Multiphoton ionization and ab initio calculation studies of pyridine-water mixed clusters using time of flight mass spectrometer

Multiphoton ionization of binary mixed clusters (C5H5N)(x)-(H2O)(y) at 532, 355 and 266 nm laser wavelengths has been investigated using TOF mass spectrometer. The experiments showed that almost all the products were protonated ions, At 532 and 355 nm, the products were mainly protonated pyridine clusters (C5H5N)(n)-H+, while at 266 nm, mixed binary cluster ions (C5H5N)(m)- (H2O)(n)-H+ appeared. It was found that the abundance of the [(C5H5N)(3)-H2O-H](+) ions was abnormally high. The calculation indicated that the ion [(C5H5N)(3)-H2O-H](+) is Of a kind of magic number structures with C-3v symmetry. A stepwise reaction mechanism is suggested that photoionization is followed by dissociation. (C) 2001 Elsevier Science B.V. All rights reserved.

红松高生长模型的研究(英文)

高生长模型是定量研究树木生长过程的有效途径,本文应用双曲线方程、Logistic方程、三个参数的Richards方程及四个参数的Richards方程对红松的高生长进行了研究。结果表明四个参数的Richards方程在模拟红松高生长时最为合适,且当其参数取不同的数值时,该方程可转化为其它理论方程。在使用四个参数的Richards方程时,可根据立地条件事先给定树高最大值,这样可使模型更符合实际情况。此外,文中还对一种以固定年龄时实际树高为参数值的模型进行了讨论,该模型对于计算给定树木的高生长将更为有效。

Decay dynamics of excited CS2 and NH3 investigated by femtosecond laser

By using the home-made femtosecond laser system and the time-of-flight mass spectrometer, the decay dynamics of excited carbon disulfide (CS2) and ammonia (NH3) are investigated in real time by pump-probe multiphoton ionization detection. The estimated lifetime constant of the NH3 (A) over tilde (1)A(2)' state (51+/-4 fs) agreed quite well with the literature report. For the first time, the decay lifetime constants of the NH3 (E) over tilde'(1)A(1)' state (937+/-93 fs), the CS2 (a) over tilde (3)A(2) state (153+/-10 fs), and the CS2 Rydberg state [(3)/(2)]6ssigma(g) ((3)Pi(g)) (948+/-23 fs) are obtained.

基于匹配相容性的高效纹理合成

文中提出一种新的基于纹理块操作的纹理合成方法.对于每个纹理块,该方法根据样本纹理生成可与它进行拼接的纹理块邻接集合,并根据多步合成计算时纹理块之间的可拼接性(即匹配相容性)对邻接集合进行优化处理,即舍弃那些在多步操作后会引起匹配冲突的块.这样,合成计算时,可节省大量的关于邻接块之间的相似性度量计算,减少合成过程中的匹配冲突,由此提高纹理合成的效率.其合成质量,可与目前合成质量最好的纹理优化方法相媲美;而在合成速度方面,新方法的时间复杂度基本上是与目标纹理的大小成线性关系的,并经实验表明,新方法能以交互绘制的速度合成1024×1024像素的大纹理,而这是已有合成方法难以达到的.

变水处理与短期遮荫对作物水分利用效率的影响

变水处理与短期遮荫对棉花水分利用效率的影响研究表明 ,在充分供水 -水分胁迫 -复水的变水处理过程中 ,短期遮荫使净光合速率、蒸腾速率、水分利用效率降低 ;光照 -遮荫 -光照期间 ,总的水分利用效率以水分胁迫的最高 ,充分供水的次之 ,复水处理最低 ,其中遮荫 40 %的水分利用效率高于遮荫 75%的处理 .回归分析表明 ,水分利用效率与光合速率表现出极显著正相关 ,两者回归直线的斜率随水分胁迫而增大 ,而水分利用效率与蒸腾速率的关系较弱 ,多数处理两者相关达不到显著水平

辽河三角洲的自然资源与区域开发

辽河三角洲有丰富的地上和地下资源，是农业综合开发和油田建设的重点地区。其区域资源开发以油田、稻田、苇田和虾田开发为核心，在土地利用主要做到全面规划与统筹兼顾；对淡水资源不足的问题要从开源与节流两方面来进行解决；对河口湿地景观生态系统要注意保护，发挥业已建立的自然保护区的功能；对河口湾水产资源更要加强保护与培育。

