Efeito de parâmetros analíticos sobre a precisão de métodos de extração de zinco do solo

Fifteen soil samples and four extradants (DTPA, Na 2EDTA, HCl and Mehlich 1) were used to study soil extraction methods for available zinc. Each extradant was studied in three soil:solution ratios (1:2, 1:4 and 1:10) and in three extraction periods in the ratio most frequently used. The zinc extracted by DTPA, Na 2EDTA and HCl was not affected by use of soil:solution ratios 1:2 and 1:4, but the amount extracted increased with the 1:10 ratio. In this relation, the variation coefficients increased. With Mehlich, no definite tendency was observed. The increase of extraction period for DTPA extractant, in 1:2 ratio, had little effect on the amount of zinc extracted and on the precision. As to Na 2EDTA extractant in 1:10 ratio, with the increase of extraction time, both increased. As to HCl and Mehlich, both in 1:4 ratio, the increase in extraction period had no effect on the amount of zinc extracted and no definite effect on the precision. Thus, the use of 1:2 ratio for DTPA and Na 2EDTA and 1:4 ratio for acid extractants is recommended. Concerning the period of extraction, 120 min should be used with DTPA and Na 2EDTA, 15 min with HCl and 5 min with Mehlich.