机进行控制,通过基于Pentium机上工SA总线的接口电路来控制数据采集过程,实现了测量设备的智能化,并具有高速度、高可靠性的特点。配合软件工作可完全实现实验的无人监控。论文第一部分介绍了这个系统开发的背景及意义。第二部分是这个系统的组成和硬件结构、性能。这个系统完成的主要功能是:(1)采集数据并处理;(2)控制外设马达的运动;(3)显示系统的状态。第三部分是调试过程以及针对在调试中出现的各种实际问题提出的解决办法和预防措施。在设计工作完成之后,本系统在兰州近代物理研究所的加速器实验大厅中进行了模拟实验,并采集了部分数据。通过对获取数据的处理,获得了比较满意的结果。在论文的最后一部分中给出了本系统在实际运行后得出的实验结果以及此系统中可待完善之处。

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这篇论文里,我们对基于ms Windows的微机γ谱分析程序的数学原理,算法及程序设计进行了阐述;同时,我们也介绍了测试结果,此结果表明了拟合过程的高效性,高稳定性与准确性,并且,程序计算出的峰面积也是可接受的。 在第一部分里,全面阐述了数学原理与算法,包括由M. A. Mariscotti设计且已衍生出许多新算法的叫作DIFDIF的找峰算法,由BFGS方法实现的以χ2为拟合优值的拟合过程,在求峰下净面积及进行系统刻度中需要使用的公式等等。这些内客构成了γ谱分析程序设计哲学的核心,也是本论文的重点。 第二章里,我们一方面概括地介绍了基于面向对象思想的从系统分析到设计整个过程的系统开发文档;另一方面,我们也介绍了一些有用的程序片段,它们或者关于C++或MS Windows程序设计方法,或者关于运行时间错的处理。

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本文介绍我们最新研制的微功耗核谱数据获取系统。目前,该系统基于微型计算机(IBM PC 486)获取,有待进一步发展成单片机获取系统。该系统具有功能强、功耗低、体积小、重量轻以及抗辐射的特点。为了降低功耗,电路设计中尽量使电路简单化,并选用微功耗、抗辐射的MOS场效应管元件。功率消耗单通道小于2.2w,若做成四通道可少于4W。 本系统以脉冲幅度分析方式获取数据,软件采用Turbo C 2.0编写,界面友好,操作方便。

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The reactions of both thiophene and H2S onMo(2)C/Al2O3 catalyst have been studied by in situ FT-IR spectroscopy. CO adsorption was used to probe the surface sites of Mo2C/Al2O3 catalyst under the interaction and reaction of thiophene and H2S. When the fresh Mo2C/Al2O3 catalyst is treated with a thiophene/H-2 mixture above 473 K, hydrogenated species exhibiting IR bands in the regions 2800-3000 cm(-1) are produced on the surface, indicating that thiophene reacts with the fresh carbide catalyst at relatively low temperatures. IR spectra of adsorbed CO on fresh Mo2C/Al2O3 pretreated by thiophene/H-2 at different temperatures clearly reveal the gradual sulfidation of the carbide catalyst at temperatures higher than 473 K, while H2S/H-2 can sulfide the Mo2C/Al2O3 catalyst surface readily at room temperature (RT). The sulfidation of the carbide surface by the reaction with thiophene or H2S maybe the major cause of the deactivation of carbide catalysts in hydrotreating reactions. The surface of the sulfided carbide catalyst can be only partially regenerated by a recarburization using CH4/H-2 at 1033 K. When the catalyst is first oxidized and then recarburized, the carbide surface can be completely reproduced.