Heat capacity and enthalpy of fusion of penconazole (C13H15C12N3)

Low-temperature heat capacities of penconazole (C13H15Cl2N3) were precisely measured with an automated adiabatic calorimeter over the temperature rang from 78 to 364 K. The sample was observed to melt at 332.38 +/- 0.06 K. The molar enthalpy and entropy of fusion of the compound were determined to be 33580 +/- 11 J mol(-1), 101.03 +/- 0.02 J mol(-1) K-1, respectively. Further research of the melting process for this compound was carried out by means of differential scanning calorimetry (DSC) technique. The result was in agreement with that obtained from the measurements of heat capacities. (C) 2003 Elsevier B.V. All rights reserved.

Low-temperature heat capacity and thermodynamic properties of crystalline 2-chloro-5-trichloromethylpyridine

The low-temperature heat capacities of 2-chloro-5-trichloromethylpyridine were measured with a high-precision automated adiabatic calorimeter in the temperature range from 80 K to 345 K. A solid-liquid phase transition was observed from 318.57 K to 327.44 K with peak temperature 324.67 K; the molar enthalpy and entropy of phase transition, DeltaH(m) and DeltaS(m), were determined to be 14.50 +/-0.02 kJ mol(-1) and 44.66 +/- 0.07 kJ K-1 mol(-1), respectively. The thermal stability was investigated through thermogravimetric analysis (TG). The TG and DTG results reveal that 2-chloro-5-trichloromethylpyridine starts to lose mass at 332 K due to evaporation and completely changes into vapour at 483 K under the present experimental conditions.

长白山地区红松树干呼吸的研究

采用土壤呼吸气室于2003年5～10月测定了长白山阔叶红松林主要树种红松不同径阶不同方位的树干呼吸,同时监测了树干温度和林内温度.结果表明,树干呼吸速率具有明显的季节变化趋势,呈单峰曲线,8月出现最大值,2月呼吸速率最低.树干呼吸速率与树干温度具有显著幂指数关系,同时表现出大径阶树干呼吸速率与温度因子间曲线拟合效果好于小径阶红松.不同径阶树干呼吸速率均呈南面高于北面,并随树干径阶的减小南北面呼吸速率差异降低.不同径阶红松树干平均维持呼吸占总树干呼吸6363%,红松树干径阶越大维持呼吸所占比例越大.依树干径阶大小顺序分别为6676%、7329%和5084%.不同径阶红松树干呼吸Q10值在256～332之间,利用呼吸Q10值分别获得不同径阶树干Rt和Rm的季节变化趋势.因此,当估算生态系统呼吸时应考虑树干不同部位和不同径阶之间的差异.

Structure and oxygen permeability of a dual-phase membrane

The dual-phase membrane of La0.15Sr0.85Ga0.3Fe0.7O3-delta-Ba0.5Sr0.5Fe0.2Co0.8O3-delta (LSGF-BSCF) was prepared successfully. This membrane was characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron probe micro-analyzer (EPMA). This membrane has a dense dual-phase structure: LSGF being the dense body of this membrane and BSCF as another phase running along the LSGF body. This structure is favorable for the oxygen permeation through the membrane. The oxygen permeation test shows that the oxygen permeation flux of LSGF-BSCF membrane (Jo(2) = 0.45 ml/min cm(2), at 915 degreesC) is much higher than that of LSGF membrane (Jo(2) = 0.05 ml/min cm(2)). Thickness dependence of oxygen permeation indicates that the oxygen permeation is controlled by the bulk diffusion. Compared to pure BSCF the dual-phase membrane of LSGF-BSCF is stable in reducing atmosphere. (C) 2003 Elsevier B.V. All rights reserved.

一种高速安全反向代理服务器的设计与实现

安全反向代理服务器架设在真实网页服务器与用户浏览器之间靠近真实服务器的一侧,通过传输层安全协议保障用户与真实服务器之间的通信.作为基于传输层安全协议的虚拟专用网服务器的一个最重要的组成部分,安全反向代理有着极大的商业价值和技术含量.在FreeBSD-6.3的基础上设计并实现了一个与传统TCP/IP并行的TCP/IP跳转表.基于TCP/IP跳转表设计并实现了一种多加速卡调度算法.设计并实现了直接从加速卡队列获取数据包的代理转发协议栈.设计并实现了基于后台真实服务器反馈的负载均衡算法.测试表明,由这些算法和协议栈组成的高速安全反向代理服务器新进连接数达到了国内领先水平.

推求土壤水分运动参数的简单入渗法──Ⅱ.实验验证

预报土壤中水分流动需要的土壤导水特性可通过观测水平土柱的入渗过程来确定，这一观测过程的分析是基于对Richards方程求积分解。土壤水分特征曲线中的参数由观测的水平立柱的特征湿润长度和吸力来确定，非饱和土壤导水率由已确定的特征曲线中的参数和测定的饱和导水率导出。供试土壤有三种，它们的质地从砂壤到粘壤。由这种方法所确定的这三种土壤的水分特征曲线与实测的特征曲线符合良好，所确定的砂壤的非他和导水率与实测值的比较令人满意。利用数值法和积分法分别计算了土壤含水量剖面，计算结果吻合良好，说明了这种方法的合理性。

三工河流域新老绿洲发育度的比较

绿洲是干旱区最重要的景观单元之一。人工绿洲是在干旱条件下经长期人类活动改造而形成的特殊景观。随着人类对绿洲水土资源开发利用程度的不断加强,绿洲呈现出不同的发展阶段。从天然绿洲到人工绿洲,是人类适应和改造干旱区自然环境的历程。在这一人地相互作用的过程中,绿洲显示出明显的发育演化特征。从多学科综合的角度,提出绿洲发育度的概念,并从灌溉体系的建设状况、水资源的利用水平、植被与生态建设、农业发展程度、社会经济水平和绿洲景观结构等7个方面提出了绿洲发育度的评价指标体系,以天山北坡2个人工绿洲为例,从空间上定量比较2个绿洲的发育程度,其中阜康市绿洲发育度高于222团绿洲(阜北农场)。

杀伤血管内皮生长因子受体1阳性细胞的靶向毒素

白喉毒素(diphtheria toxin DT) 是棒状白喉杆菌被茁噬菌体感染后分泌的一种外毒素. 它可以阻断真核细胞的蛋白质合成,杀死细胞. 血管内皮生长因子(VEGF) 的R82A,K84A,H86A突变体可以和肿瘤血管上高表达的VEGF受体1 (VEGFR-1) 特异性结合. 首先从白喉杆菌中提取基因组DNA,扩增出白喉毒素C区、T区基因. 并运用点突变技术,制成VEGF的R82A,K84A,H86A突变体. 利用这个可以和肿瘤血管上特异性受体相结合的VEGF的突变体,代替白喉毒素上的受体结合区,制成了针对VEGFR-1的靶向融合毒素——DT391-mVEGF. 以去除了受体结合区的DT391为阴性对照,细胞实验表明,融合毒素对VEGFR-1阳性的肿瘤细胞有特异性杀伤作用.