Ages and isotopic signatures of peat cores from a boreal landscape, Interior Alaska

To determine the influence of fire and thermokarst in a boreal landscape, we investigated peat cores within and adjacent to a permafrost collapse feature on the Tanana River Floodplain of Interior Alaska. Radioisotope dating, diatom assemblages, plant macrofossils, charcoal fragments, and carbon and nitrogen content of the peat profile indicate ~600 years of vegetation succession with a transition from a terrestrial forest to a sedge-dominated wetland over 100 years ago, and to a Sphagnum-dominated peatland in approximately 1970. The shift from sedge to Sphagnum, and a decrease in the detrended tree-ring width index of black spruce trees adjacent to the collapse coincided with an increase in the growing season temperature record from Fairbanks. This concurrent wetland succession and reduced growth of black spruce trees indicates a step-wise ecosystem-level response to a change in regional climate. In 2001, fire was observed coincident with permafrost collapse and resulted in lateral expansion of the peatland. These observations and the peat profile suggest that future warming and/or increased fire disturbance could promote permafrost degradation, peatland expansion, and increase carbon storage across this landscape; however, the development of drought conditions could reduce the success of both black spruce and Sphagnum, and potentially decrease the long-term ecosystem carbon storage.

(Table 1) Age determination of sediment core MD99-2284

Dansgaard-Oeschger (D-O) cycles are the most dramatic, frequent, and wide-reaching abrupt climate changes in the geologic record. On Greenland, D-O cycles are characterized by an abrupt warming of 10 ± 5°C from a cold stadial to a warm interstadial phase, followed by gradual cooling before a rapid return to stadial conditions. The mechanisms responsible for these millennial cycles are not fully understood but are widely thought to involve abrupt changes in Atlantic Meridional Overturning Circulation due to freshwater perturbations. Here we present a new, high-resolution multiproxy marine sediment core monitoring changes in the warm Atlantic inflow to the Nordic seas as well as in local sea ice cover and influx of ice-rafted debris. In contrast to previous studies, the freshwater input is found to be coincident with warm interstadials on Greenland and has a Fennoscandian rather than Laurentide source. Furthermore, the data suggest a different thermohaline structure for the Nordic seas during cold stadials in which relatively warm Atlantic water circulates beneath a fresh surface layer and the presence of sea ice is inferred from benthic oxygen isotopes. This implies a delicate balance between the warm subsurface Atlantic water and fresh surface layer, with the possibility of abrupt changes in sea ice cover, and suggests a novel mechanism for the abrupt D-O events observed in Greenland ice cores.

Age determination of sediment cores of the Golf of Lions

Siliciclastic turbidites represent huge volumes of sediments, which are of particular significance for (1) petroleum researchers, interested in their potential as oil reservoirs and (2) sedimentologists, who aim at understanding sediment transport processes from continent to deep-basins. An important challenge when studying marine turbidites has been to establish a reliable chronology for the deposits. Indeed, conventional marine proxies applied to hemipelagic sediments are often unreliable in detrital clays. In siliciclastic turbidites, those proxies can be used only in hemipelagic intervals, providing a poor constraint on their chronology. In this study, we have used sediments from the Rhône Neofan (NW Mediterranean Sea) to demonstrate that pollen grains can provide a high-resolution chronostratigraphical framework for detrital clays in turbidites. Vegetation changes occurring from the end of Marine Isotopic Stage 3 to the end of Marine Isotopic Stage 2 (from ~30 to ~18 ka cal. BP) are clearly recorded where other proxies have failed previously, mainly because the scarcity of foraminifers in these sediments prevented any continuous Sea Surface Temperature (SST) record and radiocarbon dating to be obtained. We show also that the use of palynology in turbidite deposits is able to contribute to oceanographical and sedimentological purposes: (1) Pinus pollen grains can document the timing of sea-level rise, (2) the ratio between pollen grains transported from the continent via rivers and dinoflagellate cysts (elutriating) allows us to distinguish clearly detrital sediments from pelagic clays. Finally, taken together, all these tools show evidence that the Rhône River disconnected from the canyon during the sea-level rise and thus evidence the subsequent rapid starvation of the neofan at 18.5 ka cal. BP. Younger sediments are hemipelagic: the frequency of foraminifers allowed to date sediments with radiocarbon. First results of Sea Surface Temperature obtained on foraminifers are in good agreement with the dinoflagellate cysts climatic signal. Both provide information on the end of the deglaciation and the Holocene.

