ILPES: nuevas bases de trabajo y síntesis de actividades 1986-1987 = ILPES: new operational bases, and summary of activities 1986-1987

Presenta los principales lineamientos para el trabajo que el ILPES debera desempenar en el proximo bienio, asi como un resumen de las actividades realizadas en 1986-1987.

Bases para el desarrollo de la industria de bienes de capital en un marco de cooperación regional

Discute las actividades de las instituciones vinculadas al sector de bienes de capital participantes en la reunion, con el fin de coordinar los trabajos futuros, aprovechar los recursos reciprocos y concertar esfuerzos convergentes a la preparacion de las reuniones intergubernamentales que se consideren pertinentes.

Silver(I) complexes with symmetrical Schiff bases: Synthesis, structural characterization, DFT studies and antimycobacterial assays

Synthesis, structural and spectroscopic characterizations, molecular modeling and antimycobacterial assays of new silver(I) complexes with two Schiff bases - MBDA and MBDB - are reported. The complexes [Ag(MBDA) 2]NO3, or AgMBDA, and [Ag(MBDB)NO3] or AgMBDB, were obtained by the reaction of the respective ligands with silver(I) nitrate in methanol. The Schiff bases were previously obtained by mixing ethylenediamine or 1,3-diaminopropane with p-anisaldehyde. The characterizations of the complexes were based on elemental (C, H and N) and thermal (TG-DTA) analyses and 13C and 1H NMR and FT-IR spectroscopic measurements, as well as X-ray structure determination for AgMBDA. Spectroscopic data predicted by DFT calculations are in agreement with the experimental data for the AgMBDA complex. The AgMBDA complex has a monomeric structure with a molar proportion 1:2 Ag/ligand, while AgMBDB presents a 1:1 proportion. The complexes AgMBDA and AgMBDB showed to be more effective against Mycobacterium tuberculosis than antibacterial agent silver sulfadiazine - SSD. © 2013 Elsevier Ltd. All rights reserved.