大别（超）包产到户铁岩和阜新火山岩铂族元素斌存规律研究

The platinum-group elements (PGE), including Os, Ir, Ru, Rh, Pt and Pd, axe strongly siderophile and chalcophile. On the basis of melting temperature, the PGE may be divided into two groups: the Ir group (IPGE, >2000°C) consisting of Os, Ir and Ru, and the Pd group (PPGE, <20GO°C) consisting of Rh, Pt and Pd. Because of their unique geochemical properties, PGE provide critical information on global-scale differentiation processes, such as core-mantle segregation, late accretionary history, and core-mantle exchange. In addition, they may be used to identify magma source regions and unravel complex petrogenetic processes including partial melting, melt percolation and metasomatism in the mantle, magma mixing and crustal contamination in magma chambers and melt crystallization.Compared with other rocks, (ultra)mafic rocks have lower REE content but higher PGE content, so PGE have advantages in studying the petrogeneses and evolution of them. In this study, we selected (ultra)mafic rocks collected in Dabie Orogen and volcanic rocks from Fuxin Region. Based on the distribution and behaviour of platinum-group elements, combined with other elements, we speculate the magma evolution and source mantle of these (ultra)mafic rocks and volcanic rocks.Many (ultra)mafic rocks are widely distributed in Dabie Region. According to their deformation and metamorphism, we classed them into three types. One is intrusive (ultra)mafic rocks, which are generally undeformed and show no or little sign of metamorphism, such as (ultra)mafic intrusions in Shacun, zhujiapu, Banzhufan, qingshan, Xiaohekou, Jiaoziyan, Renjiawan and Daoshichong. The other one is ultrahigh pressure metamorphic (ultra)mafic rocks, some of them appeared as eelogites, such as complex in Bixiling and adjacent Maowu. Another one is intense deformed and metamorphic, termed as tectonic slice, alpine-type (ultra)mafic rocks. The most representative is Raobazhai and Dahuapin. However, there are many controversies about the formation of those (ultra)mafic rocks. Here, we select typical rocks of the three types. The PGE were determined by inductively coupled plasma mass spectrometry (ICP-MS) ater NiS fire-assay and tellurium co-precipitation.The PGE tracing shows that three components are needed in the source of the cretaceous (uitra)mafic intrusions. They could be old enriched sub-continental lithospheric mantle, lower crust and depleted asthenospheric mantle. The pattern of PGE also shows the primitive magma of these intrusions underwent S saturation. According to palladium, we can conclude that the mantle enrich in PGE. Distribution of PGE in Bixiiing and Maowu (ultra)mafic rocks display they are products of magmas fractional crystallization. The (ultra)mafic rocks in Bixiiing and Maowu are controlled by various magmatic processes and the source mantle is depleted in PGE. Of interest is that the mantle produced UHP (ultra)mafic rocks are PGE-depleted, whereas the mantle of cretaceous (ultra)mafic intrusions are enrich in PGE. This couldindicate that the mantle change from PGE-enriched to PGE-depleted during120-OOMa, which in accord with the time of tectonic system change in the East China. At the same time, (ultra)mafic intrusions in cretaceous took information of deep mantle, which means the processes in deep mantle arose structural movement in the crust The character of PGE in alpine-type (ultra)mafic rocks declared that the rocks had experienced two types of metasomatic processes - hydrous melt derived from slab and silicate melt. In addition, we analyze the platinum-group elements in volcanic rocks on the northern margin of the North China Craton, Fuxin. The volcanic rocks characterized by negative anomalies of platinum. This indicates that platinum alloys, which may host some Pt resided in the mantle. The PGE patterns also show that Jianguo alkali basalts derived from asthenospheric mantle source, but wulahada high-Mg andesites derived from lithospheric mantle.