Late Glacial and Holocene data from sediment cores MD99-2236 and MD99-2256

The Laurentide Ice Sheet (LIS) was a large, dynamic ice sheet in the early Holocene. The glacial events through Hudson Strait leading to its eventual demise are recorded in the well-dated Labrador shelf core, MD99-2236 from the Cartwright Saddle. We develop a detailed history of the timing of ice-sheet discharge events from the Hudson Strait outlet of the LIS during the Holocene using high-resolution detrital carbonate, ice rafted detritus (IRD), d18O, and sediment color data. Eight detrital carbonate peaks (DCPs) associated with IRD peaks and light oxygen isotope events punctuate the MD99-2236 record between 11.5 and 8.0 ka. We use the stratigraphy of the DCPs developed from MD99-2236 to select the appropriate DeltaR to calibrate the ages of recorded glacial events in Hudson Bay and Hudson Strait such that they match the DCPs in MD99-2236. We associate the eight DCPs with H0, Gold Cove advance, Noble Inlet advance, initial retreat of the Hudson Strait ice stream (HSIS) from Hudson Strait, opening of the Tyrrell Sea, and drainage of glacial lakes Agassiz and Ojibway. The opening of Foxe Channel and retreat of glacial ice from Foxe Basin are represented by a shoulder in the carbonate data. DeltaR of 350 years applied to the radiocarbon ages constraining glacial events H0 through the opening of the Tyrell Sea provided the best match with the MD99-2236 DCPs; DeltaR values and ages from the literature are used for the younger events. A very close age match was achieved between the 8.2 ka cold event in the Greenland ice cores, DCP7 (8.15 ka BP), and the drainage of glacial lakes Agassiz and Ojibway. Our stratigraphic comparison between the DCPs in MD99-2236 and the calibrated ages of Hudson Strait/Bay deglacial events shows that the retreat of the HSIS, the opening of the Tyrell Sea, and the catastrophic drainage of glacial lakes Agassiz and Ojibway at 8.2 ka are separate events that have been combined in previous estimates of the timing of the 8.2 ka event from marine records. SW Iceland shelf core MD99-2256 documents freshwater entrainment into the subpolar gyre from the Hudson Strait outlet via the Labrador, North Atlantic, and Irminger currents. The timing of freshwater release from the LIS Hudson Strait outlet in MD99-2236 matches evidence for freshwater forcing and LIS icebergs carrying foreign minerals to the SW Iceland shelf between 11.5 and 8.2 ka. The congruency of these records supports the conclusion of the entrainment of freshwater from the retreat of the LIS through Hudson Strait into the subpolar gyre and provides specific time periods when pulses of LIS freshwater were present to influence climate.

(Table 1) Age determination of North Atlantic sediment cores

High-resolution sediment cores from the Vøring Plateau, the North Iceland shelf, and the East Greenland shelf have been studied to investigate the stability of major surface currents in the Nordic Seas during the Holocene. Results from diatom assemblages and reconstructed sea-surface temperatures (SSTs) indicate a division of the Holocene into three periods: the Holocene Climate Optimum (9500-6500 calendar (cal) years BP), the Holocene Transition Period (6500-3000 cal years BP) and the Cool Late Holocene Period (3000-0 cal years BP). The overall climate development is in step with the decreasing insolation on the Northern Hemisphere, but regional differences occur regarding both timing and magnitude of SST changes. Sites under the direct influence of the Norwegian Atlantic Current and the Irminger Current indicate SST cooling of 4-5°C from early Holocene to present, compared to 2°C recorded under the East Greenland Current. Superimposed on the general Holocene cooling trend, there is a high-frequency SST variability, which is in the order of 1-1.5°C for the Vøring Plateau and the East Greenland shelf and 2.5-3°C on the North Iceland shelf.

(Table 1) Age determination of sediment core MD01-2404

We analyzed the high-resolution foraminifer isotope records, total organic carbon (TOC), and opal content from an Okinawa Trough core MD012404 in order to estimate the monsoon hydrography and productivity changes in the East China Sea (ECS) of the tropical western Pacific over the past 100,000 years. The variability shown in the records on orbital time scales indicates that high TOC intervals coincide with the increases of boreal May-September insolation driven by precession cycles (~21 ka), implying a strong connection to the variations in monsoons. We also observed possibly nearly synchronous, millennial-scale changes of the ECS surface hydrography (mainly driven by salinity changes but also by temperature effects) and productivity coincident with monsoon events in the Hulu/Dongge stalagmite isotope records. We found that increased freshening and high productivity correlate with high monsoon intensity in interstadials. This study suggests that the millennial-scale changes in monsoon hydrography and productivity in the ECS are remarkable and persistent features over the past 100,000 years.

