Preparation of polyacrylonitrile–natural polymer composite precursors for carbon fiber using ionic liquid co solvent solutions

We report on the use of ionic liquid co-solvents in the preparation of polyacrylonitrile–natural polymer carbon fibers as low cost environmentally friendly alternatives to conventional carbon fibers precursors and processing solvents. We have characterized the structure properties of the new composites as a function of dissolving solvent using solid state NMR, DSC, FTIR and TGA. We show that the dissolving solvent plays a significant role in the properties of the new composites, we also find that the incorporation of the natural polymer additive impacts the thermal transition temperatures for the PAN

Effect of genotype and sex on fiber growth rate of alpacas for their first year of fleece production

The sale of alpaca fiber is the main income for thousands of families in the Central Andes of Peru. Little information exists on the fiber length growth rate of alpaca (FLG), especially throughout their first year of life when the fiber is most valuable. We aimed to determine the monthly FLG of 22 alpaca offspring of two genotypes (9 Suri, 13 Huacaya) and considering sex differences (10 females, 12 males) in the High Andes of Peru. FLG growth was determined using dye-bands. An additive lineal model with three factors (genotype, sex, month) was used for statistic analysis. To evaluate the effect of genotype and sex on the profile of the FLG throughout the year a two factor repeated-measures model was used. The results showed that FLG was affected by genotype and month but not sex. The Suri genotype had 20% higher FLG than Huacaya genotype alpacas (1.34 vs 1.10 cm/month, P < 0.001). FLG increased over each of the first three months (P < 0.05) and then maintained a near constant rate for the remainder of the first year. The resulting staple length indicates that shearing at ages from 8 to 12 months of age will provide fleeces of sufficient length for textile processing.

Gamma-irradiated carbon nanotube yarn as substrate for high-performance fiber supercapacitors

As an electrical double layer capacitor, dry-spun carbon nanotube yarn possesses relatively low specific capacitance. This can be significantly increased as a result of the pseudocapacitance of functional groups on the carbon nanotubes developed by oxidation using a gamma irradiation treatment in the presence of air. When coated with high-performance polyaniline nanowires, the gamma-irradiated carbon nanotube yarn acts as a high-strength reinforcement and a high-efficiency current collector in two-ply yarn supercapacitors for transporting charges generated along the long electrodes. The resulting supercapacitors demonstrate excellent electrochemical performance, cycle stability, and resistance to folding-unfolding that are required in wearable electronic textiles.

Associations between the physiological basis of fabric-evoked prickle, fiber and yarn characteristics and the Wool ComfortMeter value

The association between the incidents counted by the measurement wire of the Wool ComfortMeter (WCM) and the previously published neurophysiological basis for fabric-evoked prickle have been investigated for lightweight knitted woolen fabrics. The fiber lengths and diameters capable of triggering the fabric-evoked prickle sensation were calculated using Euler’s buckling formula, and it is suggested that fibers as fine as 10 mm are capable of triggering the prickle response if they have a short enough free length protruding from the surface. Good agreement was found between the sensory assessed human prickle sensation and the wearer prickle response predicted using the WCM outputs, especially when the latter were transformed using Stevens’s Psychophysical Power Law.

Properties of bio-based polymer nylon 11 reinforced with short carbon fiber composites

In this work, micro-composite materials were produced by incorporating 3-mm long reclaimed short carbon fibers into bio-based nylon 11 via melt compounding. A systematic fiber length distribution analysis was performed after the masterbatching, compounding and an injection moulding processes using optical microscopy images. It was found that the large majority of the fibers were within the 200-300 μm in length range after the injection moulding process. The mechanical (flexural and tensile), thermo-mechanical, and creep properties of the injection moulded materials are reported. We found that an enhancement in flexural and Young's modulus of 25% and 14%, respectively, could be attained with 2 wt% carbon fiber loading whilst no significant drawback on the ductility and toughness of the matrix was observed. The creep resistance and recovery of the nylon 11, tested using dynamic mechanical thermal analysis at room temperature and 65°C, was significantly improved by up to 30% and 14%, respectively, after loading with carbon fiber. This work provides an insight into the property improvement of the bio-based polymer nylon 11 using a small amount of a reclaimed engineered material. © 2014 Society of Plastics Engineers.