利用宽频带台阵资料研究华北地区地壳及上地幔间断面结构

Intense tectonic renovation has occurred in the eastern continent of china since Mesozoic, as evidenced by the high heat flow, widespread magma extrusion and volcanic activities, and development of large sedimentary basins. To explain the cause and mechanism for the tectonic process in this period, some researchers have put forward various models, such as mantle plume, subduction of the Pacific slab, Yangtze Block-North China Block collision, etc. Their seismological evidence, however, is still scarce..During the period from 2000 to 2003, large temporary seismic arrays were established in North China by the Institute of the Geology and Geophysics, Chinese Academy of Sciences. Total 129 portable seismic stations were linearly emplaced across the western and eastern boundaries of the Bohai Bay Basin, and accumulated a large amount of high-quality data. Moreover, abundant data were also collected at the capital digital seismic network established in the ninth five-year period of national economic and social development. These provide an unprecedented opportunity for us to study the deep structure and associated geodynamic mechanism of lithospheric processes in North China using seismological techniques.Seismology is a kind of observation-based science. The development of seismic observations greatly promotes the improvement of seismologic theory and methodology. At the beginning of this thesis, I review the history of seismic observation progress, and present some routine processing techniques used in the array seismology. I also introduce two popular seismic imaging methods (receiver function method and seismic tomography).Receiver function method has been widely used to study the crustal and upper mantle structures, and many relevant research results have been published. In this thesis I elaborate the theory of this method, including the basic concept of receiver functions and the methodology for data pre-processing, stacking and migration. I also address some problems often encountered in practical applications of receiver function imaging.By using the teleseismic data collected at the temporary seismic arrays in North China, in particular, the traveltime information of P-to-S conversion and multiple reverberations of the Moho discontinuity, I obtain the distributions of the crustal thickness and the poisson ratio at the northwest boundary area of the Bohai Bay Basin and discuss the geological implications of the results.Through detailed intestigations on the crustal structural feature around the middle part of the Tanlu fault, considerable disparity in poisson ratios is found in the western and eastern sides of the Tanlu fault. Moreover, an obvious Moho offset is coincidently observed at the same surface location. A reasonable density model for the Tanlu fault area is also derived by simulating the observed gravity variations. Both receiver function study and gravity anomaly modeling suggest that the crustal difference between the western and eastern sides of the Tanlu fault is mainly resulted from their different compositions.With common conversion point imaging of receiver functions, I estimate the depths of the upper and lower boundaries of the mantle transition zone, i.e., the 410 and 660 km discontinuities, beneath most part of the North China continent The thickness of the transition zone (TTZ) in the study area is calculated by subtracting the depth of .410 km discontinuity from that of the 660km discontinuity. The resultant TTZ is 10-15 km larger in the east than in the west of the study area. Phase transitions at the 410 km and the 660 km discontinuities are known to have different Clapeyron slopes. Therefore, the TTZ is sensitive to the temperature changes in the transition zone. Previous studies have shown that the TTZ would be smaller in the mantle plume areas and become larger when the remnants of subducted slabs are present The hypothesis of mantle plume cannot give a reasonable interpretation to the observed TTZ beneath North China, Instead, the receiver function imaging results favor a dynamic model that correlates the thermal structure of the mantle transition zone and associated upper mantle dynamics of North China to the Pacific plate subduction process.

Isotope geochronology of Dapingzhang spilite-keratophyre formation in Yunnan Province and its geological significance

On the basis of the geological field investigations and isotope geochronological studies the Sm-Nd isochron age (513 Ma?0 Ma), Rb-Sr isochron age (511 Ma? Ma) and K-Ar age (312-317 Ma) of the Dapingzhang spilite-keratophyre formation in Yunnan Province are presented. From these geochronological data it is evidenced that this suite of volcanic rocks was formed in the Cambrian and the parent magma was derived from a depleted mantle, which was influenced by crustal contamination and/or seawater hydrothermal