Alkenone and foraminifera records from sediment samples off Namibia

Radiocarbon stratigraphy is an essential tool for high resolution paleoceanographic studies. Age models based on radiocarbon ages of foraminifera are commonly applied to a wide range of geochemical studies, including the investigation of temporal leads and lags. The critical assumption is that temporal coupling between foraminifera and other sediment constituents, including specific molecular organic compounds (biomarkers) of marine phytoplankton, e.g. alkenones, is maintained in the sediments. To test this critical assumption in the Benguela upwelling area, we have determined radiocarbon ages of total C37-C39 alkenones in 20 samples from two gravity cores and three multicorer cores. The cores were retrieved from the continental shelf and slope off Namibia, and samples were taken from Holocene, deglacial and Last Glacial Maximum core sections. The alkenone radiocarbon ages were compared to those of planktic foraminifera, total organic carbon, fatty acids and fine grained carbonates from the same samples. Interestingly, the ages of alkenones were 1000 to 4500 yr older than those of foraminifera in all samples. Such age differences may be the result of different processes: Bioturbation associated with grain size effects, lateral advection of (recycled) material and redeposition of sediment on upper continental slopes due to currents or tidal movement are examples for such processes. Based on the results of this study, the age offsets between foraminifera and alkenones in sediments from the upper continental slope off Namibia most probably do not result from particle-selective bioturbation processes. Resuspension of organic particles in response to tidal movement of bottom waters with velocities up to 25 cm/s recorded near the core sites is the more likely explanation. Our results imply that age control established using radiocarbon measurements of foraminifera may be inadequate for the interpretation of alkenone-based proxy data. Observed temporal leads and lags between foraminifera based data and data derived from alkenone measurements may therefore be secondary signals, i.e. the result of processes associated with particle settling and biological activity.

(Table 1) Age determination of sediment core KY07-04-PC1

Variations in Mg/Ca-based sea surface temperature and oxygen isotope ratio (d18O) of the surface water in the northern East China Sea (ECS) were reconstructed with high resolution during the last 18 kyr using planktic foraminifera. Millennial-scale variations between warmer, more saline surface water and cooler, less saline surface water were recognized during the early deglacial period and the Holocene, suggesting changes in the mixing ratio between the Kuroshio Water and the Changjiang Diluted Water. Stronger East Asian summer monsoon (EASM) precipitation events in south China are identified at 10.5, 8.8, 7.0, 5.3, 4.7, 2.9, 1.7, and 0.5 ka, based on sea surface salinity (SSS) records of the northern ECS. Weaker EASM precipitation events are also detected at 9.3, 8.3, 7.3, 6.0, 3.3, 2.3, 0.7, and 0.4 ka during the Holocene. These events agree with the maxima in d18O records of stalagmites from various parts of the Changjiang (Yangtze) River drainage. This agreement supports that our SSS record properly captures the millennial-scale dry (less EASM precipitation) events over the drainage basin of the Changjiang River during the Holocene. These dry events are also in good agreement with North Atlantic ice-rafted events, suggesting a teleconnection between North Atlantic climate and the EASM during the Holocene.

Biogenic opal, carbonat concentrations and stable oxygen isotope ratios of foraminifera from sediment cores of the Southern Ocean

We present records of biogenic opal percentage and burial rate in 12 piston cores from the Atlantic and Indian sectors of the Southern Ocean. These records provide a detailed, quantitative description of changing patterns of opal deposition over the last 450 kyr. The striking regional coherence of these records suggests that dissolution in the deep sea and sediment pore waters does not obscure the surface productivity signal, and therefore these opal time series can be used in combination with other surface water tracers to make inferences about the chemistry and circulation of the Southern Ocean under different global climate conditions. Three broad depositional patterns can be distinguished. Northernmost records (39°-42°S latitude) are characterized by enhanced opal burial during glacial periods and strong 41 kyr periodicity. Records from cores just north of the present Antarctic Polar Front (46°-49°S) show even larger increases in opal burial rate during glacial intervals, but have variance concentrated in the 100 and 23 kyr bands. Southernmost records (51°-55°S) are completely out of phase with those to the north, with greatly reduced opal burial rates during glacial periods. Taken as a whole, the opal records show no evidence for the increased total Antarctic productivity predicted by recent geochemical models of atmospheric CO2 variability. The areal expansion of Southern Ocean sea ice over the present zone of high siliceous productivity provides one plausible explanation for the glacial-interglacial opal patterns. The excess silica not taken up in this zone during glacial periods would contribute to greater nutrient availability and thus higher productivity in the subantarctic region. However, local circulation changes may act to modify this basic signal, possibly accounting for the observed differences in the opal variance spectra.

