A novel way to synthesize high regular and periodic organic mesoporous silicas

Organic mesoporous silicas (OMSs) were synthesized in the presence of urea via one-pot synthesis method, in which tetraethyl orthosilicate (TEOS) and 3-aminopropyltriethoxysilica (APTES) were used as the silica resources, non-ionic surfactant was used as the template. XRD results showed that the average periodic mesopore sizes of OMSs in the presence of urea were larger than those in the absence of urea. It was also found that the pore sizes of the products in the presence of urea distributed more narrowly than those in the absence of urea, and the contents of organosiloxane incorporated into OMSs, the pore wall thicknesses, the pore volumes and the surface areas of the products all increased with the use of urea. This shows a novel way to synthesize high regular and periodic organic mesoporous silicas.

Mechanical properties and miscibility of polyethersulfone phenoxy blends

The blends of polyethersulfone and phenoxy were prepared by melt mixing in a Brabender-like apparatus. The specimens for measurements were made by compression molding and then were water-quenched at room temperature under pressure. The tensile strength, tensile modulus, elongation at break and yield, density, thermal analysis, and dynamic mechanical properties were each measured. The dependence of tensile strength, tensile modulus, elongation at break and yield, and density on composition was obtained. The relationship between tensile modulus and elongation at break and yield and speed of the crosshead at different weight ratios of the blends is shown. The effects of composition and miscibility on the mechanical properties are discussed. (C) 1996 John Wiley & Sons, Inc.

(η~5-C_9H_7)_3Ln·OC_4H_8(Ln=Nd、Gd、Er)的合成及晶体结构

合成了三茚基稀土配合物(η~5-C_9H_7)_3Ln·OC_4H_8(Ln=Nd、Gd、Er),经元素分析、红外光谱、水解产物核磁共振谱及质谱表征,并测得了(η~5-C_9H_7)_3Nd·OC_4H_8(1)及(η~5-C_9H_7)_3Gd·OC_4H_8(2)的晶体结构。(1)、(2)均属六方晶系,P6_3空间群,Z=2。(1)的晶体学参数为a=b=1.1843(3)nm,c=1.0304(4)nm,V=1.25165(87)nm~3,D_c=1.49g·cm~(-3),最后一致性因子R=0.049;(2)的晶体学参数a=b=1.1805(2)nm,c=1.0236(2)nm,V=1.23536(56)nm~3,D_c=1.54 g·cm~(-3),R=0.023。平均Nd-C=0.2812nm,Gd-C=0.2795nm;Nd-O=0.2557(21)nm,Gd—O=0.2459(13)nm。配合物中四氢呋喃的四个碳原子处于完全无序状态。

A NEW KIND OF FLOW-THROUGH ELECTROCHEMICAL DETECTOR USING CARBON-FIBER ELECTRODE FOR LIQUID-CHROMATOGRAPHY

An electrochemical detector which was constracted by using a carbon fibre electrode in a flow-through cell was connected with a liquid chromatographic column. Thus a sensitive,

Dibenzyl bromophenols with diverse dimerization patterns from the brown alga Leathesia nana

Six novel dibenzyl bromophenols (1-6) with different dimerization patterns and two propyl bromophenol derivatives (7 and 8), together with 11 known bromophenol derivatives, were isolated from the ethanolic extract of the brown alga Leathesia nana. On the basis of spectroscopic methods the structures of the new compounds were determined as 5,6'-diethyloxymethyl-3,4,2'-tribromo-2,3',4'-trihydroxydiphenyl ether (1), 2-(2,3-dibromo-4,5-dihydroxybenzyl)-3,5-dihydroxy-4-methoxybenzyl alcohol (2), 6-(2,3-dibromo-4,5dihydroxybenzyl)-2,3-dibromo-4,5-dihydroxy benzyl methyl ether (3), 9,10-dihydro-9,10-dimethoxy-3,4,7,8-tetrabromo-1,2,5,6-tetrahydroxyanthracene (4), (+)-3-(2,3-dibromo-4,5-dihydroxyphenyl)-4-bromo-5,6-dihydroxy-1,3-dihydroisobenzofuran (5), rel-(4aS*,10aR*)-(+/-)-6,7-dibromo-4a-hydroxy-3,8-dihydroxymethyl-10a-methoxy- 1,4,4a, 10a-tetrahydrodibenzo[b,e][1,4]dioxin-1-one (6), (E)-2-methyl-3-(2,3-dibromo-4,5-dihydroxyphenyl)propenal (7), and 2-methyl-3-(2,3-dibromo-4,5-dihydroxyphenyl)-1-propanol (8). Some compounds including 3 showed in vitro selective cytotoxicity against several human cancer cell lines. This is the first brown alga to be reported containing bromophenols.