Mantle-derived gaseous components in ore-forming fluids of the Xiangshan uranium

The Xiangshan U deposit, the largest hydrothermal U deposit in China, is hosted in late Jurassic felsic volcanic rocks although the U mineralization post dates the volcanics by at least 20 Ma. The mineralization coincides with intrusion of local mantle-derived mafic dykes formed during Cretaceous crustal extension in South China. Ore-forming fluids are rich in CO2, and U in the fluid is thought to have been dissolved in the form of UO2 (CO3)22− and UO2 (CO3) 34− complexes. This paper provides He and Ar isotope data of fluid inclusions in pyrites and C isotope data of calcites associated with U mineralization (pitchblende) in the Xiangshan U deposit. He isotopic compositions range between 0.1 and 2.0Ra (where Ra is the 3He/4He ratio of air=1.39×10−6) and correlates with 40Ar/36Ar; although there is potential for significant 3He production via 6Li(n,α)3H(β)3He reactions in a U deposit (due to abundant neutrons), nucleogenic production cannot account for either the 3He concentration in these fluids, nor the correlations between He and Ar isotopic compositions. It is more likely that the high 3He/4He ratios represent trapped mantle-derived gases. A mantle origin for the volatiles of Xiangshan is consistent with the δ13C values of calcites, which vary from −3.5‰ to −7.7‰, overlapping the range of mantle CO2. The He, Ar and CO2 characteristics of the ore-forming fluids responsible for the deposit are consistent with mixing between 3He- and CO2-rich mantle-derived fluids and CO2-poor meteoric fluids. These fluids were likely produced during Cretaceous extension and dyke intrusion which permitted mantle-derived CO2 to migrate upward and remobilize U from the acid volcanic source rocks, resulting in the formation of the U deposit. Subsequent decay of U within the fluid inclusions has reduced the 3He/4He ratio, and variations in U/3He result in the range in 3He/4He observed with U/3He ratios in the range 5–17×103 likely corresponding to U concentrations in the fluids b0.2 ppm.

浙江省矾山明矾石矿床地球化学特征兼论中生代成矿体系

矾山明矾石矿床位于江山－绍兴深断裂南东侧，海西印支褶皱带的南东侧，中国板块东南构造区与太平洋板块的交接处，属于中国板块东南构造区。该矿床产在矾山破火山口内，是一个超大型明矾石矿床，同时矿床中的钒、镓含量也达到了综合利用的品位。该矿床研究程度低，缺少地球化学特征研究。因此，本次工作系统研究了该矿床常量元素、微量元素、稀土元素、硫和铅同位素地球化学特征。本次对明矾石矿床的研究获得以下几点初步认识： 1：成矿物质来源于火山岩。矿区火山岩中的K、Al、Na等矿石元素含量明显比其他地区高，并且从围岩→矿化围岩→矿石呈明显的富集趋势。稀土资料和铅同位素资料也都表明成矿物质来源于中生代火山岩。 2：V、Ga含量达到了综合利用的品位。微量元素资料表明，矿石中V平均含量为211.6ppm，Ga平均含量为16.78ppm，都大于地壳丰度，尤其是V远大于地壳丰度；同时发现，成矿时V以V¬5＋形式通过与Al3＋发生类质同像进入明矾石晶格，而矿石中Ga含量除与Al3＋外还与Fe3＋含量有关。 3：明矾石的稀土元素地球化学特征比较复杂。根据δEu值不同可分为三类： Eu弱负异常型，Eu弱正异常型和Eu强正异常型。影响稀土元素分布的因素主要为成矿原岩中富含碱性长石和成矿时的氧逸度和温度，另外矿石结构（如孔隙度）对稀土元素分布也有影响。研究表明，矿石稀土配分模式为轻稀土富集型，与火山岩基本一致。 4：硫同位素研究发现，黄铁矿的δ34S值为1.9～3.2‰，明矾石的δ34S值为13.62～16.02‰，后者明显大于前者。本次研究认为黄铁矿的δ34S值代表当时的岩浆源硫，而明矾石较大的δ34S值为岩浆硫经过同位素分馏的结果。铅同位素研究发现，明矾石矿石的206Pb/204Pb＝17.963～18.606，207Pb/204Pb＝15.439～15.672，208Pb/204Pb＝38.405～38.796。通过与中生代火山岩和基底变质岩的对比，本次研究认为明矾石的铅源为中生代火山岩来源，与基底变质岩并无直接的来源关系。 5：通过明矾石矿床的地球化学特征研究，结合实际地质特征和前人研究成果，本次研究提出了以下矿床成因：明矾石矿床形成环境为浅成低温氧化环境；成矿物质来源于围岩，成矿所需的硫源为分馏的岩浆硫；矿床形成时期为73～95Ma，比围岩晚10～20Ma；矿床成因为火山热液交代成因。 浙江省中生代火山岩成矿体系主要指受浙江省中生代火山构造、岩浆活动控制的一系列不同类型的矿床组合。成矿体系主要受江绍深断裂带和中生代陆相火山岩控制。前人对成矿体系中的单一矿床研究较多，但是缺少横向对比研究。本次工作主要通过对成矿体系中的两类矿床（金属矿床和非金属矿床）进行对比研究，结合中生代火山岩演化过程，初步探索成矿体系中各类矿床间的联系以及成矿体系与火山岩演变的关系。本次工作取得以下几点初步认识： 1：成矿体系中各类矿床的整体分布受江绍深断裂、温州－镇海大断裂等一些深大断裂控制。各矿床的具体控（容）矿构造都为次级压－压扭性断裂和破火山口构造，其中破火山口构造在成矿过程中占非常重要的作用。 2：成矿体系中各类矿床的成矿温度低，深度浅，为典型的浅成低温矿床。 3：铅同位素资料表明，矿床的铅源为中生代火山岩来源，与基底并无直接联系。氢氧同位素资料表明，各类矿床的成矿流体以中生代大气降水为主，岩浆水占很少部分或并无参与成矿。 4：成矿体系存在明显的成矿成岩时差，金属矿床在12.44～45.6Ma，萤石矿床为25～75Ma，其他非金属矿床为10～20Ma；铅锌（银）金等金属矿床为具有明显的两期成矿特征。