(Table 3) Age determination of sediment cores from the SW Pacific Ocean

Eight- to ten-point depth profiles (from 1200 to 4800 m water depth) of oxygen and carbon isotopic values derived from benthic foraminifera, averaged over selected times in the past 160 ka, are presented. The data are from 10 sediment cores off eastern New Zealand, mainly North Chatham Rise. This lies under the Deep Western Boundary Current in the Southwest Pacific and is the main point of entry for several water masses into the Pacific Ocean. The benthic isotopic profiles are related to the structure of water masses at present and inferred for the past. These have retained a constant structure of Lower Circumpolar Deep Water-Upper Circumpolar Deep Water/North Pacific Deep Water-Antarctic Intermediate Water with no apparent changes in the depths of water mass boundaries between glacial and interglacial states. Sortable silt particle size data for four cores are also examined to show that the vigour of the inflow to the Pacific, while variable, appears to have remained fairly constant on average. Among the lowest Last Glacial Maximum values of benthic d13C in the world ocean (-1.03 per mil based on Cibicidoides wüllerstorfi) occurs here at ~2200 m. Comparable values occur in the Atlantic sector of the Southern Ocean, while those from the rest of the Pacific are distinctly higher, confirming that the Southern Ocean was the source for the unventilated/nutrient-enriched water seen here. Oxygen and carbon isotopic data are compatible with a glacial cold deep water mass of high salinity, but lower nutrient content (or better ventilated), below ~3500 m depth. This contrasts with the South Atlantic where unventilated/nutrient-enriched water extends all the way to the sea bed. Comparison with previous studies also suggests that the deeper reaches of the Antarctic Circumpolar Current below ~3500 m are not homogeneous all around the Southern Ocean, with the Kerguelen Plateau and/or the Macquarie-Balleny Ridges posing barriers to the eastward spread of the deepest low-d13C water out of the South Atlantic in glacials. These barriers, combined with inferred high density of bottom waters, restricted inter-basin exchange and allow three glacial domains dominated by bottom waters from Weddell Sea, Adelie Coast and Ross Sea to be defined. We suggest that the Ross Sea was the main source of the deep water entering the Pacific below ~3500 m.

(Table 2) Age determination of Florida Straits sediment cores

The waters passing through the Florida Straits today reflect both the western portion of the wind-driven subtropical gyre and the northward flow of the upper waters which cross the equator, compensating North Atlantic Deep Water export as part of the large-scale Atlantic meridional overturning circulation. It has been postulated from various lines of evidence that the overturning circulation was weaker during the Younger Dryas cold event of the last deglaciation. We show here that the contrast in the oxygen isotopic composition of benthic foraminiferal tests across the Florida Current is reduced during the Younger Dryas. This most likely reflects a decrease in the density gradient across the channel and a decrease in the vertical shear of the Florida Current. This reduced shear is consistent with the postulated reduction in the Atlantic meridional overturning circulation. We find that the onset of this change in density structure and flow at the start of the Younger Dryas is very abrupt, occurring in less than 70 years.

(Table 2) Age determination of sediment cores from the continental shelf of Mac Roberston Land, East Antarctica

Geochemical records are presented for five sediment cores from basins on the continental shelf of Mac. Robertson Land, East Antarctica. The cores contain 2-4 m thick sequences of hemipelagic, siliceous mud and ooze (SMO) deposited under seasonally open marine conditions. The inner and middle shelf SMO sequences are massive dark olive green material, whereas the outer shelf SMO sequences are dark olive material interspersed with light olive green layers ~1-10 cm thick. The biogenic material is dominated by marine diatoms including Fragilariopsis curta, Fragilariopsis cylindrus, and Chaetoceros spp. in the dark-colored SMO and Corethron criophilum in the light-colored layers. Radiocarbon dates suggest that the cores provide continuous accumulation records extending from < 1 kyr before present (B.P.) back as far as 4-15 kyr B.P., with estimated accumulation rates of 0.07-5 mm/yr. The three core records from the middle and outer shelf suggest six episodes of increased accumulation of biogenic material at ~5.5 kyr B.P. (all three cores), 1, 2, and 6.2 kyr B.P. (two of the three cores), and 3.8 and 10.8 kyr B.P. (one core), most of which coincide with Corethron layers. We interpret these features as the result of enhanced diatom production over the outer shelf, possibly related to climatic warm periods. The absence of such features in the inner shelf core records is thought to reflect a relatively constant level of seasonal diatom production in adjacent waters maintained by a coastal polynya.