Chemical composition of rocks and minerals from the Karymsky volcanic center, Eastern Kamchatka

The powerful eruption in the Akademii Nauk caldera on January 2, 1996 marked a new activity phase of the Karymsky volcano and became a noticeable event in the history of modern volcanism in Kamchatka. The paper reports data obtained by studying more than 200 glassy melt inclusions in phenocrysts of olivine (Fo82-72), plagioclase (An92-73), and clinopyroxene (Mg# 83-70) in basalts of the 1996 eruption. The data were used to estimate composition of the parental melt and physicochemical parameters of the magma evolution. According to our data, the parental melt corresponded to low magnesium, high aluminum basalt (SiO2 = 50.2%, MgO = 5.6%, Al2O3 = 17%) of the mildly potassium type (K2O = 0.56%) and contained much dissolved volatile components (H2O = 2.8%, S = 0.17%, and Cl = 0.11%). Melt inclusions in the minerals are similar in chemical composition, a fact testifying that the minerals crystallized simultaneously with one another. Their crystallization started at pressure ~1.5 kbar, proceeded within a narrow temperature range of 1040+/-20°C, and continued until near-surface pressure ~100 bar was reached. Degree of crystallization of the parental melt during its eruption was close to 55%. Massive crystallization was triggered by H2O degassing under pressure <1 kbar. Magma degassing in an open system resulted in escape of 82% H2O, 93% S, and 24% Cl (of their initial contents in the parental melt) to the fluid phase. Release of volatile compounds to the atmosphere during the eruption that lasted for 18 h was estimated as 1.7x10**6 t H2O, 1.4x10**5 t S, and 1.5x10**4 t Cl. Concentrations of most incompatible trace elements in the melt inclusions are close to those in the rocks and to the expected fractional differentiation trend. Melt inclusions in plagioclase were found to be selectively enriched in Li. The Li-enriched plagioclase with melt inclusions thought to originate from cumulate layers in the feeding system beneath Karymsky volcano, in which plagioclase interacted with Li-rich melts/brines and was subsequently entrapped and entrained by the magma during the 1996 eruption.

(Table 1) Composition of magmatic rocks from the Iceland-Faeroe Rise

Devoted to composition of magmatic rocks from the Iceland-Faeroe Rise and their origin.

Dinoflagellates and pollen of the Brito-Arctic Igneous Province flora, ODP Hole 104-642E

Palynological studies of the intrabasaltic sediment layers in the lower volcanic series from ODP Leg 104 outer Voring Plateau Hole 642E Cores 102 through 109 indicated abundant pollen and rarer dinoflagellate cysts. The dinoflagellates belong to the Apectodinium hyperacanthum Zone and indicate an age equivalent to nannoplankton Zones NP9-lower NP10 around the Paleocene/Eocene boundary. The pollen and spore assemblage found here in 12 of the samples from the lower volcanic series is of well- preserved and distinctive specimens and contains unusual forms of pollen from the Taxodiaceae and the Hamamelidae. It has not been transported far from vegetation that was dominated by conifer forest with some ferns and deciduous arborescent angiosperms. Nearly identical assemblages are found elsewhere in the Brito-Arctic Igneous Province, in intrabasaltic sediments from eastern Greenland, the Faeroe Islands, the Isle of Mull, and Antrim (Northern Ireland), and above basalt at the Rockall Plateau. The assemblage is also present in sediments around the Paleocene/Eocene boundary in Spitsbergen. This pollen and spore flora is also associated with dinoflagellate cysts of the Apectodinium hyperacanthum Zone in the deposits from eastern Greenland, the Rockall Plateau, and Spitsbergen, suggesting that these are correlative. Assemblages of the same age from the North Sea, Denmark, and the London and Paris Basins are different. Paleobotanical evidence suggests a short survival of the intrabasaltic flora, and that all the deposits considered here are of about the same age. We propose that at around the Paleocene/Eocene boundary a distinct flora, named here as the Brito-Arctic Igneous Province (BIP) flora, occurred on the line of volcanicity stretching from Rockall to the Greenland Sea, and even to Spitsbergen. Geophysical evidence supports our view that the Rockall to East Greenland intrabasaltics are more or less contemporaneous, at about the Paleocene/Eocene boundary. However, the comparable pollen and spore assemblage in the Hebridean province, at Mull and Antrim, is from pyroclastics that may be a little older.

Petrology, mineralogy, and chemistry of basaltic rocks at DSDP Leg 81 Holes

We detail the petrography and mineralogy of 145 basaltic rocks from the top, middle, and base of flow units identified on shipboard along with associated pyroclastic samples. Our account includes representative electron microprobe analyses of primary and secondary minerals; 28 whole-rock major-oxide analyses; 135 whole-rock analyses each for 21 trace elements; 7 whole-rock rare-earth analyses; and 77 whole-rock X-ray-diffraction analyses. These data show generally similar petrography, mineralogy, and chemistry for the basalts from all four sites; they are typically subalkaline and consanguineous with limited evolution along the tholeiite trend. Limited fractionation is indicated by immobile trace elements; some xenocrystic incorporation from more basic material also occurred. Secondary alteration products indicate early subaerial weathering followed by prolonged interaction with seawater, most likely below 150°C at Holes 552, 553A, and 554A. At Hole 555, greenschist alteration affected the deepest rocks (olivine-dolerite) penetrated, at 250-300°C.