Bromophenols coupled with derivatives of amino acids and nucleosides from the red alga Rhodomela confervoides

Three new bromophenols coupled with pyroglutamic acid derivatives and one bromophenol coupled with deoxyguanosine were obtained from the red alga Rhodomela confervoides. By spectroscopic methods including 2D NMR and single-crystal X-ray structure analysis their structures were elucidated as N-(2,3-dibromo-4,5-dihydroxybenzyl)methyl pyroglutamate (1), N-(2,3-dibromo-4,5-dihydroxybenzyl)pyroglutamic acid (2), N-[3-bromo-2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxybenzyllmethyl pyroglutamate (3), and 2-N-(2,3-dibromo-4,5-dihydroxybenzylamino)deoxyguanosine (4), respectively. Compounds 1-4 were evaluated against several microorganisms and human cancer cell lines, but found inactive. To our knowledge this is the first report of bromophenols coupled with amino acid or nucleoside derivatives through the C-N bond.

一个先进的工业机器人计算机控制系统——ARCS

随着工业机器人及其应用的不断发展,要求一个强有力的计算机系统来控制它的工作,并具有灵活、方便的机器人编程语言.本文系统地介绍了我们自行设计并实现的一个先进的机器人控制系统——ARCS.该系统主要包括两部分:(1)一个实时多任务的机器人控制软件SVAL系统,该系统支持一种通用性较强的机器人编程语言——SVAL语言.(2)一个支持该软件系统工作的、具有开放式结构的硬件环境.ARCS系统具有良好的实时性、可扩展性及基于外部传感器信号进行控制的能力.由于该系统的开放式结构.使其根据不同要求可方便地增删其功能,并可控制不同类型的机器人.我们已成功地实现对PUMA760机器人的控制,并在其上引入了力觉与接近觉的传感器,采样时间可缩短到16ms.一年多的运行结果证明,该系统稳定可靠,性能良好,现在正向产品转化.

滑动控制理论在海洋机器人动态定位系统中的应用

本文论述了一种新的鲁棒性控制方法——滑动控制理论.并将该方法应用于海洋机器人的动态定位系统设计.仿真结果表明该方法是相当成功和有效的,对系统的参数变化有强鲁棒性.

稳定碳同位素示踪农林生态转换系统中土壤有机质的含量变化

为了观察生态系统的转变对土壤有机质的影响，在贵州茂兰喀斯特原始森林保护区内农林生态系统发生转变的地域，分析了土壤有机质含量和土壤有机质的δ13C值.森林点土壤有机碳含量普遍较高于农田点，表明,毁林造田加速了土壤有机质的降解，使土壤有机质总量减少；对比森林点与农田点的δ13C值，计算表明，毁林造田同时也降低了土壤有机质中活性大的组分的比例，使土壤肥力下降.

喀斯特森林群落退化对浅层岩溶地下水化学的影响

对贵州中部喀斯特地区植被调查及径流和岩溶水样分析,探讨喀斯特森林群落退化过程中浅层岩溶地下水化学组成的变化。结果表明:喀斯特森林生态系统降雨中离子浓度大小的排序为SO2 -4 > K+ 、Ca2 + 、HCO-3 >Na + 、Mg2 + 、Cl - > NO-3 、NH+4 > PO3 -4 ,而径流中离子浓度的大小排序为HCO-3 > SO2 -4 Ca2 + > Mg2 + 、Cl - > K+ 、Na + 、NO-3 > NH+4 > PO3 -4 ;岩溶地下水离子组成与径流总体相似,但岩溶地下中HCO-3 、Ca2 + 和Mg2 + 的含量及电导率明显增加高于地表径流。随着喀斯特森林群落从阔叶林群落向灌木林群落、灌草群落方向演替,其岩溶地下水中HCO-3 和Ca2 + 比例明显减少,而SO2 -4 比例明显增加。岩溶地下水的HCO-3 、Ca2 + 含量与森林覆盖率之间存在显著的正相关,而K+ 、NH+4 含量与森林覆盖率之间则存在显著的负相关。HCO-3 含量是影响岩溶地下水电导率的最重要因子,其次是Ca2 + ,再次是K+ 、Mg2 + ;岩溶地下水电导率可以作为评价喀斯特森林群落退化对生态环境影响的数量指标。

C 228 INST-D 2013. 390 Juguetes y productos decorativos elaborados en madera tallada y torneada.

14 fotografías, trece a color.

A modern pioneer in Korea the life story of Henry G. Appenzeller

http://www.archive.org/details/amodernpioneerin00grifuoft

An heroic bishop : the life-story of French of Lahore

http://www.archive.org/details/anheroicbishopli00stocuoft

A history of Indian missions on the Pacific coast : Oregon, Washington and Idaho / by Myron Eells ; with an introduction by G.H. Atkinson.

http://www.archive.org/details/missionspacific00eellrich

The pastor's missionary manual.

Boston University Theology Library