Reflectance response of tapered optical fiber coated with graphene oxide nanostructured thin film for aqueous ethanol sensing

In this work, optical sensing performance of tapered multimode fiber tip coated with graphene oxide (GO) nanostructured thin film towards aqueous ethanol with different concentrations is investigated. The tapering process of the optical fiber is done by a glass processing machine. The multimode optical fiber tip is dip-coated with GO and annealed at 70 °C to enhance the binding of the nanomaterials to the silica fiber. FESEM, Raman microscopy and XRD analyses are performed to micro-characterize the GO thin films. The morphology of the GO is observed to be in sheets forms. The reflectance response of the GO coated fiber tip is compared with the uncoated tip. The measurements are taken using a spectrophotometer in the optical wavelength range of 550-720 nm. The reflectance response of the GO coated fiber tip reduced proportionally, upon exposure to ethanol with concentration range of 5-80%. The dynamic response of the developed sensor showed strong reversibility and repeatability when it is exposed to ethanol with concentrations of 5%, 20% and 40% in distilled water. At room temperature, the sensor shows fast response and recovery as low as 19 and 25 s, respectively. © 2014 Elsevier B.V.

Identify kinetic features of fibers growing, branching, and bundling in microstructure engineering of crystalline fiber network

Fibers growing, branching, and bundling are essential for the development of crystalline fiber networks of molecular gels. In this work, for two typical crystalline fiber networks, i.e. the network of spherulitic domains and the interconnected fibers network, related kinetic information is obtained using dynamic rheological measurements and analysis in terms of the Avrami theory. In combination with microstructure characterizations, we establish the correlation of the Avrami derived kinetic parameter not only with the nucleation nature and growth dimensionality of fibers and branches, but also with the fiber bundles induced by fiber-fiber interactions. Our study highlights the advantage of simple dynamic rheological measurements over other spectroscopic methods used in previous studies for providing more kinetic information on fiber-fiber interactions, enabling the Avrami analyses to extract distinct kinetic features not only for fibers growing and branching, but also for bundling in the creation of strong interconnected fibers networks. This work may be helpful for the implementation of precise kinetic control of crystalline fiber network formations for achieving desirable microstructures and rheological properties for advanced applications of gel materials. This journal is © the Partner Organisations 2014.

Effects of variation in wool fiber curvature and yarn hairiness on sensorial assessment of knitted fabrics

Previous investigations have shown that prickle discomfort sensations of wool fabrics are primarily determined by the mean fiber diameter of the wool. It is also known that differences in wool fiber curvature (crimp) affect softness of handle of greasy wool and of wool textiles. In a replicated experiment, we investigated if wearers could detect the effect of using 17 µm superfine wool of low (74°/mm) or high (114°/mm) fiber curvature, and when the wools were blended with 17 µm cashmere (fiber curvature 49°/mm) in differing proportions, on four comfort sensations. Eight single jersey knitted fabrics were assessed under a controlled protocol using forearm sleeves made of the test fabric and a control fabric. Data (37 sensorial assessments of high curvature wool fabrics; 38 sensorial assessments of low curvature wool fabrics) were analyzed using linear mixed model analysis (restricted maximum likelihood), which included fixed effects for wool type and blend ratio and a random effect for participant. The use of a control sleeve fabric reduced variance due to participant effects by providing an anchor for each sensation over time. Wool fiber curvature affected participant assessment of breathability, comfort, feel after exercise (damp/dry) and skin feel (prickly/soft), with preferred values associated with high curvature (crimp) superfine wool. Increasing the proportion of cashmere in fabrics increased skin feel (better assessed softness). Skin feel was strongly associated with the evaluation of the fabrics by the Wool ComfortMeter and with increasing hairiness of yarns.

The influence of fiber diameter, fabric attributes and environmental conditions on wetness sensations of next-to-skin knitwear

