Crescimeno de apatita na superfície da liga Ti-7, 5Mo empregando tratamento higrotérmico

The objective of the present work was to evaluate surface of experimental alloy Ti-7.5Mo after hydrothermal treatment. Ingots were obtained in arc melting furnace under an argon atmosphere and then homogenized under vacuum at 1100ºC for 86.4 ks to eliminate chemical segregation and after cold worked discs were cutting and grinding. For surface treatment, samples were immersed in a container with NaOH aqueous solution 5M, autoclaved, washed with distilled water. Followed, samples were heat treated and they were soaking in 5xSBF to form an apatite layer on the surface. Surfaces were investigated by, scanning electron microscopy, X-Rays powder diffraction, atomic force microscopy and contact angle, in order to evaluate the wettability of the alloy surface. The results were compared with our previous studies using the group of chemical surface treatments and results shows better condition is 120 minutes in the autoclave

Caracterização da liga do sistema binário Ti-15Mo para aplicações biomedicas

As they have excellent mechanical properties, corrosion resistance and biocompatibility, much research has been conducted with respect to biomedical applications of titanium alloys. This work aims to study the experimental system binary alloy Ti-15Mo, in the raw state of fusion and heat treatment after homogenization, solubilization and calcination (simulating conditions employed for nanotube growth) targeting biomedical applications. Samples were obtained by casting the components in an electric arc furnace with inert atmosphere of argon. After obtaining the alloy, it was heat treated at three different heat treatments, namely homogenizing, calcining and simulation solubilization. The phases present were analyzed by X-ray diffraction, optical microscopy and microhardness testing

Variação do estoque de madeira morta em diferentes altitudes de floresta ombrófila densa atlântica

As florestas tropicais são naturalmente amplos reservatórios de carbono devido à alta produtividade e extensão (Malhi et al. 2000). Em termos do ciclo do carbono, o papel das florestas tropicais como fonte ou sumidouro de CO2 tem sido amplamente debatido (Saleska et al. 2003), portanto, estudos sobre a capacidade de estoque de carbono destes ecossistemas são particularmente relevantes para compreendermos a dinâmica do CO2 para o atual ciclo global do carbono e para compreender o potencial desses ecossistemas atuarem como sumidouro ou fontes de CO2. O objetivo do presente estudo foi verificar se a biomassa de madeira morta acima do solo varia com a altitude (5-50m e 50-500m) em uma Floresta Ombrófila Densa (Mata Atlântica) para entender como o estoque de carbono dessa necromassa varia entre os locais, estoque esse que é matéria prima para liberação de CO2 para atmosfera pelo processo de decomposição. Para estimar a necromassa em pé foram consideradas todas as árvores mortas em pé com diâmetro na altura do peito (DAP = 1,3 metros de altura) maior que 4,8 cm (ou PAP > ou igual a 15 cm), de acordo com protocolo proposto pelo RAINFOR (Rede Amazônica de Inventários Florestais). Todas as árvores mortas em pé foram quantificadas e classificadas a partir da verificação do estado de decomposição da casca de cada indivíduo em quatro classes de decomposição, que possuem diferentes densidades de madeira relacionadas ao estágio de decomposição. A biomassa de madeira morta acima do solo variou com a altitude (figura 2). Essa variação foi de 1,14 Mg ha-1 (parcela B, Terras Baixas) a 7,57 Mg ha-1 (parcela J, F.O.D. Submontana). Em relação às fitofisionomias, houve uma variação de 8,40 Mg ha-1 (Terras Baixas) a 18,38 Mg ha-1 (F.O.D. Submontana)

Efeitos indiretos das aranhas Peucetia spp. (Oxyopidae) e Misumenops argenteus (Thomisidae) no sucesso reprodutivo de Trichogoniopsis adenantha (DC) (Asteraceae) e no comportamento das guildas associadas à planta

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Uso de cascas de laranja como adsorvente de contaminantes no tratamento de água

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Rainwater major and trace element contents in Southeastern Brazil: an assessment of a sugar cane region in dry and wet period

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Analisando a possibilidade de um anel ao redor de um satélite