混凝土薄壳球形水窖结构的优化设计

分析球形水窖空间结构的应力分布情况并进行几何尺寸优化,避免建设者根据经验来确定球形水窖的厚度、构造及混凝土标号,以节省建窖材料,同时防止应力不足而发生破坏。【方法】利用基于ANSYS平台新开发的窖体有限元分析软件,对实际中窖壁厚度为4和11 cm的混凝土薄壳球形水窖进行空间结构应力分析,同时以水窖耗材量最小为目标函数,以许用应力和变形量为约束条件,对其进行几何尺寸优化。【结果】计算得出窖壁厚度为4和11 cm的水窖最大拉应力分别为1 380.00和447.31 kPa,最大压应力分别为5 153.20和1 896.70 kPa;优化出空窖不利工况下容积为20,30和40 m3的球形水窖窖壁最佳厚度,即栗钙土地区分别为0.051,0.061和0.065m,黄土地区分别为0.050,0.059和0.062 m。【结论】经软件优化计算后的球形水窖结构,既能满足强度和刚度的要求,同时也最大限度地节约了材料用量;利用新开发的窖体结构优化分析软件,能够对球形水窖进行空间应力分析与结构优化,可以作为球形水窖设计软件。

螺旋藻的开发及应用前景

综述了螺旋藻的营养价值、保健功效、生产及应用,并展望了开发前景。

人工混交林中杉木、桤木和刺楸细根养分迁移的初步研究

比较分析了杉木 桤木和杉木 刺楸混交林中杉木、桤木和刺楸活细根、死细根的N、P、K含量 .结果表明 ,桤木细根N迁移能力较强 ,刺楸较弱 ,杉木细根N不迁移 ;P在桤木和刺楸细根中迁移能力较强 ,而在杉木细根中基本不迁移 ;3个树种细根脱落前都将K迁移回树体内 .比较分析 2个混交林中活细根N、P、K在树种间的差异 ,发现在杉木 桤木混交林中桤木根部N可能向杉木迁移 ,而在杉木 刺楸混交林中刺楸根部K可能向杉木根部迁移 ,但迁移机制还有待于从根 土界面生态过程进行研究

赤霉素、硫脲处理对黄精根状茎和须根发生的影响

为诱导无芽黄精根状茎产生不定芽,选择不同的化学物质进行诱导处理。结果表明,GA3处理效果明显,选用0.4 mg/L的GA3浸泡25 min对黄精根状茎不定芽的产生和须根生长有明显促进作用,高浓度抑制其生长;1%硫脲浸泡处理对黄精无顶芽根状茎萌发新芽和须根有明显的抑制作用。

生物有机肥对提高土壤肥力及作物品质等综合效果研究

本文阐述了将有机废弃物无害化处理后对土壤、作物、化肥利用率、禽流感防治及对环境的综合效应。

气候变化政治共识的确定性与科学认识的不确定性

<正>2009年12月召开的联合国哥本哈根气候变化会议上围绕如何应对气候变化问题的争论实质上是关于未来发展道路和发展权力的争论。哥本哈根会议再次显示,发达国家通过把对气候变化的科学认识转变为政治共识而在国际气候变化事务中占有更多的话语权。但作为政治共识的气

Quality analysis of herbal medicine products prepared from Herba sarcandrae by capillary electrophoresis with electrochemical detection

A capillary electrophoresis with electrochemical detection(CE-ED) method was developed for the quality analysis of herbal medicine products prepared from the same herb of Herba Sarcandrae: Fufang Caoshanhu tablets, Qingrexiaoyanning capsules, and Xuekang oral liquids. Under the optimal analysis conditions, the low detection limit[1.0x10(-7) mol/L(S/N=3)] and the wide linear range(1.0x10(-7)-1.0x10(-4) mol/L) were obtained for quality standard compound of isofraxidin. The precisions of the peak current and the migration time(as RSDs) for the real sample analysis were 2.0%-2.6%, and 1.2%-1.8% for isofraxidin, respectively.

Crystallization Kinetics of Syndiotactic Polypropylene Studied by Time-Dependent Light Attenuation

Crystallization kinetics of syndiotactic polypropylene ( sPP) was observed by light attenuation measurements. The initial stages of temperature dependent sPP crystallization fall in the range of Rayleigh scattering and Rayleigh-Debye-Gans scattering. Initial time and growth time of crystallization were obtained, and the trend of crystallization temperature dependent linear attenuation coefficient on the radius and the index of the refraction of the spherulite were evaluated.

Photochemical synthesis and self-assembly of gold nanoparticles

Colloidal gold was prepared by UV light irradiation of the mixture of HAuCl4 aqueous solution and poly(vinyl pyrrolidone) (PVP) ethanol solution in the presence of silver ions. The resulting sheet-like nanoparticles were found to self-assemble into nanoflowers by a centrifuging process. The results of control experiments reflected that only suitable size sheet-like nanoparticles could assemble into the flower-like structures. The presence of Ag ions and PVP are essential for the formation process of nanoflowers.