吉林金川西大甸子泥炭沉积中火山物质的发现及其意义附：泥炭中胡敏酸的稳定碳同位素值（δ<'13>C）作为古气候代用指标可行性研究

泥炭以发育广泛、连续沉积好、沉积速率大（可达1mm/a甚至更大）、记录丰富等特点,正成为过去全球变化研究的良好综合地质档案.参考冰芯、黄土、深海沉积物等中矿物固体的研究思路和方法,希望能对泥炭中可能存在的火山物质和其它风粉尘进行研究.在对吉林金川西大甸子泥炭样品的处理过程中,摸索出一套泥炭样品中固体物质（如火山物质）初步的处理、分析方法;并对金川西大甸子干玛珥泥炭沉积中部一段泥砂状物质进行鉴定,首次发现火山玻璃,判断这些泥砂物为火山灰砂.目前研究表明,泥炭纤维素的δ<'13>C序列能较好地反映古气候变化,那么泥炭中胡敏酸的δ<'13>C序列可否也能反映古气候变化,该文对此作了初步研究.用碱溶酸沉淀方法从泥炭中提取出所谓的胡敏酸,用燃烧法将胡敏酸、纤维素中的碳转化为CO<,2>气体,测定它们的稳定碳同位素组成（δ<'13>C）.与能较好地反映气候变化的纤维素δ<'13>C序列相比,胡敏酸的δ<'13>C序列反映气候变化不明显.

Structure of glasses and melts

Wilding, M. C., Benmore, C. J. (2006). Structure and Glasses and Melts. reviews in Mineralogy and Geochemistry, 63 (1), 275-311 RAE2008

Sinusite odontogénica

Monografia apresentada à Universidade Fernando Pessoa para obtenção do grau de Licenciada em Medicina Dentária.

Os motivos da não erupção dos terceiros molares

Projeto de Pós-Graduação/Dissertação apresentado à Universidade Fernando Pessoa como parte dos requisitos para obtenção do grau de Mestre em Medicina Dentária

Hydrocarbon Potential of the Infra-salt Strata

This schematic geological cross-section of Angola offshore is representative of the majority of the Atlantic-type divergent margins. It illustrates the main geological features allowing to understand the different petroleum systems occurring, particularly, in South Atlantic divergent margins : (i) Pre-Pangea rocks (Precambrian granite-gneiss basement, volcanic rocks an/ or Paleozoic sediments, more or less, metamorphosed), which lie underneath the pre-rifting unconformity (PRU), in blue in the cross-section ; (ii) The rift-type basins developed during the lengthening of the Pangea supercontinent ; (iii) The breakup unconformity (BUU), which highlight the upper limit of the rift-type basins, in which organic rich lacustrine shales with a parallel internal configuration are potential source-rocks (organic matter type I) ; (iv) The SDRs (seaward dipping reflectors), which, generally, do not have any generating hydrocarbon potential (just 5 m of lacustrine shales are known in Austral basin) ; (v) The BUU is fossilized by SDRs (subaerial volcanism) or by margin infra-salt sediments (forming the mistakenly called by some American geoscientists "sag basin") ; (vi) The Loeme salt basin, which is a twin of the Brazilian salt basin, that is to say, that both basins have always been individualized ; (vii) The transgressive (backstepping) and regressive (forestepping) phases of the post-Pangea continental encroachment cycle ; (v) The interface between these sedimentary phases, correspond to the emplacement of potential marine source-rocks (organic matter type-II) ; (vi) Potential dispersive source rocks (organic matter type III) are possible in the regressive sedimentary interval.