This study investigated the relationships between the sensations of sweaty, damp, muggy and clingy, as assessed by human response from wearer trial garment assessment, and fiber type, fiber, yarn and fabric properties and instrumental fabric measurements of next-to-skin knitwear. Wearer trial assessment of 48 fabrics followed a strict 60 minute protocol including a range of environmental conditions and levels of exercise. Adjusted mean weighted scores were determined using linked garments. Instrumental fabric handle measurements were determined with the Wool HandleMeter (WHM) and Wool ComfortMeter. Data were analyzed using forward stepwise general linear modeling. Mean fiber diameter (MFD) affected the sweaty, damp, muggy and clingy sensation responses accounting for between 23.5% and 56.2% of the variance of these sensations. In all cases, finer fibers were associated with lower sensation scores (preferred). There were also effects of fiber type upon sweaty, muggy and clingy scores, with polyester fiber fabrics having higher scores (less preferred) compared with fabrics composed of wool, particularly for peak sweaty scores in hot and active environments. Attributes such as fabric density, yarn linear density, knitting structure and finishing treatments, but not fabric thickness, accounted for some further variance in these attributes once MFD had been taken into account. This is explained as finer fibers have a greater surface area for any given mass of fiber and so finer fibers can act as a more effective sink for moisture compared with coarser fibers. No fabric handle parameter or other attribute of fiber diameter distribution was significant in affecting these sensation scores.

Nerve guidance conduits from aligned nanofibers: improvement of nerve regeneration through longitudinal nanogrooves on a fiber surface

A novel fibrous conduit consisting of well-aligned nanofibers with longitudinal nanogrooves on the fiber surface was prepared by electrospinning and was subjected to an in vivo nerve regeneration study on rats using a sciatic nerve injury model. For comparison, a fibrous conduit having a similar fiber alignment structure without surface groove and an autograft were also conducted in the same test. The electrophysiological, walking track, gastrocnemius muscle, triple-immunofluorescence, and immunohistological analyses indicated that grooved fibers effectively improved sciatic nerve regeneration. This is mainly attributed to the highly ordered secondary structure formed by surface grooves and an increase in the specific surface area. Fibrous conduits made of longitudinally aligned nanofibers with longitudinal nanogrooves on the fiber surface may offer a new nerve guidance conduit for peripheral nerve repair and regeneration.

UV protection performance of textiles affected by fiber cross-sectional shape

Abstract
In this study, a model was set up for simulating the effects of varying fiber cross-sectional shapes on ultraviolet protection of fibers. The fiber diameter and fiber type were also involved in the model setting. Experiments of diffuse reflectance spectra measurement on natural (wool, cotton, silk), regenerated (bamboo viscose) and synthetic (polyester, nylon) fibers were conducted to verify the model predicted results. When a more complex shape was assumed as the fiber cross-section for model calculation, the predicted results have a better agreement with the actual results. The effects on ultraviolet absorption from fibers with different cross-sectional shapes were investigated at a single fiber, fiber bundle and yarn levels. With the same material, when the fiber cross-sectional area and the areal coverage of a single fiber were constant, the triangular shape had the lowest ultraviolet transmittance and the highest ultraviolet reflectance for a single fiber and also for a fiber bundle. The difference of fiber cross-sectional shapes was also significant in the ultraviolet protection of a single yarn.

Facile fabrication of superhydrophobic conductive graphite nanoplatelet/vapor-grown carbon fiber/polypropylene composite coatings

The fabrication of superhydrophobic surfaces with mechanical durability is challenging because the surface microstructure is easily damaged. Herein, we report superhydrophobic conductive graphite nanoplatelet (GNP)/vapor-grown carbon fiber (VGCF)/polypropylene (PP) composite coatings with mechanical durability by a hot-pressing method. The as-prepared GNP/VGCF/PP composite coatings showed water contact angle (WCA) above 150° and sliding angle (SA) less than 5°. The superhydrophobicity was improved with the increase of VGCF content in the hybrid GNP and VGCF fillers. The more VGCFs added in the GNP/VGCF/PP composite coating, the higher porosity on the surface was formed. Compared to the GNP/PP and VGCF/PP composite coatings, the GNP and VGCF hybrid fillers exhibited more remarkable synergistic effect on the electrical conductivity of the GNP/VGCF/PP composite coatings. The GNP/VGCF/PP composite coating with GNP:VGCF = 2:1 possessed a sheet resistance of 1 Ω/sq. After abrasion test, the rough microstructure of the GNP/VGCF/PP (2:1) composite coating was mostly restored and the composite coating retained superhydrophobicity, but not for the VGCF/PP composite coating. When the superhydrophobic surface is mechanically damaged with a loss of superhydrophobicity, it can be easily repaired by a simple way with adhesive tapes. Moreover, the oil-fouled composite surface can regenerate superhydrophobicity by wetting the surface with alcohol and subsequently burning off alcohol.