983 resultados para Characterization physical chemistry


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The Frobenius solution to Legendre/s equation is developed in detail as is Rodrigue's formula, which is employed to normalize Legendre polynomials.

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The difficulties of applying the Hartree-Fock method to many body problems is illustrated by treating Helium's electrons up to the point where tractability vanishes. Second, the problem of applying Hartree-Fock methods to the helium atom's electrons, when they are constrained to remain on a sphere, is revisited. The 6-dimensional total energy operator is reduced to a 2-dimensional one, and the application of that 2-dimensional operator in the Hartree-Fock mode is discussed.

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The Frobenius solution to the differential equations associated with the harmonic oscillator (QM) is carried out in detail.

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The continued fraction method for solving differential equations is illustrated using three famous differential equations used in quantum chemistry.

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This is a set of P. Chem. problems posed at slightly higher than the normal text book level, for students who are continuing in the study of this subject.

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Helium Hamiltonian transformations are discussed in extreme detail.

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These readings are a compendium of earlier works put together and corrected for errors. The subject is solution thermodynamics, based on the one dimensional binary solution as "extended" to three dimensions.

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One component systems are treated from the point of view of the Gibbs' phase rule.