Sintomatologia associada à erupção dentária

Projeto de Pós-Graduação/Dissertação apresentado à Universidade Fernando Pessoa como parte dos requisitos para obtenção do grau de Mestre em Medicina Dentária

Paleoenvironmental reconstruction of the coastal Monte Léon and Santa Cruz formations (Early Miocene) at Rincón del Buque, Southern Patagonia: A revisited locality

© 2015 Elsevier Ltd.Sedimentological, ichnological and paleontological analyses of the Early Miocene uppermost Monte León Formation and the lower part of the Santa Cruz Formation were carried out in Rincón del Buque (RDB), a fossiliferous locality north of Río Coyle in Santa Cruz Province, Patagonia, Argentina. This locality is of special importance because it contains the basal contact between the Monte Léon (MLF) and the Santa Cruz (SCF) formations and because it preserves a rich fossil assemblage of marine invertebrates and marine trace fossils, and terrestrial vertebrates and plants, which has not been extensively studied. A ~90m-thick section of the MLF and the SCF that crops out at RDB was selected for this study. Eleven facies associations (FA) are described, which are, from base to top: subtidal-intertidal deposits with Crassotrea orbignyi and bioturbation of the Skolithos-Cruziana ichnofacies (FA1); tidal creek deposits with terrestrial fossil mammals and Ophiomorpha isp. burrows (FA2); tidal flat deposits with Glossifungites ichnofacies (FA3); deposits of tidal channels (FA4) and tidal sand flats (FA5) both with and impoverish Skolithos ichnofacies associated; marsh deposits (FA6); tidal point bar deposits recording a depauperate mixture of both the Skolithos and Cruziana ichnofacies (FA7); fluvial channel deposits (FA8); fluvial point bar deposits (FA9); floodplain deposits (FA10); and pyroclastic and volcaniclastic deposits of the floodplain where terrestrial fossil mammal remains occur (FA11).The transition of the MLF-SCF at RDB reflects a changing depositional environment from the outer part of an estuary (FA1) through the central (FA2-6) to inner part of a tide-dominated estuary (FA7). Finally a fluvial system occurs with single channels of relatively low energy and low sinuosity enclosed by a broad, low-energy floodplain dominated by partially edaphized ash-fall, sheet-flood, and overbank deposits (FA8-11). Pyroclastic and volcaniclastic materials throughout the succession must have been deposited as ash-fall distal facies in a fluvial setting and also were carried by fluvial streams and redeposited in both estuarine and fluvial settings. These materials preserve most of the analyzed terrestrial fossil mammals that characterize the Santacrucian age of the RDB's succession. Episodic sedimentation under volcanic influence, high sedimentation rates and a relatively warm and seasonal climate are inferred for the MLF and SCF section.Lateral continuity of the marker horizons at RDB serve for correlation with other coastal localities such as the lower part of the coastal SCF south of Río Coyle (~17.6-17.4Ma) belonging to the Estancia La Costa Member of the SCF.

Acid gas hazards in the crater of Villarrica volcano (Chile)

The atmospheric concentrations of the acid gases SO2, HCl, and HF were measured during austral summer 2001 in the summit crater area of Villarrica volcano using 'filter packs'. These data were collected in order to assess the acid gas hazards to tourists who ascend the volcano. The authors compared their acid gas concentration results with exposure limits outlined by the National Institute of Occupational Safety and Health (NIOSH-United States of America). The authors conclude that tourists who visit the summit crater of Villarrica may be exposed to non-lethal concentrations of SO2 and HCl that exceed the recommended exposure limits defined by NIOSH, while atmospheric concentrations of HF do not exceed the recommended exposure limits.