On November 26 th, 2005, Rhea, one of Saturn's moons, is found by Cassini spacecraft approximately at 5.105 km from Saturn. Observations in situ reveal that electrons are depleted in the moon's vicinity. However, Rhea is considered massive enough to retain a thin atmosphere. Assumption was that the atmosphere of Rhea was not composed exclusively of gas, its likely contains solid material that can absorb magnetospheric particles. According to Jones et al. (2008), these particles were in a speci c position so that at the moment of observation the electrons could not be detected. In opposition to this idea there is a group, Tiscareno et al. 2010, Cornell University Library, that underwent intensive search for any material that might be orbiting Rhea using Cassini images, however the could not identify any. Second recommendation made by American researchers and other countries, and accepted by the National Board of Research the Cassini Equinox Mission will continue in orbit around Saturn until 2016.The probe will perform several maneuvers with high inclination to delve into the main ring system, and then enter in Saturn's atmosphere and collide with planet. This research is of great importance because until today no rings were found orbiting satellites. The goal of this work is to analyze the orbital evolution of a set of particles around Rhea disturbance of Saturn, J2 e J4 and check results by the numerical simulations and the possibility of a stable ring orbiting Rhea.

Imagens de satélite na análise da relação entre queimadas, aerossóis atmosféricos e precipitação

The direct and indirect effects of atmospheric aerossols in the amazonic climate have been focus of many published. This work aims to analyze a possible relation among Burns, atmospheric aerossols and precipitation above South America. It uses the avaluable data from the satellites AQUA/TERRA and TRMM and the images furnished by NOAA and GOES. These analysis can provide some explanations about the effects of emission of aerosols by burns on the composition of atmosphere and cloud formation, mainly in Amazon. We use the Aerosol Optical Depth (AOD) from MODIS/TERRA-AQUA, burns index from CPTEC and rain rate from TRMM. The data we use were obtained from 2000 until 2012. The study is divided in two parts. In the first one, it was performed a quantitative analysis between number of burns and aerosols emission. It was identified a great variability in space and time of the AOD on South America. On the north, northeast and center-west, the AOD is significant during the winter period, with peak on August and September. The southeast is affected by aerosols from center-west due to the dynamical transport. In the second part, it was evaluated the relation between AOD and precipitation in a 13-year period. The statistical analysis shows up a negative correlation of 0.72 between August and October, on Legal Amazon. These result indicate an inverse relation between AOD and rain rate. The other months present not significant correlation. These results are in a good agreement with the literature, in which in-situ methods were applied or combined with satellites data. The increasing of aerosols concentration in the atmosphere are reinforced during drier years. It can affect the increasing process of water drops, decreasing the precipitation. We also verified higher values of AOD (0.25 - 0.3) during years with El Niño, than the climatologically average (~0.15 - 0.2), ... (Complete abstract click electronic access below)

Estudo sobre uma turbina a gás instalada em uma refinaria de petróleo

The gas turbine (GT) is known to have: low cost of capital over the amount of energy, high flexibility, high reliability, short delivery time, commissioning and commercial operation at the beginning and quick departure. The gas turbine is also recognized for its superior environmental performance, manifested in air pollution containment and reducing greenhouse gases (Mahi, 1994). Gas turbines in simple cycle mode (SC) have long been used by utilities to limited power generation peak. In addition, manufacturing facilities use gas turbines for power generation units on site, often in combination with the process of heat production, such as hot water and steam process. In recent years, the performance of industrial gas turbines has been improved due to significant investments in research and development, in terms of fuel to electricity conversion efficiency, plant capacity, availability and reliability. The greater availability of energy resources such as natural gas (NG), the significant reduction of capital costs and the introduction of advanced cycles, have also been a success factor for the increased use of gas turbines to load applications base (Poulikas, 2004). Open Cycle Gas Turbine with a greater degree of heat to the atmosphere may alternatively be used to produce additional electricity using a steam cycle, or to compose a cogeneration process. The combined cycle (CC) uses the heat from the gas turbine exhaust gas to increase the power output and increase the overall efficiency of more than 50% second (Najjar, 2001). The initial discovery of these cycles in the commercial power generation market was possible due to the development of the gas turbine. Only from the 1970s that gas turbine inlet temperature and therefore the exhaust gas temperature was sufficiently high to allow a better efficiency in the combined cycle ... (Complete Abstract click electronic access below)

Crescimento de apatita na superfície da liga Ti-25Ta empregando dois tipos de tratamento de superfície: biomimético e deposição de polímero por eletrofiação