Geochemical and isotopic evidence for seawater contamination of the hydrothermal system of Taal volcano, Luzon, the Philippines

The hydrologic structure of Taal Volcano has favored development of an extensive hydrothermal system whose prominent feature is the acidic Main Crater Lake (pH<3) lying in the center of an active vent complex, which is surrounded by a slightly alkaline caldera lake (Lake Taal). This peculiar situation makes Taal prone to frequent, and sometimes catastrophic, hydrovolcanic eruptions. Fumaroles, hot springs, and lake waters were sampled in 1991, 1992, and 1995 in order to develop a geochemical model for the hydrothermal system. The low-temperature fumarole compositions indicate strong interaction of magmatic vapors with the hydrothermal system under relatively oxidizing conditions. The thermal waters consist of highly, moderately, and weakly mineralized solutions, but none of them corresponds to either water-rock equilibrium or rock dissolution. The concentrated discharges have high Na contents (>3500 mg/kg) and low SO4/Cl ratios (<0.3). The Br/Cl ratio of most samples suggests incorporation of seawater into the hydrothermal system. Water and dissolved sulfate isotopic compositions reveal that the Main Crater Lake and spring discharges are derived from a deep parent fluid (T≃300°C), which is a mixture of seawater, volcanic water, and Lake Taal water. The volcanic end member is probably produced in the magmatic-hydrothermal environment during absorption of high-temperature gases into groundwater. Boiling and mixing of the parent water give rise to the range of chemical and isotopic characteristics observed in the thermal discharges. Incursion of seawater from the coastal region to the central part of the volcano is supported by the low water levels of the lakes and by the fact that Lake Taal was directly connected to the China sea until the sixteenth century. The depth to the seawater-meteoric water interface is calculated to be 80 and 160 m for the Main Crater Lake and Lake Taal, respectively. Additional data are required to infer the hydrologic structure of Taal. Geochemical surveillance of the Main Crater Lake using the SO4/Cl, Na/K, or Mg/Cl ratio cannot be applied straightforwardly due to the presence of seawater in the hydrothermal system.

Modelling high particulate matter and ozone episodes in the Trans-Manche region

There is concern in the Cross-Channel region of Nord-Pas-de-Calais (France) and Kent (Great Britain), regarding the extent of atmospheric pollution detected in the area from emitted gaseous (VOC, NOx, S02)and particulate substances. In particular, the air quality of the Cross-Channel or "Trans-Manche" region is highly affected by the heavily industrial area of Dunkerque, in addition to transportation sources linked to cross-channel traffic in Kent and Calais, posing threats to the environment and human health. In the framework of the cross-border EU Interreg IIIA activity, the joint Anglo-French project, ATTMA, has been commissioned to study Aerosol Transport in the Trans-Manche Atmosphere. Using ground monitoring data from UK and French networks and with the assistance of satellite images the project aims to determine dispersion patterns. and identify sources responsible for the pollutants. The findings of this study will increase awareness and have a bearing on future air quality policy in the region. Public interest is evident by the presence of local authorities on both sides of the English Channel as collaborators. The research is based on pollution transport simulations using (a) Lagrangian Particle Dispersion (LPD) models, (b) an Eulerian Receptor Based model. This paper is concerned with part (a), the LPD Models. Lagrangian Particle Dispersion (LPD) models are often used to numerically simulate the dispersion of a passive tracer in the planetary boundary layer by calculating the Lagrangian trajectories of thousands of notional particles. In this contribution, the project investigated the use of two widely used particle dispersion models: the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model and the model FLEXPART. In both models forward tracking and inverse (or·. receptor-based) modes are possible. Certain distinct pollution episodes have been selected from the monitor database EXPER/PF and from UK monitoring stations, and their likely trajectory predicted using prevailing weather data. Global meteorological datasets were downloaded from the ECMWF MARS archive. Part of the difficulty in identifying pollution sources arises from the fact that much of the pollution outside the monitoring area. For example heightened particulate concentrations are to originate from sand storms in the Sahara, or volcanic activity in Iceland or the Caribbean work identifies such long range influences. The output of the simulations shows that there are notable differences between the formulations of and Hysplit, although both models used the same meteorological data and source input, suggesting that the identification of the primary emissions during air pollution episodes may be rather uncertain.