Titanium and its alloys has been widely used as materials for metallic biomaterials implants are usually employed to restore the hard tissue function, being used for artificial joints and bones, synthetic plates, crowns, dental implants and screws . Objective of this work was the surface modification of Ti-alloy 25Ta from biomimetic surface treatment of employment and deposition of polymer by electrospinning. The league was obtained from the fusion of the pure elements in the arc furnace with controlled atmosphere. The ingots were subjected to heat treatment, cold forged and sectioned discs with 13 mm diameter and 3 mm thick. Two surface treatments was evaluated, biomimetic and electrospinning with PCL fiber. The biomimetic treatment was performed involving alkaline treatment for three molarities 1.5M, 3M and 5M with immersion in SBF. The electrospinning was performed using PCL polymer alloy surface after the alkali treatment Ti25Ta 1M. For this group the polymer coated surfaces were immersed in calcium phosphate containing solution for immobilization of apatite. The results were compared with previous studies using surface treatment group to verify hydroxyapatite formation on the sample surface and it is concluded that the best condition is biomimetic treatment with 5M alkali treatment and heat treatment at 80 ° C for 72 hours

Incorporação da apatita na superfície da liga Ti30ta empregando tratamento alcalino associado à eletrofiação de fibras de PCL

Pós-graduação em Engenharia Mecânica - FEG

Tomografia da ionosfera a partir do GNSS e técnicas algébricas: estudo de caso para a região brasileira

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Carbono tipo diamante em componentes de implantes dentários: avaliação das propriedades antimicrobianas e de adesão de Escherichia coli

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

A gênese e a distribuição socioespacial das chuvas no município de Ubatuba-SP

This monograph aims to contribute to the understanding and analysis of extreme events and its correlation with anthropogenic actions, in order to understand the levels of human interference in the environment and to identify potential social and environmental damage that such events may result in Ubatuba, located on the northern coast of São Paulo state. Therefore, two strategies were established, on one hand, episodic analysis of extreme weather events, and on the other, the analysis of the impact of atmospheric phenomena in everyday society. In this case we gave greater emphasis to analysis years that had higher total rainfall. In this sense, the research was based on the standard deviation technique and percentages, which supported to characterize the exceptional rainy years, in addition, use of rhythm analysis technique that has helped to identify the active atmospheric systems. From a qualitative point of view, field works were carried out in order to make use of news by the local press and civil defense for years considered extreme (positive standard deviation). From this, it was analyzed how the extreme episodes of rainfall trigger repercussions in geographic space. Also the spatial distribution of rainfall were carried out by means of quantitative analysis of six rain gauges. It was found that the highest occurrences of impacts, are located in the central areas of the city, as well as the highest rainfall totals. In fact, Ubatuba/SP suffers from very high rainfall totals and has a singularity on the climate...

Analise das emissões de CO2 e de energia - simulação com novas tecnologias siderúrgicas

The process of steel production emits a large quantity of greenhouse gases, specifically carbon dioxide (CO2), and the reduction of such emissions is one of the main challenges for the industry in the 21st. Century. To quantify these emissions, the Worldsteel Association (association of the 170 large steel manufacturers of the world) published a methodology (CO2 Emission Data Collection) for calculation and comparison of CO2 emissions among its members. After that, in 2010, this methodology became an ISO (International Organization for Standardization) norm. Today, the calculation of the CO2 emissions in steel making companies follow the ISO 14404-1 for units with blast furnaces and the ISO 14404-2 for units with electric furnaces. In the last years, new technologies were and continue to be developed for the steel making sector aiming at energetic improvements and greenhouse gas reductions (mainly CO2) by the several processes involved in the production of steel. This work had the objective of producing a tool to calculate the CO2 emissions for the steel making sector. An Excel spreadsheet was developed to calculate the emission intensities of CO2 of a steel plant, the Usina Presidente Vargas, of the Companhia Siderúrgica Nacional (CSN). The spreadsheet furnishes results of CO2 emissions and energetic fluxes, and simulates the benefits that some of the new technologies can give to the company. The spreadsheet calculates the emissions in two ways: a) based on the carbon fluxes that enter the unit, and b) based on the emissions of each specific process within the unit (coking, sinterization, blast furnace, among others)